PAINT STRIPPING USING WHEAT STARCH BLASTING

Revision Date: 11/01
Process Code: Navy/Marines: ID-01-06; Air Force: ST01; Army: DPT
Usage: Navy: Low; Marines: Low; Army: Low; Air Force: Low
Compliance Impact: Medium
Alternative for: Chemical Paint Stripping
Applicable EPCRA Targeted Constituents: Toluene (CAS: 108-88-3), Xylene (CAS: 1330-20-7), Methyl Ethyl Ketone (CAS: 78-93-3), Acetone (CAS: 67-64-1), N-Butyl Alcohol (CAS: 71-36-3), Lead (CAS: 7439-92-1), Chromium (CAS: 7440-47-3), Zinc Compounds, Phenol (CAS: 108-95-2), Chloroacetic Acid (CAS: 79-11-8), Dichloromethane (CAS: 75-09-2)

Overview: Wheat starch blasting is a user-friendly blasting process available as a fully developed stand-alone system specifically designed for wheat starch blasting, or as a process that can be adapted for use in systems designed for plastic media blasting (PMB). The abrasive media is a crystallized form of wheat starch that is non-toxic, biodegradable, and made from renewable resources. The abrasive blast media is similar in appearance to plastic media, except that it is softer.

The wheat starch blasting process propels the media at less than a 35-psi nozzle pressure for most applications. The low pressure and relatively soft media have minimal effect on the surfaces beneath the paint. For this reason, wheat starch is well suited for stripping paints without risking damage to the substrate. Examples include removing paint from aluminum alloys and composites like graphite, fiberglass, and aramid (Kevlar™).

The wheat starch blasting process can remove a variety of coatings. Coating types range from resilient rain-erosion resistant coatings found on radomes and radar absorbing materials, to the tough polyurethane and epoxy paint systems. The wheat starch blast process has also been shown to be effective in removing vinyl coatings, sealants, and bonding adhesive flash while leaving the metal-to-metal bond primer intact. It has also been found effective in removing the paint from the cadmium-plated parts, while leaving the plating intact.

There are several process-specific requirements for wheat starch blasting systems. For instance, a moisture control system is needed to control the storage conditions of the medium. This is especially important when the system is shut down for an extended period of time, as moisture can severely affect the performance of the abrasive blast media. Another concern is the removal of blast contaminants from the wheat starch media. Low levels of dense particle contamination in the media may result in a rough surface finish on delicate substrates. To avoid this situation, spent wheat starch residue is dissolved in water and then either filtered or separated in a dense particle separator/centrifuge. The wheat starch media is recycled in the system and may be used for up to 15 to 20 cycles. The waste stream generated by wheat starch blasting is sludge from the recycling system. This system produces approximately 85% less waste sludge compared to chemical stripping.


Compliance Benefit:

Use of wheat starch blasting as a replacement for chemical paint strippers results in the following compliance benefits:

  • Elimination of volatile organic compounds (VOCs) used as strippers that are associated with the formation of smog typically regulated by state and local air pollution control districts.
  • Elimination of hazardous air pollutants (HAPs) in strippers that are regulated by federal, state, and local regulations including the National Emissions Standards Hazardous Air Pollutants (40 CFR 63).
  • Elimination of all SARA Title III reporting substances from coating process (by the Navy) (40 CFR 355, 370, and 372; and EO 12856).
  • Reduced volumes of organic wastes, which must be managed as hazardous waste under 40 CFR 260 and related sections.
  • Reduced occupational exposures that are regulated under 29 CFR 1910.

Compliance benefits include: 1) elimination of recordkeeping and reporting requirements under the Title V, NESHAP Program and SARA programs, 2) reduce administrative burden associated with hazardous waste (i.e., tracking, plans, reports, training), and 3) reduced administrative burden associated with OSHA (i.e., training and recordkeeping).

The compliance benefits listed here are only meant to be used as a general guideline and are not meant to be strictly interpreted. Actual compliance benefits will vary depending on the factors involved, e.g. the amount of workload involved.


Materials
Compatibility:


Wheat starch blasting can be used on metal and composite surfaces. Direct contact of wheat starch with water must be avoided to maintain the integrity of the blast media. Wheat starch blasting requires explosion protection. If conditions are right, a static electrical charge developed by a high velocity wheat starch particle in air could effectively ignite the material. Preventive measures must be taken.


Safety and Health:

As with any blasting operations, airborne dust is a major safety and health concern. Proper precautions should be taken to ensure that personnel do not inhale dust/particulate matter. Additional protective measures should be taken when stripping lead, chromate, zinc chromate, or solvent-based paints, as these components may be hazardous. Inhalation of lead and zinc compounds can irritate the respiratory system and some compounds are known to be carcinogenic. Inhalation of paint solvents can irritate the lungs and mucous membranes. Prolonged exposure can affect respiration and the central nervous system. Proper personal protective equipment should be used.

