POWDERED ACTIVATED CARBON WASTEWATER TREATMENT

Revision Date: 10/01
Process Code: Navy/Marines: SR-15-99; Air Force: FA09; Army: N/A
Usage: Navy: Medium; Marines: Low; Army: Medium; Air Force: Medium
Compliance Impact: Low
Alternative for: N/A
Applicable EPCRA Targeted Constituents: Trichloroethylene (CAS: 25323-89-1), Tetrachloroethylene (CAS: 127-18-4), Chlorinated Solvents, Pesticides, Polychlorinated Biphenyls (CAS: 1336-36-3), Phenolic Compounds, Fuel Hydrocarbons, Organics

Overview: The powdereded activated carbon wastewater treatment system combines biological treatment (such as the activated sludge process) with adsorption on powdereded activated carbon (PAC). The technology removes organic contaminants from wastewater and minimizes the inhibitory effects of process wastewater containing toxic organic compounds. Mobile powdereded activated carbon wastewater treatment systems can be furnished as continuous flow or batch treatment systems. Continuous flow systems come mounted on a mobile trailer, with treatment capacities from 2,500 to 10,000 gallons per day. Batch operated or continuous flow package plants can be provided for flows to 100,000 gal/d. In-ground systems of up to 53,000,000 gal/day are currently in operation.

Typically, living microorganisms (biomass) and PAC contact wastewaters in an aeration basin (anaerobic systems are also available). Biomass removes biodegradable organic contaminants through biological assimilation, while the carbon physically adsorbs conventional and toxic organics.

The degree of removal achieved by the system depends on the influent waste characteristics and the system's operating parameters. Important considerations are biodegradability, absorbability, and concentrations of toxic inorganic compounds, such as heavy metals.

Powdereded activated carbon wastewater treatment systems can be adjusted to specific waste stream feeds by varying the concentration of the PAC in the system, adjusting the retention time of the mixed liquor, and adjusting the waste-to-biomass ratio. If necessary, the temperature and the pH of the incoming waste can be adjusted, and nutrients can be added.

After the aeration cycle, solids (PAC, with adsorbed organics, biomass, and inert solids) are removed through settling. The removed solids are mostly returned to the aeration tank, with only excess solids being removed. Solids may be regenerated to recover PAC, or may be dewatered and disposed.

A two-stage powdereded activated carbon wastewater treatment system may be applied where environmental standards require an even higher degree of treatment. In the first stage aeration basin, a high level of biomass and PAC removes most contaminants. The second stage aeration basin polishes the first stage effluent. The virgin PAC, added just before the second stage, and the counter flow of solids to the first stage increases process efficiency. Excess solids are removed from the first stage and treated as described above.


Compliance Benefit: The use of a powdereded activated carbon wastewater treatment system can help facilities meet pretreatment standards for discharges of wastewater to a POTW (40 CFR 403) or meet effluent limits of a NPDES permit (40 CFR 122). In addition, this treatment process may help facilities meet the requirements of waste reduction under RCRA, 40 CFR 262, Appendix. Wastewater treatment units that are covered under a NPDES permit or provide for pretreatment prior to discharge into a POTW may not need to comply with requirements for a hazardous waste treatment permit.

The compliance benefits listed here are only meant to be used as a general guideline and are not meant to be strictly interpreted. Actual compliance benefits will vary depending on the factors involved, e.g. the amount of workload involved.


Materials Compatibility:
No materials compatibility issues were identified.


Safety and Health: Care should be taken when handling wastewater polluted with organic substances. They have a high order of dermal toxicity. Proper personal protection equipment is, therefore, highly recommended.

Consult your local industrial health specialist, your local health and safety personnel, and the appropriate MSDS prior to implementing any of these technologies.


Benefits: A powdereded activated carbon wastewater treatment system has been applied for:
  • Pretreatment and end-of-pipe treatment of industrial process wastewaters
  • Combined industrial/municipal wastewaters
  • Contaminated surface runoff and groundwater
  • Landfill leachates

The technology can be very useful at Naval installations that have a combined industrial and municipal collection system.

powdered activated carbon wastewater treatment systems can treat liquid wastes with a chemical oxygen demand (COD) in excess of 60,000 parts per million (ppm), including toxic volatile organic compounds in excess of 1,000 ppm. Treatability studies have shown that the system can reduce the concentration of specific toxic organic chemicals to below the detection limit.

Other benefits of the system include:

  • Stability in the face of shock loadings
  • Color and ammonia removal
  • Improved sludge settleability
  • The process can be retrofitted into an existing activated sludge system at minimal cost


Disadvantages:
  • High capital cost
  • High operating cost


Economic Analysis: The capital and operating costs of a powdered activated carbon wastewater treatment system depends on the influent quality and the effluent standards. The budget level capital cost estimate for a mobile powdered activated carbon wastewater treatment system ranges from $100,000 to $300,000. The operational costs range from less than $0.50 to greater than $1.00 per 1,000 gallons, depending upon a number of variables. Costs of wastewater treatment vary from one location to another. Factors determining the wastewater treatment costs are: the treatment technology used, the flow rate, and the level and type of contamination. Each Naval activity will have to examine the cost effectiveness of the treatment technology needed before selecting the appropriate treatment system.


Approving Authority: Approval is controlled locally and should be implemented only after engineering approval has been granted. Major claimant approval is not required.


NSN/MSDS:
Product NSN Unit Size Cost MSDS*
None Identified     $  


*There are multiple MSDSs for most NSNs.
The MSDS (if shown above) is only meant to serve as an example.


Points of Contact: Navy:
Mr. Charles Sokol
Environmental Engineer, ESC 423
Naval Facilities Engineering Service Center
1100 23rd Avenue
Port Hueneme, CA 93043
Phone: (805) 982-5318
DSN: 551-5318
FAX: (805) 982-4832
Email: sokolcw@nfesc.navy.mil


Vendors: This is not meant to be a complete list, as there are other manufacturers of this type of equipment.

US Filter, Zimpro Division, Inc.
301 W. Military Road
Rothschild,  WI   54474
Phone: (715) 359-7211
or (800) 826-1476
FAX:  (715) 355-3335
URL:  http://www.zimpro.com/


Sources: None listed


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