RECYCLING ACTIVATED CARBON

Revision Date: 01/04
Process Code: Navy/Marines: IND-025-99, SER-015-99; Air Force: FA09, FA10; Army: N/A
Usage List: Navy: Low; Marines: Low; Army: Low; Air Force: Low
Alternative For: Single use/disposal of spent activated carbon waste streams
Compliance Impact: Low
Applicable EPCRA Targeted Constituents and CAS Numbers: Toxic Organic Compounds

Overview: Carbon adsorption is a process in which a contaminated waste liquid- or vapor-phase waste stream is treated by removing the targeted contaminant (the adsorbate) through contact with a solid surface (the adsorbent). Activated carbon that has been processed to significantly increase the internal surface contact area is widely used in many applications as the adsorbent material. Use of different raw materials (e.g., coal, wood, and coconut shells) and processing techniques has resulted in a range of carbon types, in both powdered and granular forms. These types have various adsorption characteristics that tend to make them better suited for specific environmental applications. Granular activated carbon (GAC) is most commonly used for removal of a wide range of toxic organic compounds from contaminated groundwater, industrial wastewater, and vapor phase waste streams. Powdered activated carbon (PAC) is used extensively in biological waste treatment systems, and typically involves different handling and disposal practices than those used for GAC systems.

Activated carbon waste stream can be classified into a variety of possible categories, including both hazardous and non-hazardous waste. The handling and disposal of activated carbon waste streams can pose a significant economic and logistical burden on the waste generator. The incentives for recycling spent activated carbon wastes include financial benefits and reduced liabilities associated with improper handling or disposal of the activated carbon waste stream.

Many companies offer activated carbon recycling services as part of an overall service arrangement or as a stand-alone service. The specific service offered will depend on such factors as the characteristics of the GAC treatment system, the volume of spent carbon to be handled, and the capabilities of the selected vendor. Spent carbon waste can be handled in either bulk shipments via tanker truck or rail cars, or in drums or alternative containers. Virtually all spent carbon waste to be regenerated is processed using a thermal destruction/scrubbing system, which destroys the organic contaminants as well as regenerates the carbon for reuse. Some vendors offering activated carbon regeneration services will segregate the waste batches handled from each customer, if required, while other vendors will "blend" together waste carbon batches from multiple customers prior to processing. This process can be a significant concern to those seeking to minimize liability associated with mixing and disposal of their waste stream with other unidentified wastes from other sources.


Compliance Benefit: Recycling activated carbon (if hazardous) may help facilities meet the requirements of waste reduction under RCRA (40 CFR 262) and Executive Order (EO) 13148. If the activated carbon is non-hazardous, recycling will help facilities meet the requirements of EO 13101 requiring executive agencies (e.g., Department of Defense) to incorporate waste prevention and recycling into their daily operations.

The compliance benefits listed here are only meant to be used as general guidelines and are not meant to be strictly interpreted. Actual compliance benefits will vary depending on the factors involved, e.g., the amount of workload involved.


Materials Compatibility: No materials compatibility issues were identified.


Safety and Health: Activated carbon may contain toxic impurities that can be irritating to the eyes, skin, and mucous membranes. Proper personal protective equipment is recommended. Consult your local industrial health specialist, your local health and safety personnel, and the appropriate MSDS prior to implementing this technology.


Benefits:
  • Eliminates the cost, handling, and related liabilities associated with spent carbon disposal at off-site facilities.
  • Significantly reduces the volume of fresh carbon that must be purchased to regenerate the system.


Disadvantages:
  • Regeneration of powdered activated carbon is typically not practical.
  • If carbon is contaminated with PCBs, dioxins, heavy metals, or DCBP (dichlorobromopropane), regeneration may not be an option.
  • Special packaging may be required if carbon has certain chemical properties (e.g., 2<Ph>11, halide and sulfur contamination, etc.)
  • Regenerate of carbon on-site is not economically feasible unless more than 400,000 pounds of spent AC is generated per year.


Economic Analysis: It is recommended that activated carbon be purchased from a virgin activated carbon supplier that will accept the spent carbon for regeneration. Typically, activated carbon sample analysis and shipping fees are paid by the user, however, there is no charge for regeneration. The economics associated with recycling spent activated carbon will vary based on the volume, system characteristics, contaminants, and handling mode (i.e., bulk or packaged units).

One vendor, Envirotrol, Inc., which performs custom segregated reactivation by which the same carbon is shipped back to the original user, offered the following cost comparison.

Assumptions:

  • Facility uses 2,000 lbs. of activated carbon per month.
  • Spent carbon from the facility is classified as hazardous and must be incinerated.
  • Incineration costs $0.60/lb.
  • Virgin carbon costs $1/lb.
  • Reactivated carbon costs $0.65/lbs.
  • Losses during reactivation of carbon equals 15%. This loss is made up for with virgin carbon when carbon is shipped back to user.
  • Labor and freight costs are the same for both uses.

Table 1. Cost Comparison of Annual Use of Virgin versus Reactivated Carbon

 

Virgin Carbon

Reactivated Carbon

Carbon Purchase: $24,000 $16,860
Carbon Disposal: $14,400 $0
Total: $38,400 $16,860

Economic Analysis Summary:

  • Annual Savings for Recycling Activated Carbon: $21,540
  • Capital Cost for Diversion Equipment/Process: $0
  • Payback Period for Investment in Equipment/Process: Immediate

Click Here to view an Active Spreadsheet for this Economic Analysis and Enter Your Own Values. To return from the Active Spreadsheet, click the Back arrow on the Tool Bar.


NSN/MSDS: None identified.

Approving Authority: Appropriate authority for making process changes should always be sought prior to procuring or implementing any of the technologies identified herein.

Points of Contact: For more information

Vendors: This is not meant to be a complete list, as there may be other manufacturers of this type of equipment.

Calgon Carbon Corporation
P.O. Box 717
1500 Calgon Carbon Drive
Pittsburgh,  PA   15230-0717
Phone: (800) 422-7266 or (866) 225-4660
E-mail:  customerrelations@calgoncarbon.com
URL:  http://www.calgoncarbon.com/


Carbtrol Corporation
955 Connecticut Avenue, Suite 5202
Bridgeport, CT  06607
Phone: (800) 242-1150
FAX:  (203) 337-4353
E-mail:  info@carbtrol.com
URL:  http://www.carbtrol.com


Envirotrol, Inc.
432 Green Street
P.O. Box 61
Sewickley,  PA   15143
Phone: (412) 741-2030
FAX:  (412) 741-2670
E-mail:  info@envirotrol.com
URL:  http://www.envirotrol.com/


Related Links:

None


Sources: Mr. Scott Berner, Naval Air Station Jacksonville, January 1999.