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final report
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Pollution Prevention
Assistance Tools for the Fiber Reinforced Plastics and
Boat Manufacturing Industries
Submitted to Minnesota Pollution Control Agency
Small Business Assistance Program,
December
21, 2001
Background The fiber reinforced plastics (FRP)
industry today is experiencing significant growth as
more products are made from reinforced plastic for
greater durability, strength, and life. Thousands of
products are now manufactured from reinforced plastics
including building materials, sporting equipment,
appliances, automotive/aircraft parts, boat and canoe
hulls, and bodies for recreational
vehicles.
Growth in the industry also poses environmental
and health concerns especially for shops that are not
willing or able to "change with the times" and upgrade
to new, more efficient technologies. Environmental and
health risks come from the styrene in the resin that is
released when the resin has contact with air, resulting
in employee exposure and VOC (styrene) releases to the
environment.
Employee exposure is now regulated by an
Occupational Safety and Health Administration (OSHA)
workplace airborne threshold limit value (TLV) of 50
parts per million (ppm) in many states including
Minnesota. Releases to air are regulated by the Clean
Air Act (CAA) National Emission Standards for Hazardous
Air Pollutants (NESHAP) for reinforced plastic
composites and boat manufacturing. Neither of these
standards can be met cost-effectively without
implementing pollution prevention methods and
technologies that reduce styrene emissions.
Styrene reduction strategies rely on minimizing
resin contact with air and can be achieved in a number
of different ways. These methods include maximizing
transfer of resin into the mold (operator training and
improved resin application techniques), reducing styrene
content in resins (low styrene resins), and curing
resins in a closed system (closed mold).
This
project demonstrated these methods and technologies to
FRP shops with an emphasis on open molders, assisted
with implementation or adoption by shops, documented
results from three shops with five different methods or
technologies, and transferred those results to other FRP
shops in the industry.
Review of Objective and
Scope of Work The
Minnesota Technical Assistance Program (MnTAP), in
partnership with the Minnesota Pollution Control Agency
(MPCA) Small Business Assistance Program (SBAP),
assisted fiberglass shops with implementation of
pollution prevention strategies that will help the
industry meet or go beyond regulatory thresholds for
compliance with OSHA and the CAA. As a result of this
outreach and assistance effort, the FRP industry has a
greater understanding of pollution prevention
opportunities for their shops and the benefits that
implementing pollution prevention can have on the
environment and their bottom line. Many shops have
implemented pollution prevention practices and
technologies and are benefiting from reduced styrene
emissions, reduced regulatory requirements, and cost
savings.
Project
Results Results from
this two-year project were achieved through a series of
activities including conducting outreach, providing
technical assistance (site visits and interns),
demonstrating technologies, documenting reductions and
cost savings as a result of pollution prevention
implemented, and technology transfer of
results.
These project activities are illustrated in the
pictorial below beginning with outreach and ending with
technology transfer of results, and are also discussed
in the following section.
| |
Outreach |
Phone
Contact |
Site Visits |
Student Interns |
Technology Demonstration |
Documented Results |
Technology Transfer |
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100 shops |
32 calls |
22 visits |
2 companies |
170 attendees |
4
case studies |
100 letters |
Outreach MnTAP
provided input to SBAP on a letter that went out
to 100 FRP shops promoting the project and the
opportunity for site visits. SBAP and MnTAP
conducted additional promotion throughout the
project using the Crosslink newsletter and
SOURCE newsletter, respectively.
Phone
Contact Over
the two-year project period, approximately 32
phone contacts were made with FRP shops discussing
pollution prevention technologies and
opportunities, lining up site visits, promoting
the loan/grant programs, interns, and Demo Days,
and addressing regulatory compliance
needs.
Site
Visits Outreach efforts and phone calls resulted
in 22 site visits conducted over the two years.
Site visits addressed issues ranging from
pollution prevention technology opportunities to
air permit questions. Potential student intern
projects were also identified as a result of site
visits.
Student
Interns Site
visits provided the opportunity to scope out
student intern projects for the summer period.
