RECYCLING ACTIVATED CARBON
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Overview: | Carbon adsorption is a process in
which a contaminated waste liquid- or vapor-phase waste stream is treated
by removing the targeted contaminant (the adsorbate) through contact with
a solid surface (the adsorbent). Activated carbon that has been processed
to significantly increase the internal surface contact area is widely
used in many applications as the adsorbent material. Use of different raw
materials (e.g., coal, wood, and coconut shells) and processing
techniques has resulted in a range of carbon types, in both powdered and
granular forms. These types have various adsorption characteristics that
tend to make them better suited for specific environmental applications.
Granular activated carbon (GAC) is most commonly used for removal of a
wide range of toxic organic compounds from contaminated groundwater,
industrial wastewater, and vapor phase waste streams. Powdered activated
carbon (PAC) is used extensively in biological waste treatment systems,
and typically involves different handling and disposal practices than
those used for GAC systems.
Activated carbon waste stream can be classified into a variety of possible categories, including both hazardous and non-hazardous waste. The handling and disposal of activated carbon waste streams can pose a significant economic and logistical burden on the waste generator. The incentives for recycling spent activated carbon wastes include financial benefits and reduced liabilities associated with improper handling or disposal of the activated carbon waste stream. Many companies offer activated carbon recycling services as part of an overall service arrangement or as a stand-alone service. The specific service offered will depend on such factors as the characteristics of the GAC treatment system, the volume of spent carbon to be handled, and the capabilities of the selected vendor. Spent carbon waste can be handled in either bulk shipments via tanker truck or rail cars, or in drums or alternative containers. Virtually all spent carbon waste to be regenerated is processed using a thermal destruction/scrubbing system, which destroys the organic contaminants as well as regenerates the carbon for reuse. Some vendors offering activated carbon regeneration services will segregate the waste batches handled from each customer, if required, while other vendors will "blend" together waste carbon batches from multiple customers prior to processing. This process can be a significant concern to those seeking to minimize liability associated with mixing and disposal of their waste stream with other unidentified wastes from other sources. | ||||||||||||
Compliance Benefit: | Recycling activated carbon (if
hazardous) may help facilities meet the requirements of waste reduction
under RCRA (40 CFR 262) and Executive Order (EO) 13148.
If the activated carbon is non-hazardous, recycling will help facilities
meet the requirements of EO 13101 requiring executive agencies
(e.g., Department of Defense) to incorporate waste prevention and recycling into their daily
operations.
The compliance benefits listed here are only meant to be used as general guidelines and are not meant to be strictly interpreted. Actual compliance benefits will vary depending on the factors involved, e.g., the amount of workload involved. | ||||||||||||
Materials Compatibility: | No materials compatibility
issues were identified.
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Safety and Health: | Activated carbon may contain
toxic impurities that can be irritating to the eyes, skin, and mucous
membranes. Proper personal protective equipment is recommended. Consult
your local industrial health specialist, your local health and safety
personnel, and the appropriate MSDS prior to implementing this
technology. | ||||||||||||
Benefits: |
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Disadvantages: |
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Economic Analysis: | It is recommended that
activated carbon be purchased from a virgin activated carbon supplier that
will accept the spent carbon for regeneration. Typically, activated carbon
sample analysis and shipping fees are paid by the user, however, there is
no charge for regeneration. The economics associated with recycling spent
activated carbon will vary based on the volume, system characteristics,
contaminants, and handling mode (i.e., bulk or packaged units).
One vendor, Envirotrol, Inc., which performs custom segregated reactivation by which the same carbon is shipped back to the original user, offered the following cost comparison. Assumptions:
Table 1. Cost Comparison of Annual Use of Virgin versus Reactivated Carbon
Economic Analysis Summary:
Click Here to view an Active Spreadsheet for this Economic Analysis and Enter Your Own Values. To return from the Active Spreadsheet, click the Back arrow on the Tool Bar. | ||||||||||||
NSN/MSDS: | None identified.
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Approving Authority: | Appropriate authority for making process changes should always be sought prior to procuring or
implementing any of the technologies identified herein. | ||||||||||||
Points of Contact: | For more information | ||||||||||||
Vendors: | This is not meant to be a
complete list, as there may be other manufacturers of this type of
equipment.
Calgon Carbon Corporation | ||||||||||||
Carbtrol
Corporation 955 Connecticut Avenue, Suite 5202 Bridgeport, CT 06607 Phone: (800) 242-1150 FAX: (203) 337-4353 E-mail: info@carbtrol.com URL: http://www.carbtrol.com | |||||||||||||
Envirotrol, Inc. 432 Green Street P.O. Box 61 Sewickley, PA 15143 Phone: (412) 741-2030 FAX: (412) 741-2670 E-mail: info@envirotrol.com URL: http://www.envirotrol.com/ | |||||||||||||
Related Links: |
None
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Sources: | Mr. Scott Berner, Naval Air Station Jacksonville, January 1999. |