PLASMA ARC TECHNOLOGY


Revision Date: 6/01
Process Code: Navy/Marines: IND-025-99; Air Force: HW01; Army: N/A
Usage List: Navy: Medium; Marines: Medium; Army: Medium; Air Force: Medium
Alternative For: Hazardous waste landfill disposal and incineration
Compliance Impact: High
Applicable EPCRA Targeted Constituents and CAS Numbers: Various

Overview: The plasma arc technology (PAT) uses heat generated by a plasma arc to melt the inorganic portion of waste material while destroying the organic portion. Types of waste materials tested include medical incinerator ash, Longhorn sludge, open burning ground soil, agricultural and plastic/glass blast media, surrogate absorbent materials, Mendocino soil spiked with dichlorobenzene, and waste paint.

Several demonstration tests were performed in a Plasma Arc Centrifugal Treatment (PACT) system designed and built by Retech, Inc., Ukiah, California, specifically for pilot-scale testing. The heart of the PACT-2 system is its primary combustion chamber, which consists of a 2-foot diameter centrifuge (i.e., a tub) heated by a RP-75 T plasma torch fitted with a 200 kW power supply. Typically the chamber gas temperature ranges between 927-1200°C (1700-2200°F), and the temperature of the molten material is approximately 1650°C (3000°F). The primary chamber operates under a slight vacuum.

The waste is fed into the primary chamber from an Archimedes screw-type feeder. The feeder is approximately 152-cm (5-ft) long, 51 cm (20 in) in diameter with 7.6-cm (3-in) high flights. The feeder drops the waste onto an auger screw-type feeder, which introduces the waste to the tub through a port in the chamber wall. For proper feeding to the auger feeder, material size is limited to approximately a 1-in cube of solid, dense material.

Once the tub reaches its capacity, feeding is stopped and a dwell time of approximately 30 minutes is maintained. The molten material is drained by slowing the tub rotation speed, allowing the material to flow through a hole in the bottom center of the tub. The material is cast into a steel slag mold, which rotates with the tub. To remove the mold, tub rotation is stopped. The PACT-2 system is equipped with an automatic mold alignment mechanism that allows a slag mold manipulator to lift the mold, move it to the slag mold chamber, and then pull it out of the chamber into the work area. The mold manipulator is enclosed in the slag mold chamber, which has an isolation valve that keeps solid material or gases from entering during processing. The valve also allows the primary chamber to remain hot while the slag mold is changed. Once an empty mold is put in place, the system can be restarted and processing of waste can resume.

Process gases exit the primary chamber through a port in the chamber wall. These gases enter the secondary combustion chamber, which is heated by an RP-250N plasma torch. The temperature range is the same as the primary combustion chamber. A 2-second residence time is maintained to ensure complete destruction of the hazardous organic compounds. Off gases are pulled through the system by a venturi educator located in the pollution abatement portion of the system.


Compliance Benefit: PACT is used to destroy hazardous wastes. The destruction process renders the waste non-hazardous while reducing its volume. The destruction of hazardous waste helps facilities meet the requirements of waste reduction under RCRA, 40 CFR 262, and may also help facilities reduce their generator status and lessen the regulatory burden (e.g., recordkeeping, reporting, inspections, transportation, accumulation time, emergency prevention and preparedness, and emergency response) under RCRA, 40 CFR 262.

The compliance benefits listed here are only meant to be used as general guidelines and are not meant to be strictly interpreted. Actual compliance benefits will vary depending on the factors involved, e.g., the amount of workload involved.

Materials Compatibility: No materials compatibility issues were identified.


Safety and Health: Caution must be exercised with the equipment, as high voltages are a potential danger. The process employs two plasma torches, each of which are capable of a sustained output of 160 kW. The torches must be shielded and protected.

Since the process is use to treat hazardous and combustible materials, proper personal protective equipment must be worn and other safety practices must be employed. Consult your local industrial health specialist, your local health and safety personnel, and the appropriate MSDS prior to implementing this technology.

The PAT waste treatment process has several safety advantages when compared to conventional incineration systems. The primary advantage is the use of less air for combustion. Water-cooled chambers allow better sealing, which reduces the risk of uncontrolled releases of noxious fumes. Water cooling reduces the exterior surface temperature, which reduces burn and fire hazards. It also allows for faster shutdown, and a significant thermal capacitance for responding to unusual events. Rapid cooling and capture of the reaction products in the slag or in the off-gas treatment systems reduces the opportunities for operator contact with the hazardous materials.