MnTAP supported two student interns during the
course of the project:
• |
Sellner Manufacturing, Faribault (2000):
Evaluated (but did not implement) non-atomized
spray equipment. |
• |
Fiberglas Fabricators, Le Center (2001):
Evaluated (implementation pending) use of
robotics and Laser
Touch. |
Technology Demonstrations – Demo
Days MnTAP
worked with SBAP to plan and hold a very
successful event on August 8, 2001, FRP Demo Days,
which combined seminars, resource booths, and
technology demonstrations. Over 170 people
attended the event, including 50% fiberglass
fabricators (representing 33 different shops), 22%
vendors, 14% consultants, and 14% business
assistance programs. Seminar topics ranged from
regulatory compliance to current technologies such
as VEC closed mold used at Larson-Glastron.
Technology demonstrations included Light RTM
closed mold and non-atomizing resin application
guns.
MnTAP’s primary roles with this event
included brochure development, vendor and attendee
registration, promoting the event to fiberglass
shops and vendors, assistance with program
development, and soliciting speakers and
participants for demonstrations.
This event helped fulfill one of MnTAP’s
strategic goals of technology diffusion which
involves actually showing and demonstrating
specific technologies to shop people. Hands on
demonstrations help prove that the technology can
work in a shop setting to improve efficiency,
reduce waste, and cut costs.
Description of Technology
Applications MnTAP
worked closely with three companies over the
two-year period on five technologies that resulted
in significant fiberglass process improvements.
The benefits included more efficient use of raw
materials, reduction of both styrene emissions and
cured resin solid waste, and cost savings from
less use of raw materials and less waste to
dispose of in landfills. The five technologies are
discussed briefly below:
Closed Mold—Light Resin Transfer
Molding (RTM) Light
RTM is a closed mold process that significantly
reduces styrene emissions, improves productivity
and quality, and optimizes material use. It is a
technique that allows the typical open molder an
opportunity to do closed molding with minimal
training and expense. Phoenix has demonstrated
that a large fraction of current open molded parts
can be done by conventional and Light RTM. In
fact, Phoenix has converted to 60% closed molding,
one-quarter of which is Light RTM. Activities
using closed mold have resulted in 80,000 pounds
fewer styrene emissions (20,000 pound reduction
using Light RTM) over the 2000 and 2001 production
years.
Controlled Spray – Laser
Touch® Laser
Touch® is a tool that can improve spray
technique, increasing the efficiency of material
use and reducing waste, assuming a thorough
controlled spray training program is in place.
Mounted on a spray gun, the Laser
Touch® unit has two laser beams that
converge into one beam when the gun is properly
positioned. Improved accuracy and consistency
ensures material placement, maximizing transfer
efficiency, and resulting in less waste produced.
Fiberglas Fabricators found that they could reduce
solid waste from open molding by nearly 28% if the
tool was used in conjunction with controlled spray
training. This translated to a potential savings
of $23,700 in materials and decrease in landfill
wastes of 20%.
Raw Material
Monitoring These
units are capable of giving the spray operator
real time information on materials added to the
mold during processing. With the help of the SBAP
loan program, Fiberglas Fabricators purchased
Technology for Manufacturer (TFM) raw material
monitoring equipment. Real time information
allowed Fiberglas Fabricators to reduce the
average "over weightage" of their parts, which has
reduced materials consumed by 20,000 pounds per
year. This saves them $10,000 and reduces styrene
emissions by 2,000 pounds per year due to less
resin consumed.
Non-Atomized Application—Magnum
Venus Fluid Impingement Technology
(FIT) FIT is
a non-atomized application method that can reduce
styrene emissions by 50% or more compared to
conventional equipment. The resin or gelcoat exits
the gun in two low-pressure streams which cross
each other, creating a fan pattern. The
application equipment can employ either internal
or external mix, and chopped glass can be mixed
into the fan pattern as it is applied. Coupled
with the use of low styrene resins, Sunrise
Fiberglass has reduced emissions by 16,000 pounds
per year, down 43 percent from 1999 levels of
36,000.
At Fiberglas Fabricators, FIT was
demonstrated to be effective in reducing styrene
emissions in gelcoating applications. Reduced
overspray led to a significant material savings of
5%, and styrene emissions during gelcoating were
reduced by 35% as a result of nonatomized
spray.
Low Styrene Resins
(LSR) Low
styrene resins contain 38% or less styrene on a
weight basis compared to conventional resins. The
LSR have a higher viscosity than conventional
resins (making roll out more difficult over
reinforcing material) and are more sensitive to
temperature fluctuations (requiring improved
temperature control). The cost of low-styrene
resins is comparable to conventional resins.
