Cleaning Liquids

 

Cleaning solutions, solvents and degreasers come in three forms:

  1. Petroleum based mixtures of mineral spirits, Stoddard solvent, petroleum naphtha, and xylene. Mineral spirits is a solvent commonly used for part cleaning because of its ability to quickly dissolve oil, grease, dirt, grime, burnt-on carbon, and heavy lubricants. 
  2. Halogenated solvents found in degreasers and carburetor cleaners
  3. Aqueous (water based) detergent cleaners. 

 

These cleaning liquids are generally applied in four ways:

  1. Soak tanks – degreasers and carburetor cleaners
  2. Sinks – mineral spirits, solvents, and aqueous
  3. Spray cabinets
  4. Spray cans – aerosol and refillable

 

Parts Washers - Mineral Spirits

Parts washers using mineral spirits and other hydrocarbon solvents are the oldest and most common means of degreasing parts. Most mineral spirits-based parts washers continually recirculate the solvent through a filter to extend the time between solvent change-out. Most of the petroleum solvents used in these washers are considered hazardous wastes due to their low flash point and resulting ease of ignition. The variety of metal particles, dissolved lubricants, and other debris suspended in the dirty solvent further contribute to the hazardous nature of the solvent. The tendency of shop personnel to use aerosol cans of brake cleaner and other chlorinated solvents over the open parts washer also adds to the hazardous nature of used parts washer solvent.

 

Solvents-principally from parts washers-are typically the largest source of hazardous waste generated by vehicle repair shops. Solvent use and waste can be reduced by reducing solvent cleaning requirements (if possible); extending solvent life and recycling used solvent on-site. Recycling can be done via lease/purchase of a parts washer that filters and recycles the solvent. If 750 gallons or more per year of solvents are being disposed of as a hazardous waste, buying or leasing such a unit may make good business sense.

 

The need to have mineral spirits-based parts washers periodically serviced by a licensed vendor results in a substantial expense for many auto repair shops. Mineral spirits-based parts washers can use many of newer, alternative solvents that are not hazardous if used alone. Switching to one of these may very well reduce the overall expense of parts washing. Depending upon the volume of parts washing, it may be economically feasible to purchase or lease a spray cabinet-type parts washer that uses an aqueous detergent solution instead of solvents.

 

Parts Washers – Aqueous

Aqueous (water-based) parts washers have proven to be a cost effective and environmentally friendly alternative way to clean parts for most medium- to large-sized vehicle repair facilities. Any shop using several solvent-based parts washers should investigate switching to an aqueous parts washer with a recyclable waste water system. A recyclable system minimizes or eliminates potential wastewater disposal problems. Despite their environmental benefits, certain precautions need to be taken regarding byproducts of aqueous parts washer operations. It is important to remember that the sludge that gathers at the bottom of an aqueous parts washer can be a hazardous waste due to the presence of metal particles and/or certain solvents.

DO

DO NOT

 

Brake And Carburetor Cleaners

Brake and carburetor cleaners traditionally have consisted of chlorinated hydrocarbons-such as methylene chloride-dispensed from aerosol spray cans. Recently there has been a move toward the use of alternative solvents, primarily in reaction to the numerous health hazards posed by chlorinated hydrocarbons and increasing government regulation of such solvents. Chlorinated solvents are also a problem in the auto repair shop environment due to the risk of contaminating other waste fluids (antifreeze, motor oil, etc.) with overspray or run-off. Careless use of chlorinated solvents can easily lead to contamination of other fluids that would otherwise be considered non-hazardous. An aerosol can that will not function properly but is still full may be a hazardous waste.

 

N-Hexane Use as a Brake Cleaner

Hexane is a solvent. It's used mainly in vegetable oil extraction and in cleaners, degreasers, glues, and spray paints. n-Hexane is one kind of hexane. Commercial hexane usually contains 200/0 to 800/0 n-hexane, so you should treat all hexane as if it's n-hexane. Pure n-hexane is a colorless, very fast- evaporating liquid with a faint disagreeable odor.

