PRECIPITATION AND MICROFILTRATION WASTEWATER TREATMENT SYSTEMS

Revision Date: 9/01
Process Code: Navy/Marines: N/A; Air Force: N/A; Army: N/A
Usage: Navy: Medium; Marines: Medium;
Army: Medium; Air Force: Medium
Compliance Impact: Low
Alternative for: N/A
Applicable EPCRA Targeted Constituents: Heavy Metals

Overview: The precipitation and microfiltration process uses a combination of treatments on a variety of wastes. Chemical precipitation of heavy metals is the first treatment in this process. Precipitates and all particles larger than 0.1 to 0.2 micron size are filtered through a unique tubular fabric crossflow microfilter. Concentrate is dewatered using conventional processes, such as filter press or centrifuge.

Microfiltration modules are fabricated from a tubular woven polyester material. Wastes pumped into these polyester tubes form a dynamic membrane that produces a high quality filtrate and removes all particles larger than 0.1 to 0.2 micron. Turbulence continually maintains the membrane and maximizes treatment efficiency.

Metals are removed via precipitation by adjusting the pH in a reaction tank. Metal hydroxides or oxides form a dynamic membrane with other suspended solids. The concentrate, which contains up to 50 percent solids by volume, is periodically discharged to solids concentration and drying systems (filter press, centrifuge, or sludge thickener). Water from solids concentration is recycled to the feed tank.

Constituents are removed using seeded slurry methods in the microfilter. Hardness can be removed through traditional precipitation reactions. Oil and grease can be removed by adding adsorbents. Organics and solvents can be removed using activated carbon, bone char, or powdered ion exchange resins as adsorbents.

Commercial applications include removal of heavy metals from semiconductor and components manufacturing, oil and grease removal from industrial laundry effluent, and silica removal through water softening reactions from reverse osmosis concentrate.


Compliance Benefit: The use of precipitation and microfiltration treatment system can help facilities meet pretreatment standards for discharges of wastewater to a POTW (40 CFR 403) or meet effluent limits of a NPDES permit (40 CFR 122). In addition, this treatment process may help facilities meet the requirements of waste reduction under RCRA, 40 CFR 262, Appendix.

The compliance benefits listed here are only meant to be used as a general guideline and are not meant to be strictly interpreted. Actual compliance benefits will vary depending on the factors involved, e.g. the amount of workload involved.


Materials Compatibility:
The polyester membrane support cloth is suitable for use in all conditions except high concentrations of caustic at elevated temperatures. All other system components are either plastic (PVC, polyethylene, or fiberglass) or type 316 stainless steel.


Safety and Health: Care should be taken when handling wastewater contaminated with heavy metals. They can be poisonous, and skin absorption is the major route. Proper personal protection equipment is, therefore, highly recommended.

Consult your local Industrial Health specialist, your local health and safety personnel, and the appropriate MSDS prior to implementing any of these technologies.


Benefits:
  • Modular construction allows flow rates from a few gallons per minute to virtually any capacity required .
  • Can treat any contaminant which can be converted to solid form either through precipitation or through adsorption on any of a variety of adsorbents.


Disadvantages:
  • High capital cost.
  • High operating cost.


Economic Analysis: The capital cost of the precipitation, microfiltration, and sludge dewatering treatment process will vary, depending on the particular removal challenge presented. A typical capital cost is approximately $1.00 to $2.00 per gallon per day of capacity. For example, the capital cost of a system to treat a wastewater flow of 100,000 gallons per day would be between $100,000 and $200,000. Operating costs consist of normal mechanical maintenance, neutralization chemicals, and adsorbents. Typical operating costs are in the range of $1.00 to $2.50 per 1,000 gallons.


Approving Authority: Approval is controlled locally and should be implemented only after engineering approval has been granted. Major claimant approval is not required.


NSN/MSDS:
Product NSN Unit Size Cost MSDS*
None Identified     $  


*There are multiple MSDSs for most NSNs.
The MSDS (if shown above) is only meant to serve as an example.


Points of Contact: Army:
Ms. Tracy Williams
Pollution Prevention Coordinator
Department of the Army, Anniston Army Depot
7 Frankford Avenue
Anniston, AL  36201-4199
Phone: (256) 235-7947
FAX: (256) 235-7726
Email:  williamst@anad.army.mil


Vendors: This is not meant to be a complete list as, there are other manufacturers of this type of equipment.

EPOC, Inc.
3065 N. Sunnyside
Fresno,  CA   93727
Phone: (209) 291-8144 
FAX: (209) 291-4926
Contact: Mr. Rodney Squires


Sources: None listed



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