Consult your local industrial health specialist, your local health and safety personnel, and the appropriate MSDS prior to implementing this technology.


Benefits:
  • Offers a single-step treatment for a variety of waste streams, both small and large. Media amenable to treatment includes soil, sludge, ash, solids, pastes, and liquids from industrial processing operations.
  • Requires minimal waste pretreatment.
  • Achieves destruction and removal efficiencies (DREs) in excess of the U.S. Environmental Protection Agency requirement of 99.99%. It converts organic materials into simple gaseous compounds that can be easily scrubbed and rendered harmless, and stabilizes toxic wastes in a leach-resistant, vitrified slag that is suitable for landfill deposition.
  • Is efficient in treating process by-products including fly ash and scrubber residues.
  • Offers several safety advantages in comparison to conventional incineration processes.
  • Provides volume reduction of the waste streams, ranging from 67-99%, depending on the composition of the waste stream. Corresponding benefits include reduced storage, handling, and shipping costs, in addition to providing increased life to landfills since less waste will be dumped into landfills.


Disadvantages:
  • Still in research stage.
  • Substantial initial investment in equipment and staff training.
  • Air and water permits are needed; however, the demonstration revealed air emissions met Clean Air Act standards, and the process generated wastewater that could be treated and recycled.


Economic Analysis: The National Defense Center for Environmental Excellence (NDCEE), which is operated by Concurrent Technologies Corporation, was tasked by the Department of Defense to evaluate the applicability of PAT to treat complex military wastes. This evaluation included a life-cycle cost analysis, using CTC's ECAMsm program, conducted in 1997.

Since the PACT-2 was designed as a research unit, its operating costs are higher than a full-time processing system. For this reason, a transportable PACT-5 system, a PACT-8 single torch system, and a PACT-8 also were evaluated to provide an end user configuration for processing waste materials.

Assumptions:

  • The average disposal cost for hazardous waste materials was $1,225. This cost was based on information provided by the military sites that supplied the tested waste.
  • A total of 220 days per year of processing at 7 days per week with 3 operational shifts of 8 hours each.
  • A 60% system availability, with a total operational time of 5,280 hours per year.
  • Feed to slag conversion is feed dependent, and was based on actual testing results and, where applicable, used a thermodynamic model.
  • Electricity cost was based on $0.08/KWh.
  • A PACT-5 transportable unit has at least 2 setups and incurs additional costs because it is a mobile system.
  • Breakdown of the cost categories is shown in the following table.

Table 1. Operating Costs Per Ton for Wastes Studied

Waste

PACT-2 Research

PACT-5 Transportable

PACT-8
2 Torches

PACT-8
1 Torch

Medical Ash

1687

707

694

1011

Longhorn Sludge

5764

581

478

456

Open Burning Ground Soil

2113

875

806

1266

Agricultural Blast Medium

5659

577

444

415

Plastic/Glass Blast Medium

5866

1412

1065

991

Surrogate Adsorption Medium

5781

1323

980

906

Garnet Blast Medium

2368

815

730

1202

Mendocino Soil Spike with Dichlorobenzene

2961

874

804

1288

Waste Paint

6360

1662

1398

1342

Average Treatment Cost

$4283

$981

$931

$986


NSN/MSDS: None Identified.


Approving Authority: Appropriate authority for making process changes should always be sought and obtained prior to procuring or implementing any of the technology identified herein.


Points of Contact: For more information

Vendors: This is not meant to be a complete list, as there may be other suppliers of this type of equipment.

Retech, Inc.
A Division of M-4 Environmental
100 Henry Station Road
Ukiah, CA 95482

Plasma Energy Applied Technology Corporation
4914 Moores Mill Road
Huntsville, AL 35811

Georgia Institute of Technology
School of Civil & Environmental Engineering
Atlanta, GA 30332-0612

Plasma Technology Corporation
8601 Six Forks Road, Suite 400
Raleigh, NC 27615

Plasma Technology, Inc.
1800 Old Pecos Trail, Suite O
Santa Fe, NM 87505

Westinghouse Plasma Corporation
P.O. Box 410
Madison, PA 15663
Phone: (724) 722-7052


Sources: Concurrent Technologies Corporation. Plasma Arc Technology Evaluation. Science and Technical Report. Draft. April 28, 1997.


Supplemental:

Schematic of the plasma arc technology.