BIOLOGICAL AQUEOUS WASTEWATER TREATMENT SYSTEM

Revision Date: 11/01
Process Code: Navy/Marines: SR-15-99; Air Force: FA09; Army: N/A
Usage: Navy: Medium; Marines: Medium; Army: Medium; Air Force: Low
Compliance Impact: High
Alternative for: Activated Carbon, Chemical Oxidation, UV/Ozone, UV/Peroxide, Air Stripping
Applicable EPCRA Targeted Constituents: Pentachlorophenol (CAS: 87-86-5), Creosote (CAS: 8001-58-9), Petroleum Fuels, Benzene (CAS: 71-43-2), Toluene (CAS: 108-88-3), Xylene (CAS: 1330-20-7), Ketones, Alcohols

Overview: Biological aqueous treatment systems use naturally occurring microbes to process contaminated wastewater; however, where highly toxic or recalcitrant target compounds are present, innocuous, microbial amendments are introduced. The systems use aeration and biological processes to break down contaminants before wastewater is released to a publicly owned treatment works (POTWs). Biological aqueous wastewater treatment systems can be continuous flow systems or sequencing batch reactors.

Contaminated process wastewaters flow to a mix tank where the pH is adjusted and inorganic nutrients are added. If necessary, the water is heated to an optimum temperature using both a heater and a heat exchanger to minimize energy costs. The heated water flows to a bioreactor where the contaminants are biodegraded. The degrading microorganisms may then immobilized in a multiple-cell, submerged, fixed-film bioreactor. In this process, each cell is filled with a structured packing material, where the microbes adhere. For aerobic conditions, fine bubble membrane diffusers mounted at the bottom of each cell supply air.

As water flows through the bioreactor, contaminants are degraded to biological end products, predominantly carbon dioxide and water. The resulting effluent may be discharged to a POTW or may be reused on site.

This technology can be applied to a wide variety of wastewaters. Contaminants amenable to treatment include pentachlorophenol, creosote components, gasoline and fuel oil components, chlorinated hydrocarbons, ketones, alcohols, phenolics, and solvents. Other potential target waste streams include coal tar residues and organic pesticides. The system has been used successfully at forty different locations.

Approximately ten years ago, a Pilot Unit of a BioAccelerator, which is a specific system developed by BioTrol, was tested at the MacGillis and Gibbs Superfund Site in New Brighton, Minnesota. The closed, fixed-film system was operated continuously for six weeks at three different flow rates. This demonstration project showed the following:

  • Reduced pentachlorophenol concentrations from 45 to 1 ppm in a single pass
  • Achieved 96 to 99 percent removal of pentachlorophenol
  • Produced minimal sludge and no air emissions of pentachlorophenol
  • Mineralized chlorinated phenolics
  • Eliminated biotoxicity in the wastestream
  • Required minimal operator attention


Compliance Benefit: The use of a biological aqueous wastewater treatment system can help facilities meet pretreatment standards for discharges of wastewater into a POTW (40 CFR 403). In addition, this treatment process may help facilities meet the requirements of waste reduction under RCRA, 40 CFR 262, Appendix. Wastewater treatment units that are covered under a NPDES permit or provide for pretreatment prior to discharge into a POTW may not need to comply with requirements for a hazardous waste treatment permit.

The compliance benefits listed here are only meant to be used as a general guideline and are not meant to be strictly interpreted. Actual compliance benefits will vary depending on the factors involved, e.g. the amount of workload involved.


Materials Compatibility:
No materials compatibility issues were identified.


Safety and Health: The technology itself poses no safety or health risks. However, several contaminants treated using the system are dangerous. Pesticides and herbicides must be handled with care. Skin adsorption can be a concern when handling wastewater contaminated with these chemicals. Pentachlorophenol is an experimental teratogen and carcinogen. It is also poisonous when inhaled and causes dermatitis. Proper personal protective equipment is, therefore, recommended.