 

Do you use any of these products ?

q     Amrep Brake Parts Cleaner

q     Berryman B-12 Chemtool Carb and Choke Cleaner

q     Berryman Chemtool Air-Intake Cleaner

q     Berryman Non-Chlorinated Brake Cleaner

q     Certified Labs Dylek PS Aerosol

q     Continental Research Brake Master

q     Drummond American Corp. Strafe

q     Loctite Disc Brake Quiet

q     Loctite Flam Brake Clean

q     Loctite ODC-Free Cleaner and Degreaser

q     Loctite Pro Strength Degreaser

q     Malco Brake and Parts Wash

q     Malco Carb, Choke and Injection Cleaner

q     Mantek DJC PS Aerosol

q     Penray Non-Chlorinated Brake Gard

q     Seymour of Sycamore Non-Chlorinated Brake Cleaner

q     Sherwin Williams Automotive Cleaners

q     Sherwin Williams Brake Parts Wash

q     Sherwin Williams Cleaner/Degreaser

q     Sherwin Williams Non-Chlorinated Brake Cleaner

q     Sherwin Williams Parts Wash

q     Taylor Made Non-Chlorinated Brake Cleaner

q     Technical Chemical Non-Chlorinated Brake Cleaner

q     Winzer Brake Cleaner, Non-Chlorinated

q     Wurth Brake and Parts Cleaner (liquid and aerosol)

q     Zep Aerosol Brake Parts Cleaner

q     Zep Brake Wash (liquid)

q     Zep Parts Cleaner (aerosol)

 

(These are some products reported to contain hexane in a recent survey. However, products like these can change their ingredients quite often. Be sure to check the MSDS for whatever products you're using.)

 

Problems

 

Environmental Impact

Mineral spirits contains volatile organic compounds (VOC) that contribute to smog formation and may be toxic when inhaled. Dependent upon use, solvents can also contain chlorinated hydrocarbons.  Although it is effective for cleaning, mineral spirits raises significant environmental and human health concerns.

 

Worker Safety

Using solvents creates unnecessary environmental, worker health, and fire liabilities for the shop.  Mineral spirits evaporates quickly, making worker exposure difficult to control.

The substances and the contaminants picked up in use make spent solvents hazardous waste s because they are ignitable and/or toxic.

Solvents are highly volatile and flammable you should review the MSDS  for the product prior to its use to make sure you understand the hazards it poses.  Wear appropriate skin and eye protection.  Work in a ventilated area and/or use proper respiratory protection.  Check the MSDS to determine which respirator is suggested for a specific solvent.  Most solvents contain volatile organic compounds; make sure that solvent containers are tightly covered so vapors are not released.

 

n-Hexane

Long-term overexposure to n-hexane can damage the nerves in the feet, legs, hands, and arms. The damage can last a long time and may become permanent. The symptoms include numbness, tingling, weakness (sometimes even paralysis), and reduced ability to feel touch, pain, vibration, and temperature. Short-term overexposure can cause headache, dizziness, loss of appetite, giddiness, and drowsiness. Health effects have only been reported when exposure levels were above California's workplace Permissible Exposure Limit - but people working with n-hexane can easily be exposed to levels that high. This Health Hazard Advisory was prompted by cases of nerve cases of nerve damage identified among auto mechanics using spray brake cleaner that contains n-hexane.  See Appendix K for more information on n-Hexane

 

How to know if you are working with n -Hexane

If you may be exposed to hexane at work, ask to see the Material Safety Data Sheet (MSDS) for each brake and parts cleaning product in your work area. Your employer must have an MSDS for any work- place product that contains a hazardous substance, and must make the MSDS available to you on request. If a product contains n-hexane, the MSDS should identify it in section 2 by the CAS number 110-54-3.

 

How n-Hexane enters your body

n-Hexane enters your body when you breathe n-hexane vapors or droplets of spray in the air. Some can enter your body when hexane touches your skin.  Your risk of health effects depends on the amount of n-hexane that enters your body. That depends mainly on the amount (the concentration) of hexane in the air and how long you are exposed.

 

How n- Hexane Can Affect Your Health

 

Effects on the Nervous System.

