Carver-Greenfield Process® Schematic Diagram
DEHYDRO-TECH CORPORATION
(Carver-Greenfield Process® for Solvent Extraction of Wet, Oily Wastes)
TECHNOLOGY DESCRIPTION:
The Carver-Greenfield Process® (C-G ProcessÔ) combines dehydration and solvent extraction technologies to separate wet, oily wastes into their constituent solid, water, and oil phases.
Waste is first mixed with a low cost hydro-carbon solvent. The resultant slurry mixture is fed to an evaporator system that vaporizes water and initiates solvent extraction of the indigenous oil. Depending on the water content of the feed, single-effect or energy-saving multi-effect evaporators may be used. Next the slurry of dried solids is treated in a multistage solvent extraction unit, where solids contact recycled solvent until the target amount of indigenous oil is removed.
Finally, solids are centrifuged away from the solvent, followed by "desolventizing," an operation that evaporates residual solvent. The final solids product typically contains less than 2 percent water and less than 1 percent solvent. The spent solvent, which contains the extracted indigenous oil, is distilled to separate the solvent for reuse, and the oil for recovery or disposal.
The C-G Process yields (1) a clean dry solid; (2) a water product virtually free of solids, indigenous oil, and solvent; and (3) the extracted indigenous oil which contains the hazardous hydrocarbon-soluble feed components.
The C-G Process combination of dehydration and solvent extraction has the following advantages: (1) any emulsions initially present are broken and potential emulsion formation is prevented; (2) solvent extraction is more efficient when water is not present; and (3) the dry solids product is stabilized more readily if required (for example, if metals contamination is a concern).
WASTE APPLICABILITY:
The C-G Process can treat sludges, soils, sediments, and other water-bearing wastes containing hydrocarbon-soluble hazardous compounds, including polychlorinated biphenyls, polynuclear aromatic hydrocarbons, and dioxins. The process has been commercially applied to municipal wastewater sludge, paper mill sludge, rendering waste, pharmaceutical plant sludge, and other wastes.
STATUS:
The C-G Process was accepted into the SITE program in 1990. The pilot-scale SITE demonstration of this technology was completed in August 1991 at EPA's research facility in Edison, New Jersey. Spent petroleum drilling fluids from the PAB oil site in Abbeville, Louisiana were used as process feed. The Applications Analysis Report (EPA/540/AR-92/002), Technology Demonstration Summary (EPA/540/SR-92/002), and Technology Evaluation Report (EPA/540/SR-92/002) are available from EPA.
DEMONSTRATION RESULTS:
The SITE demonstration of the C-G Process yielded the following SITE demonstration results:
· The process successfully separated the petroleum-oil contaminated sludge into its solid, indigenous oil, and water phases. No detectable levels of indigenous total petroleum hydrocarbons were present in the final solid product.
·The final solid product was a dry powder similar to bentonite. A food-grade solvent comprised the bulk of the residual hydrocarbons on the solid.
·Values for all metals and organics were well below the Resource Conservation and Recovery Act toxicity characteristic leaching procedure limits for character-istic hazardous wastes.
·The resulting water product required treatment due to the presence of small amounts of light organics and solvent. Normally, it may be disposed of at a local publicly owned treatment works.
·A full-scale C-G Process can treat drilling fluid wastes at technology-specific costs of $100 to $220 per ton of wet feed, exclusive of disposal costs for the residuals. Site-specific costs, which include the cost of residual disposal, depend on site characteristics and treatment objectives.
FOR FURTHER INFORMATION:
EPA PROJECT MANAGER:
Laurel Staley
U.S. EPA
National Risk Management Research
Laboratory
26 West Martin Luther King Drive
Cincinnati, OH 45268
513-569-7863
Fax: 513-569-7620
TECHNOLOGY DEVELOPER CONTACT:
Theodore Trowbridge
Dehydro-Tech Corporation
6 Great Meadow Lane
East Hanover, NJ 07936
201-887-2182
Fax: 201-887-2548