Consult your local industrial health specialist, your local health and safety personnel, and the appropriate MSDS prior to implementing this technology.


Benefits:
  • Capable of reducing concentrations of many organic wastewaters.
  • Produces minimal sludge and air emissions.
  • Eliminates biotoxicity in the wastestream.
  • Requires minimal operator attention.


Disadvantages:
  • Technology is not applicable for non-biodegradable contaminants, such as DDT, PCBs, dioxins, and heavy metals.


Economic Analysis: The capital cost for this technology depends on the flow rate. Typical capital costs are $15,000 for a 1 to 2 gallons per minute unit and $150,000for a 100 gallon per minute unit. Operating costs are approximately $0.75 per 1,000 gallons for a 5-gallon per minute unit and $0.40 per 1,000 gallons for a 30-gallon per minute unit.

Factors determining costs of treatment are the technology used, the flow rate, and the level and type of contamination. Each user must examine the cost effectiveness of the technology needed before selecting the system.

The assumptions on which the BioAccelerator figures are based are as follows:

Assumptions:

  • Cost comparison is based on the treatment of groundwater contaminated with 30 ppm BTEX
  • Electrical needs = 12 hp at $0.06/kW
  • Nutrients = 1.14 gpd at $1/gallon + delivery
  • Labor = 5 hours/week at $20/hour

Cost Comparison of Air Stripping/Activated Carbon, UV/Peroxide, and the BioAccelerator

Cost Air Stripping/Activated Carbon UV/Peroxide BioAccelerator
Capital: $110,000 $180,000 $150,000
Installation & Start-up: $18,000 $24,000 $20,000
Utilities/yr: $6,000 $22,500 $3,000
Carbon/yr: $87,000 $0 $0
Lamp/yr: $0 $5,000 $0
Chemicals/yr: $750 $10,000 $600
Labor/yr: $5,500 $12,000 $5,200
Depreciation/yr: $10,800 $14,400 $12,500
O&M Total/yr: $110,050 $59,400 $21,300
Cost/1000 gal. $2.79 $1.62 $0.52

Economic Analysis Summary:

    Annual Savings: $88,750 vs. air stripping/activated carbon system
    $38,100 vs. UV/peroxide system
    Capital Costs: $150,000
    Payback Periods: 1.7 years vs. air stripping/activated carbon system
    4 years vs. UV/peroxide system

    Click Here to view an Active Spreadsheet for this Economic Analysis and Enter Your Own Values. To return from the Active Spreadsheet, click the reverse arrow in the Tool Bar.


Approving Authority: Approval is controlled locally and should be implemented only after engineering approval has been granted. Major claimant approval is not required.


NSN/MSDS:
Product NSN Unit Size Cost MSDS*
None Identified     $  


*There are multiple MSDSs for most NSNs.
The MSDS (if shown above) is only meant to serve as an example.

 

Points of Contact: Civilian:
Mr. Nick Simard, Plant Manager
IT Group
Altamont Landfill Gas Plant
10840 Altamont Pass Road
Livermore, CA 94550
Phone: (925) 443-0593
FAX: (925) 443-2518

EPA:
Vince Scolarto
US EPA (MS-481)
Risk Reduction Engineering Laboratory
26 West Martin Luther King Drive
Cincinnati, OH 45268
Phone: (513) 569-7176
FAX: (513) 569-7620

 

Vendors: This is not meant to be a complete list, as there are other manufacturers of this type of equipment.

AquaTec, Inc.
1235 Shappert Drive
Rockford,  IL   61115
Phone: (800) 654-1505 
FAX: (815) 654-0038
URL: http://www.aquatecinc.com/

Aqua-Aerobic Systems, Inc.
6306 N. Alpine Road
Rockford,  IL   61111
Phone: (815) 654-2501 
FAX: (815) 654-2508
URL: http://www.aqua-aerobic.com/

 

Sources: Mr. John Fernandez, International Technology Corporation, April 1999.



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