Repeated overexposure to n-hexane (probably for months) can damage nerves in the feet, legs, hands, and arms. This is called peripheral neuropathy. The first symptom is usually numbness or tingling in the feet and legs, and then in the hands. There may be reduced ability to sense touch, pain, vibration, and temperature. Muscles may become weak, especially in the hands, legs, and feet. In severe cases, there may be muscle wasting (shrinking) and, rarely, paralysis. These effects often slowly improve if exposure is stopped, but they can last for many months and may be permanent. The symptoms may even continue to get worse for a few months after exposure stops.

 

Short-term overexposure can temporarily affect the brain, causing headache, dizziness, loss of appetite, giddiness, and drowsiness. These effects disappear within hours of stopping exposure.

 

Nerve damage has occurred among workers exposed to air concentrations of n-hexane only a little above the workplace Permissible Exposure Limit (50 ppm-see below). If exposure is not controlled, workers can easily be exposed to levels well above 50 ppm. Exposures high enough to cause short-term effects on the brain are also high enough to cause peripheral neuropathy if the exposure happens frequently.

 

n-Hexane is more likely to damage nerves if you use it together with acetone, methyl ethyl ketone (MEK), methyl isobutyl ketone (MIBK), or lead acetate. Don't use hexane in combination with these chemicals.

 

n-Hexane breaks down in the body to form methyl n-butyl ketone (MnBK) and 2,5-hexanedione (2,5-HD). Those are the chemicals that actually damage the nerves. Some products may contain MnBK or 2,5-HD.  Do not use those products.

 

Other Effects.

n-Hexane is not likely to cause health problems other than those described above. Exposure to very high levels (20 or more times the legal exposure limit) damaged the sperm-forming cells and the lungs of test animals. However, these effects have never been reported in humans. Hexane does not appear to be a special hazard to pregnancy. Hexane does not cause genetic mutations. We do not know whether hexane can cause cancer; when it was tested in animals, the results were unclear.

 

Are there any tests for health effects and exposure?

A neurologist or a doctor who specializes in occupational medicine can test whether your nerves are damaged. The simplest way is to test nerve conduction velocity (how fast a nerve carries a message). Nerve damage from hexane exposure usually occurs on both the left and the right sides of the body equally. Symptoms on just one side are likely to have some other cause, such as diabetes, carpal tunnel syndrome, medications, or alcohol.

 

A urine test for the toxic breakdown product, 2,5-hex-anedione, can be used to estimate exposure within the last week or so. The best time for such a urine sample is at the end of the last shift of a workweek. n-Hexane and its breakdown products are not stored in the body very long. They are eliminated fairly quickly in the breath and urine, although the amount in your body can increase over a workweek if you're exposed every day.

 

Workers who will be regularly exposed to hazardous substances should be given a complete physical examination at the beginning of their employment. The exam should include medical and work histories. They should also have periodic follow-up examinations.

 

How to control your exposure

Your employer must protect you from being exposed to chemicals at levels above the legal exposure limits. Call OSHA and the Cal/OSHA Consultation Service can help you and your employer-see the "Resources" section below.

 

Regulations

Spent mineral spirits is a hazardous waste and the shop owner is responsible for proper disposal of all hazardous wastes.  Some areas of the country have already restricted use of solvents in parts cleaning operations. 

 

Always check the product’s Material Safety Data Sheet (MSDS) to determine safe shop practices and proper disposal method.  Parts washing produced waste solutions are subject to RCRA reporting, waste minimization, and disposal requirements.  Parts cleaner solutions are usually contaminated with metals, oils and dirt picked up during the cleaning process.  Most solvent-based wastes are considered hazardous because they are flammable and/or toxic.  Characterized solvent wastes are judged toxic either because of their original chemical composition or because they have been contaminated with heavy metals in use.  Many petroleum distillates, mineral spirits, and naphtha have flashpoints less than 140° F.  These wastes are ignition hazards.

 

Spent solvent waste is considered hazardous due to its ignitability, toxicity characteristics, or because it contains listed chemicals.  No substance classified as a hazardous waste can be released into the sanitary sewer or storm drains! A facility must determine that its discharges are non-hazardous as described in 40 CFR 403 subsection 2.7.  Sent solvents should never be placed in a trash dumpster.  Spent parts cleaner solutions must be controlled in the shop to prevent them from contaminating any storm water drain or sewer system.  Call your local sewer system for answers to your questions concerning storm water runoff or discharging to the sewer.