Composite Fabricators Association (CFA) developed
emissions factors that show a decrease in styrene
content from 42 to 38% will reduce styrene
emissions by 16% (just from resin change) when
non-atomized equipment is used.
Documented
Results The
table below summarizes results from the five
technology applications at the three
companies. |
Summary of
Case Study Results
Company |
Annual
Styrene
Reductions (lbs) |
Annual
Cost
Savings
($) |
Method
|
Fiberglas Fabricators LeCenter |
1,000
17.7
tons scrap
2,000
46,000
3,400 |
$23,700
2,600
10,000
2,000
3,000
|
Controlled Spray/Laser Touch®
(raw materials) Laser
Touch® (FRP solid waste)
Raw material monitors – less part to part
variance, material savings
Resin FIT (permit fee savings)
Gel coat FIT (material
savings) |
Sunrise Fiberglass Wyoming |
16,000
|
27,850 |
Fluid impingement technology and low
styrene resin (cost to comply) |
Phoenix* Crookston |
10,000
30,000
|
12,500
37,500
|
Light RTM closed molding (material savings
from over-spray elimination)
Conventional RTM closed molding
|
TOTAL |
108,400
pounds styrene 17.7
tons FRP scrap |
$
119,150 |
|
* Phoenix implemented this project on their
own, but several Demo Days attendees have
contacted Phoenix regarding the Light RTM demo,
and received good information.
|
Technology Transfer of
Results |
The
following case studies were developed and are
attached to this report: |
• |
Fiber
Reinforced Plastic Shop Complies with New Air
Permit Regulations |
• |
Phoenix Industries Implements Light RTM
to Produce Fiber Reinforced
Parts |
• |
Fiberglas Fabricators uses Loan Program
to Upgrade Open Mold Processing
Equipment |
• |
Controlled Spraying and Laser
Touch® in the Fiber Reinforced
Plastics Industry
|
Project results in case study format will
be disseminated to the fiberglass shops in January
2002 at the end of the project. A letter will be
sent to the shops with case studies enclosed,
promoting the technologies, the intern program and
available grant and loan programs. Phone follow-up
to promote technical assistance and site visits
will wrap up the effort.
Discussion More
efficient manufacturing technologies will
naturally result in environmental improvements in
any industry sector. Installation of new, more
efficient technologies in the fiber reinforced
plastics industry significantly reduced styrene
emissions and cut costs for most of the shops
MnTAP worked with. Cost savings resulted from more
efficient use of material, reduced fees associated
with pollutants released to the environment, less
FRP solid waste going to the landfill, and
productivity and quality enhancements to the
manufacturing process.
Installation of the five technologies in
three fiberglass shops resulted in a reduction of
108,400 pounds of styrene emissions and 17.7 tons
of landfill waste, and a cost savings of $119,150.
Additional reductions and cost savings can be
expected if these technologies are implemented at
other sites.
Estimating 100 open mold fiberglass shops
in Minnesota, if these technologies were
implemented to varying degrees, the potential for
additional styrene reductions and cost savings
would be great. The Minnesota FRP industry
consumes 56 million pounds of raw materials
annually. The average resin content in the
laminate is 35%, with an average styrene content
of 42%. The typical industry scrap rate is 15% of
purchased raw materials. An estimated 3.1 million
pounds of styrene is emitted from the FRP industry
each year. |
Potential FRP
Industry Implementation of Demonstrated Pollution
Prevention Technologies
|
50%
Implementation |
100%
Implementation |
|
Reductions (lbs)
|
Cost
Savings ($) |
Reductions (lbs) |
Cost
Savings ($) |
Notes |
Light RTM
Styrene Raw
Material |
1,150,000 1,700,000
|
850,000
|
2,300,000 3,400,000 |
1,700,000
|
Material savings
|
Controlled Spray
Styrene Raw
Material |
75,500 1,260,000 |
2,000 630,000 65,000
|
151,000 2,520,000 |
4,000 1,260,000 130,000 |
Fee savings Material savings Avoided
landfill costs |
Raw Material Monitor
Styrene Raw
Material |
30,000 600,000 |
300,000
|
60,000 1,200,000 |
600,000
|
Lower resin consumption 2% reduction in
materials applied |
Non Atomized Resin/ Gelcoat
Styrene Raw
Material |
650,000 825,000 |
16,500 650,000 |
1,300,000 1,650,000 |
33,000 1,300,000 |
50% reduction; fee savings Material savings |
Low Styrene Resin
Styrene |
405,000 |
10,000 |
810,000 |
20,000 |
Moved from 42% to 38% styrene content in
resin |
Note: |
These columns cannot be summed up to get a
total reduction or cost savings because
technologies are implemented
independently. |
Assumption: |
Production stays at current levels.
