TECHNOLOGY ALTERNATIVES FOR DYES AND DYE INTERMEDIARY INDUSTRY IN INDIA
 
DYES AND DYE INTERMEDIARY INDUSTRY 

Dyes and Dye Intermediates industry is an important sector of the Indian Chemical Industry. This sector has grown at a very fast pace after independence and nearly half of its production is being exported today. A remarkable feature of the Indian dyestuff industry is the co-existence of units in the small, medium and large sectors, actively involved in the manufacture of dyestuffs and their intermediates. The pollution that accompanies this industry in its nature and extents, particularly, because of the non-biodegradable nature of the dyes as well as due to the presence of acid/alkali/toxic metals/carcinogenic aromatic amines in the effluents. In addition to effluent, gaseous emissions such as SO2, Nox, NH3 & HCI and solid wastes in the form of iron sludge, gypsum and sludge from treatment facilities are generated. 

The available pollution control systems and the requirements are tabulated below : 
 

Technologies/Current Practices
Requirements
Effluent treatment comprising primary (physico-chemical) and secondary (biological) systems are in practice. Some of the units have also provided tertiary treatment and incinerators for non biodegradable waste. Possibilities for adaptation of cleaner process options for reducing the water consumption and effluent generation; better management practices for segregation and reuse/recycle of the treated effluent; effective utilisation of raw materials; improvement in efficiency of process; and recovery of by-products. 

The effluent generated from manufacturing of some of the dyes and intermediates such as H-acid is not biodegradable, which requires process change.

Gaseous emissions such as SOx, NOx, HCI and NH3 are generally scrubbed. Properly designed scrubber with recovery reuse of scrubbed liquid is required.
Gypsum, iron sludge and sludge from ETP are generated as solid waste. The gypsum and iron sludge can be used in the cement and pigment industries. The sludge is either disposed off on land/secured landfill or sent to other user industries. Cleaner process technologies e.g. catalytic hydrogenation, use of spent acid after nitration for acidification of fusion mass, which can eliminate generation of iron and gypsum sludge.

SOURCE : CENTRAL POLLUTION CONTROL BOARD  
DATE: 28TH NOVEMBER, 2000  

KEYWORDS: 

TECHNOLOGY ALTERNATIVES, ALTERNATIVE TECHNOLOGIES, BEST PRACTICES, INDIAN INDUSTRY, TECHNOLOGY TIPS, POLLUTION CONTROL, CENTRAL POLLUTION CONTROL BOARD, CPCB, TECHNOLOGY OPTIONS, DYES AND DYE INTERMEDIARY INDUSTRY, DYES AND DYE INTERMEDIARY