 

Regulations that help to protect workers from n-Hexane

 

Permissible Exposure Limits.

The Cal/OSHA Standards Board sets Permissible Exposure Limits (PELs) for the amounts of certain chemicals in workplace air. The PELs are intended to protect the health of most people who are exposed every day over a working lifetime.

 

Cal/OSHA's PEL for n-hexane is 50 parts of n-hexane per million parts of air (50 parts per million, or 50 ppm). You may also see this stated as 180 milligrams of hexane per cubic meter of air (180 mg/m3). Legally, your exposure may be above the PEL at times, but only if it is below the PEL at other times, so that your average expo- sure for any 8-hour work shift is no more than 50 ppm.

 

Monitoring.

If you work with n-hexane and think you might be overexposed, talk to your supervisor or your union. If any worker might be exposed to a sub- stance at more than the legal limit, the employer must measure the amount of the substance in the air in the work area (Title 8, Section 5155(e)). You have the legal right to see and copy the monitoring results (Title 8, Section 3204).

 

You cannot rely on your sense of smell to warn you that you are being overexposed to n-hexane. n-Hexane has only a very faint smell, and it's not very irritating to the eyes, nose, or throat. You can easily be overexposed without knowing it. Measuring the amount in the air is the only reliable way to know the exposure level.

 

Hazard Communication Standard.

Under California's Hazard Communication Standard (California Administrative Code, Title 8, Section 5194), your employer must tell you if you are working with any hazardous substances, must train you to use them safely, and must make Material Safety Data Sheets available.

 

Injury and Illness Prevention Program.

Every employer must have an effective, written Injury and Illness Prevention Program (IIPP) that identifies a person with the authority and responsibility to run the program (Title 8, Section 3203). The IIPP must include methods for identifying workplace hazards, methods for correcting hazards quickly, health- and safety training at specified times, a system for communicating clearly with all employees about health and safety matters (including safe ways for employees to tell the employer about hazards), and record-keeping to document the steps taken to comply with the IIPP.

 

Access to Medical and Exposure Records.

You also have the right to see and copy your own medical records, and any records of your exposure to toxic substances. These records are important in deter- mining whether your health has been affected by your work. Employers who have such records must keep them and make them available to you for at least 30 years after the end of your employment.

 

Solutions

 

Waste Reduction

Keep soak tank containers closed when not in use to avoid evaporation.  Solvent should never be used for the general cleaning of shop floors.  When not in use, all solvent cleaning tanks must be covered and/or drain plugs closed.  Solvent losses due to inappropriate usage, equipment leaks or spills, and evaporation can range from 25 to 40 percent of total solvent usage.  Cans of spray cleaner should only be used when parts cannot be removed from the car and cleaned in a solvent sink.

 

To reduce your solvent losses use a solvent sink  with a recirculating base tank.  Place your solvent sinks close to where cleaning will be done.  Remove parts slowly after immersion to reduce drippage, install drip trays or racks to drain cleaned parts, allowing more drainage time over the sink after withdrawal, and turn off the solvent stream, covering or plugging sink when not in use.  Many solvent service companies will lease you a sink (and for a small fee), pick up dirty solvent, clean and maintain the solvent sink, and refill the sink with clean recycled solvent.  The cost for contracting with a service provider is often less than the combined cost of solvent purchase, sink maintenance, and waste disposal.

·         Consider using less hazardous solvents or switching to a spray cabinet parts washer that does not use solvent.

·         Install a filter on your solvent sink to greatly increase the life of the solvent.

·         Consider purchasing your own solvent still and recycling solvent on-site

·         Sludges, filters, and still bottoms generated from on-site solvent recovery systems are hazardous.

·         Keep spent solvent wastes in separate, labeled, closed containers.

·         Don't mix solvents with any other wastes, especially used oil!