|
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Mike
Smith, a Master’s student at Minnesota State University,
is doing thesis work that will help MnTAP understand how
much pollution prevention has penetrated the FRP
industry in Minnesota. His focus is on TRI reporters,
and he will adjust annual emissions covering the period
of 1993 to 2000 with the corrections made in emission
factors to show an accurate history of styrene
emissions. The hypothesis is that pollution prevention
implemented over the last 8 years is resulting in a
reduction of "real" styrene emissions from FRP shops due
to the many improvements made in the industry.
Information developed from this project will be
used to continue to "diffuse" these high potential
technologies into fiberglass shops. The first step will
be through a letter at the end of this project to
disseminate the case studies to FRP shops all over the
state. Additional steps could involve loaning out
equipment from vendors or MnTAP, conducting tours
through shops that have installed the equipment, and
using vendors to set up pilots or demos at various shop
sites.
Conclusion This two-year project
achieved its objective of promoting and implementing
pollution prevention practices and technologies as a
means to reduce styrene and comply with the CAA NESHAP.
Both OSHA and CAA regulations served as drivers or
motivators for companies to consider changing from
conventional methods to styrene-reducing technologies.
Throughout the project, regular and ongoing outreach
kept SBAP and MnTAP exposure high with FRP shops. The
FRP Demo Days was successful in bringing shops together
at a central location to demonstrate new and available
technologies that increase efficiency, reduce waste, and
save companies money. The project has gone far to raise
awareness of new technologies for companies to
implement.
Next
steps will involve assisting smaller fiberglass shops
who can benefit from implementation of these
technologies and reduced costs, better use of raw
materials, improved employee health, and reduced impact
on the environment.
Appendix
A Assessing
Worker Exposure to Styrene in the Reinforced Fiber
Plastics Industry From Limited Personal and Area
Sampling By Pam Russell and Claudiu Lungu, Division
of Environmental and Occupational Health, School of
Public Health
During
2000-2001, MnTAP supported an industrial hygiene
student from the University of Minnesota to
conduct sampling at a fiberglass shop with three
goals in mind: |
1. |
Develop
a generic protocol for sampling styrene in FRP
shops. |
2. |
Apply
the protocol to companies implementing pollution
prevention for before/after measures. |
3. |
Develop
a test model to estimate reduction in employee
exposure and emissions reduction as a function of
technology change. If a model existed, area
sampling for a plant could be performed to
demonstrate to the company the potential exposure
and emission reductions that could be achieved if
they implemented pollution prevention
technologies. |
On
three occasions field sampling was performed at
the fiberglass shop. The facility recently
installed fluid impingement technology (FIT) and
LSR for fiberglass application at its new
facility. Direct and passive measurement
techniques were employed to obtain short-term
exposure levels for a variety of employees working
at different operations: |
• |
direct
reading (flame/photoionization
detector) |
• |
charcoal tubes (personal sampling
pumps) |
• |
3M
organic vapor monitor (passive
personal) |
Data
collected by the student to date provides the
following observations: |
• |
Employee exposure: The 8-hour time weighted
averages for styrene were all below the federal
OSHA Permissible Exposure Limit (PEL) of 100 ppm
and some were below the Minnesota voluntary Short
Term Exposure Limit (STEL) of 50 ppm. The findings
indicated that an approved respirator program was
still required. |
• |
Impact
of pollution prevention technology: In the old
building styrene levels at the laminator were
measured at 58 ppm for 8-hour samples. In the new
building with installation of fluid impingement
technology styrene levels at the laminator were
measured at 25 ppm, a reduction of 57% (note: the
old building had different ventilation
rates). |
• |
Operator practices: Operator practices play
a huge role in their own styrene exposures.
Workers that operated spray guns or hand rolled
had greater exposures regardless of work
practices. Closer supervision, training and
improved best practices would help reduce styrene
exposure and emissions. The best pollution
prevention technologies do not eliminate the
potential for high styrene exposure to some
employees, rather operator’s position during
molding plays a more significant role in exposure
level. |
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