ZINC-NICKEL PLATING

Revision Date: 4/03
Process Code: Navy/Marines: IND-004-01, IND-004-99; Air Force: MT05; Army: ELE
Usage List: Navy: Medium; Marines: Medium; Army: Medium; Air Force: Medium
Alternative For: Cadmium Plating
Compliance Impact: Not applicable
Applicable EPCRA Targeted Constituents and CAS Numbers: Cadmium (CAS 7440-43-9)

Overview: The reflectalloy alkaline zinc-nickel plating process is a direct replacement of the cadmium process used on fasteners and steel components to provide protection against corrosion.

Cadmium plating is called out in various places in the 2J-T56-53 depot maintenance technical order. Most cadmium coatings are applied by electrodeposition, typically from a cyanide-based plating bath.

Testing was performed to compare the performance of the reflectalloy alkaline zinc-nickel process and cadmium plating process on T56 engine components. Selected T56 engine parts were obtained from San Antonio Air Logistics Center, Texas. Approximately half of the parts were used to provide baseline performance data for electroplated cadmium. The remaining parts were stripped and re-plated with zinc-nickel using the alkaline reflectalloy electroplating process.

Applied coatings were tested and evaluated based on specified corrosion and lubricity (torque-tension) methods and criteria specified in the test and evaluation plan. Test results indicated that zinc-nickel provides equal or better corrosion resistance, adhesion, and torque-tension properties to cadmium. Test results also indicated that the zinc-nickel plating was improved with Surrender Anti-Seize rather than engine oil or other lubricants.

Technical orders are being revised to include zinc-nickel plating as an alternative to cadmium plating.


Compliance Benefit: Chemicals used in cadmium and cyanide processes are toxic to humans and are strictly regulated by local, state, and federal agencies. Replacing those processes with a non-cadmium/cyanide process reduces the volume of hazardous waste, and decreases the amount of cadmium and cyanide at the facility. The reduction of hazardous waste helps facilities meet the requirements of waste reduction under RCRA, 40 CFR 262, Appendix. It may also help facilities reduce their generator status and lessen the amount of regulations (i.e., recordkeeping, reporting, inspections, transportation, accumulation time, emergency prevention and preparedness, and emergency response) they are required to comply with under RCRA, 40 CFR 262. In addition, this technology allows facilities to eliminate cadmium and cyanide bath solutions, so there is less chance that the facility would exceed reporting thresholds for cadmium and cyanide under SARA Title III (40 CFR 300, 355, 370, and 372; and EO 12856). Both process types may require an industrial wastewater discharge permit (local issue).

The compliance benefits listed here should be used as a general guideline and should not be strictly interpreted. Actual compliance benefits will vary depending on the factors involved, e.g., the amount of workload involved.


Materials Compatibility: The plating process can only be applied to metallic substrates.


Safety and Health: Caution must be exercised with the equipment. Proper personal protective equipment must be worn and other safety practices must be employed.

Consult your local industrial health specialist, your local health and safety personnel, and the appropriate MSDS prior to implementing this technology.


Benefits:
  • Elimination of cadmium and cyanide, toxic metals targeted by the Environmental Protection Agency.
  • Improved health and safety working conditions and decreased health-related costs (liability risks, protective equipment costs, and monitoring costs) compared to the use of cadmium plating.
  • Alkaline zinc-nickel plating provides equal or better corrosion resistance as cadmium plating.
  • Alkaline zinc-nickel plating was found to be the most salt-spray resistant of the several non-cadmium platings tested.


Disadvantages:
  • Zinc-nickel plating used with engine oil leads to excessive friction coefficients. If the engine oil is replaced with Surrender Anti-Seize, zinc-nickel plating has comparable torque-tension properties to cadmium.


Economic Analysis: The National Defense Center for Environmental Excellence (NDCEE), operated by Concurrent Technologies Corporation (CTC), was tasked by the Department of Defense to investigate the technical viability of the reflectalloy alkaline zinc-nickel plating process. No detailed economic analysis has been performed; however, the plating process can be implemented using existing tanks, heaters, and ventilation systems. The only cost variable will be for the initial make up for the process bath.


NSN/MSDS: None Identified.


Approving Authority: Appropriate authority for making process changes should always be sought and obtained prior to procuring or implementing any of the technologies identified herein.


Points of Contact: For more information

Vendors:

This is not meant to be a complete list, as there may be other suppliers of this type of equipment.

McGean-Rohco, Inc
2910 Harvard Avenue
Cleveland, OH 44105
Phone: (216) 441-4900


Sources: Concurrent Technologies Corporation. Hazardous Material Alternatives for the T56 Engine: Scientific and Technical Report. May 31, 2000.