 

Many shops have completely abandoned the use of brake cleaners and carburetor cleaners packaged in aerosol cans in favor of non-hazardous solvents dispensed from reusable spray cans. The new solvents are purchased in bulk, and used to refill the reusable spray can. The can is then pressurized with compressed air from the shop system, via a fitting on the top of the can. Not only are the new solvents more environmentally friendly, they are in many cases more effective cleaners than the solvents they replace. In addition, the compressed air-driven spray cans deliver a more concentrated stream of cleaner to the part in comparison to aerosol spray cans.

 

n-Hexane Usage

 

Ventilation.

Make sure that there is good ventilation. "Local exhaust ventilation" is most effective; it captures contaminated air at the source, before the hexane can spread into your breathing zone. Next best is general ventilation, which uses a fan-powered system to bring fresh air into the work area. Open doors and windows usually provide very little ventilation. An indoor fan that just blows contaminated air around without removing it from your work area is not effective.

 

Respiratory Protection.

Hexane has very poor "warning properties" (that is, it has little odor and isn't very irritating). Only supplied-air respirators are approved for protection against hexane. Filter respirators are not approved, because when the cartridge "wears out," there is no warning to alert you that the respirator no longer provides protection.

 

Skin Protection.

It may be hard to avoid getting parts cleaning products on your hands. If you can use a water-based cleaner and make sure that it's pH neutral (to prevent irritation and burns), you probably won't need protective gloves. If you must use hexane products and it is likely that you'll have a lot of skin contact, wear protective gloves and replace them often. Viton and polyvinyl alcohol are recommended, and Silvershield and chlorinated polyethylene are also good. Other glove materials, such as latex rubber, provide very poor protection against hexane. California law requires an employer to supply gloves or any other necessary safety equipment at no cost to the employee.

 

Substitution.

The surest way to protect yourself is to switch to products that don't contain hexane. Avoid using products for which you do not have an MSDS.  Especially avoid using products that combine hexane with acetone, MEK, MIBK, or lead acetate.

 

Switch to water-based (aqueous) cleaners for cleaning of brakes and other vehicle parts. Some aqueous cleaners work as well as solvent cleaners, and they don't pollute the air in the workplace or the environment. Unlike solvent cleaners, aqueous cleaners are usually non-flammable. An aqueous cleaning system will probably even save the shop money, because an automated aqueous spray cabinet for cleaning parts can greatly reduce labor time. Aqueous cleaner also lasts longer, so you won't need to buy as much of it. Environmental compliance may also be easier, and you can reduce your hazardous waste disposal costs. Experience shows that switching to an aqueous cleaning system can pay for itself within as little as three months to a year. Many vendors will offer their aqueous systems free of charge for a testing period of a week to a month to help you select the best system for your shop. If you can't switch to hexane- free products, take other steps to limit your exposure.

 

Use Less.

If you must use hexane products, use as little as possible. Keep containers closed between uses. Hexane can evaporate quickly from a hexane-soaked rag, so make sure that used rags are kept in a well- ventilated area.

 

Brake and Carburetor Cleaners

DO

DO NOT

 

Aqueous Brake Cleaning

Because of the special requirements for cleaning automotive brakes, this subject requires additional coverage.  Asbestos and other particles can cause worker safety issues as well as environmental impact.  Aerosol spray cans have become the standard and with them some very serious problems.  These will be covered in more detail in a following section.  To avoid some of these problems, the best alternatives are aqueous brake washers.  Aqueous brake washers perform as effectively as traditional solvent washers, they are better for the environment, and they reduce hazardous waste management costs and liability.

 

Washing brakes before inspection and repair helps create a clean work area. It also removes dust and debris that prevent the brakes from functioning properly and cause squeaking and grinding. Brake washing can be performed using three devices:

  1. Aerosol cans of solvent-based brake cleaner
  2. Solvent brake washing units
  3. Aqueous brake washing units

 

The best environmental practice is to use aqueous brake washing units.  Aqueous brake washing units use water-based cleaning solutions.  These solutions are nonflammable and generally less toxic than petroleum-based solvents. Furthermore, aqueous cleaners contain little or no volatile organic compounds (VOCs) that can harm the environment and shop employees.  Aqueous brake washing units are widely available and perform as well as solvent-based equipment; however, aqueous brake washers have the following advantages:

·         Little or no solvent vapors or aerosol mists that can be harmful to your workers’ health.

·         Nonflammable

·         Do not contribute to smog formation, climate change, or ozone depletion.

·         No empty aerosol cans discarded as bulky, non-biodegradable trash.

·         Reduces overall environmental and safety liabilities for the shop.

·         Can save you hundreds of dollars per year after payback period

 

Most aqueous brake washing units function much like sink-top parts cleaners.  Aqueous brake washers feature a portable basin that can be adjusted to fit under the wheel assembly.  Most technicians prefer units with adjustable sink height. Compressed air pumps the aqueous solution through a hose and a flow-though brush.  A filter is often used to collect debris and keep the solution clean.  Aqueous units range in cost from $500 to $1,200 to purchase, or $45 to $85 per month to lease (lease cost includes waste management).

 

Recycling

Spent soak tank solutions should be recycled or properly disposed of at a permitted hazardous waste disposal facility.

Many shops have cut down on the amount and toxicity of solvents they are using by turning to less-toxic alternatives.

 

There are a number of companies who provide on-site recycling equipment designed for the filtration or distillation of parts washing solutions.  You should also consider changing to water-based and/or biodegradable cleaners as substitutes for petroleum based solvents.  Check with your local trade association or your local or state regulatory agencies for information and phone numbers.

 

Waste Management

More efficient parts washing procedures can help eliminate waste.  Monitor the effectiveness of the parts washing solvent and do not change-out the solvent until it no longer will clean parts to the level expected.  Extend the life of your cleaning solution by using "dirty" solvent for pre-cleaning of dirty parts, before they are put into the main parts washer.  Minimize the number of parts washing stations in your shop.  Make sure your part washers are turned off and if they have lids, keep the lids closed when not in use.

 

Water-based parts cleaning solutions can also be dangerous because of their caustic properties.  Carburetor cleaners are corrosive liquids that contain chlorinated compounds.  Carburetor cleaner should be segregated from other wastes.  Waste carburetor cleaner should be accumulated separately for proper waste management in a suitable container or system.  Consider eliminating chlorinated carburetor cleaner and switching to a less hazardous, non-chlorinated cleaner.

 

Hazardous solvents should always be used only when no other cleaner is suitable for the job.  The major ways to avoid or reduce the generation of solvent waste include eliminating the need to use solvent; finding adequate substitutes for solvents; minimizing losses associated with solvent use; and to segregate, recycle, recover, and reuse waste solvents.

 

Terpene based cleaners are increasingly being used in place of Stoddard solvent.  The terpene cleaners are available commercially as water solutions with surfactants, emulsifiers, rust inhibitors, and other additives.  Terpenes have tested favorably as substitutes for halogenated solvents for removal of heavy greases and oily deposits.

 

Pre-cleaning parts with a wire brush, followed by steam cleaning, high-pressure wash, or hot bath that recycles an aqueous solution are efficient approaches for minimizing or eliminating the use of hazardous solvents.

 

Use halogenated solvents judiciously! Solvent should never be used for the general cleaning of shop floors, and should only be used in a well-maintained self-contained cleaning system.  When not in use, all solvent cleaning tanks must be covered and/or drain plugs closed.  Solvent can be wasted through equipment leaks, spills, poor application techniques and evaporation.

 

The cost for collection and/or the disposal of part cleaning solutions can be determined by making contact with service providers who reclaim, recondition and recycle solvents.

 

Because parts cleaning solutions are considered a hazardous material you may be subject to county Waste Generator fee and may need to update your Business Emergency Response Plan and Hazardous Communications Plan.

 

The recycling and disposal of part cleaning solutions require record keeping and reporting.  Generators that ship spent solvents for off-site treatment and disposal are required to fill out a hazardous waste manifest.  If you have questions, check with your local governing agency.

 

Minimize the costs and liabilities by switching to aqueous cleaners.  Aqueous cleaners are water-based solutions that, unlike petroleum-based solvents, are typically nonflammable and contain little or no VOCs.  Instead of dissolving grease and solids, aqueous cleaners rely on heat, agitation, and soap action to break dirt into smaller particles.  Although they clean differently, aqueous cleaners perform as well as solvents.  For this fact sheet, aqueous cleaners are defined as water-based cleaners that contain less than 5% (50 grams per liter) of VOCs.  Hundreds of aqueous cleaner formulations are commercially available.  The California South Coast Air Quality Management District maintains a list of aqueous solutions that are certified to contain less than 5% of VOCs; this list is available on the Internet at www.aqmd.gov/tao/cas/prolist.html. 

 

The cleaning equipment used is critical to successful aqueous cleaning because it applies two important mechanisms to the cleaning process: mechanical force and heat.  Two types of aqueous cleaning units that are applicable to most auto repair shops- sink-top and spray cabinets.  Most shops will likely meet all their cleaning needs by implementing both types of units.  Specialty shops that clean many transmissions and carburetors may also want to investigate using ultrasonic and immersion type units. 

 

Managing aqueous cleaning wastes

The wastes generated from aqueous cleaning should be managed as described in the following section.

 

Waste Solution. 

Aqueous cleaning solutions may qualify as hazardous waste after extended use because concentrations of metals such as cadmium, copper, lead, and zinc may exceed state or federal limits.  Therefore, auto repair shops should always use a licensed waste disposal company to manage waste solution.  Many waste disposal companies will analyze the waste solution for you to determine whether it is hazardous.  The cost of disposal will vary according to the characteristics of the waste and the volume generated, but will generally be $2 to $4 for a gallon if it is a hazardous waste and $1 to $2 for non-hazardous waste.  Unless you obtain permission from your local sewage treatment agency, do not dump waste solution in the sewer or septic system.

 

When purchased, aqueous brake washing solutions contain proprietary compounds that are either non-hazardous or considerably less hazardous than solvents.  With proper filtration and regular addition of fresh solution to make up for evaporative losses, many shops can go for years without requiring solution disposal.  Over time however, contaminants build up creating sludge and making the solution less effective.  Waste solution, sludge and filters may contain metals washed off the brake assembly, or solvents that mistakenly dripped into the sink and contaminated the solution.  Waste solution, sludge and filters should be shipped off-site as either hazardous or non-hazardous wastes.  Get data, or test the waste stream at least once to make this determination, and dispose of the waste solution and filters accordingly.  Some unit vendors will dispose of the spent solution for you and include the cost of this service in the unit’s rental price.  An informal survey of San Francisco Bay area shops revealed that aqueous solution is changed about once every 3 years, on average. 

 

Used filters. 

Used filters may be recycled along with spent engine oil filters with the permission of the recycler.  Contact your oil recycler to determine if they will take your filters.  Some recyclers will only accept used filters if they are encased in metal shells like engine oil filters, and some states prohibit recycling aqueous filters with engine oil filters.  If they are not recycled with engine oil filters, used filters should be managed as hazardous waste and disposed of by a licensed waste disposal company.  Contact your state environmental agency to learn if any special rules apply to used filters. 

 

Skimmed oil. 

Oil skimmed from an aqueous cleaning solution can be managed as used oil and recycled.  Most recyclers will accept skimmed oil with used motor oil as long as it is not contaminated with solvent.

 

Simple sludge management. 

Little or no sludge will accumulate in aqueous cleaning units with filtration, but units without filtration may accumulate sludge at the bottom.  This sludge may be disposed of along with waste solution.  Most waste disposal companies will accept a certain percentage of solids in the waste solution.  If the sludge is separated from the solution, the sludge may not be disposed of as solid waste unless tested to determine if it is non-hazardous.

 

Keeping aerosol products away from aqueous brake washers. 

If you use aerosol brake cleaners to spot clean or dry brakes after aqueous brake washing, be aware that many aerosol products contain F-listed chemicals.  An F-listed chemical is a chemical that makes each waste it contaminates a hazardous waste, no matter what its concentration in the waste is.  Even one drop of an F-listed aerosol solvent that drips into your brake washing solution is enough to make it a regulated hazardous waste!  If you must use aerosol products to spot clean, always move the aqueous brake-washing unit away from the brake area first.  To save time and avoid potential regulatory problems altogether, use compressed air to dry brakes rather than aerosol brake cleaner.