Noise exposure and explosion hazard are potential occupational safety and health hazards associated with this particular stripping process. Consult your local industrial health specialist, your local health and safety personnel, and the appropriate MSDS prior to implementing this technology.


Benefits:
  • Wheat starch is a plentiful natural resource that is biodegradable.
  • Waste generated from this process can be treated in a bioreactor.
  • Waste volume requiring subsequent disposal is estimated to be only five percent of the original volume.
  • The wheat starch blasting process can be used for removing coatings from both metallic and composite materials.
  • This process is very controllable; it can be used to selectively remove one or more layers of coating.
  • Wheat starch blasting does not cause fatigue to the substrate surface.
  • Moderate stripping rates can be achieved while maintaining a gentle stripping action.
  • Safe on soft-clad aluminum.
  • Media is inexpensive and non-toxic.
  • Reduces water use.
  • Fully developed systems available.
  • No size limitations on parts being stripped.


Disadvantages:
  • High capital investment cost.
  • Requires complex subsystems for media recovery and recycling and dust collection and control.
  • Operator training required.
  • Low levels of dense particle contamination in the media may result in a rough surface finish on delicate substrates.
  • Waste material may require costly disposal as hazardous waste .
  • Stripping rates are typically slow to moderate.
  • Stripping rates are slow and inefficient as reported by WR-ALC/TIEDM.
  • Operators must wear personal protective equipment.
  • Media is moisture sensitive and may require an air dryer for humidity control.
  • According to the Air Force Corrosion Program Office, wheat starch blasting is not considered to be a viable method of paint removal for Air Force aircraft. There may be some advantage in using this process on a limited basis to remove paint from aircraft composite or fiberglass components in an area where a very controlled environment can be assured. Due to the extreme moisture sensitivity of this process, humidity control to the extent required for very large aircraft such as the C-5 is almost impossible and not economically feasible.


Economic Analysis: Capital costs for wheat starch blasting systems will vary, depending upon the application. A PMB system can be modified for a cost of approximately $10,000 for a small application. An automated, closed, dust-free system for a large application (e.g. aircraft) can cost up to $1.5 million.

The operating costs for wheat starch blasting systems have been estimated to be 50 % less than chemical paint stripping (i.e., methylene chloride).

Assumptions:

  • Annual area of paints to be removed/year: 93,800 ft2.
  • Labor rate: $30/hr.
  • Stripping rate for wheat starch blasting: 15 ft2/hr.
  • Stripping rate for chemical stripping: 25 ft2/hr.
  • Chemical procurement cost: $11.40/gal.
  • Chemical stripping efficacy: 15.84 ft2/ gallon
  • Media usage rate: 1 lb/ft2.
  • Wheat starch media cost: $1.70/lb.
  • Hazardous waste generation rate: wheat starch blasting = 1.07 lbs/ft2.
  • Hazardous waste generation rate: chemical stripping = 5.52 lbs/ft2; this is based on a stripper requirement of 5,922 gal./yr. which is derived from the 15.84 ft2/gal rate and assuming about 1/3 remains after solvent evaporation, rinse water required is about 10 times the amount of stripper, the density of the stripper residue approaches 8.34 lbs./gal. (the density of water), and the weight of the primer and paint residue is about 6,998 lbs./yr. which is derived from the knowledge that a 17,424 ft2 C-141B aircraft with two overcoats has about 1,300 lbs. of primer and paint on it.
  • Hazardous waste disposal cost: $2/lb.

Annual Operating Cost Comparison for Wheat Starch Blasting and Chemical Stripping

 

Wheat Starch Blasting

Chemical Stripping

Operational Costs:    
Labor: $187,600 $112,560
Material: $159,460 $67,507
Hazardous Waste Disposal: $200,732 $1,035,552
Total Operational Costs: $547,792 $1,215,619
Total Recovered Income: $0 $0
Net Annual Cost/Benefit: -$547,792 -$1,215,619

Economic Analysis Summary

    Annual Savings for Wheat Starch Blasting: $667,827
    Capital Cost for Diversion Equipment/Process: $12,500,000
    Payback Period for Investment in Equipment/Process: 18.7 years

Click Here to view an Active Spreadsheet for this Economic Analysis and Enter Your Own Values. To return from the Active Spreadsheet, click the reverse arrow in the Tool Bar.


Approving Authority:

No major claimant has endorsed this technology for use on aircraft and aircraft components without subsequent additional treatment to ensure substrate is completely free of blast media. This technology should be implemented only after the cognizant authority has granted engineering approval.

For Air Force applications, paint stripping using wheat starch blasting must not be used on any aircraft or weapon systems without the knowledge and approval of the appropriate system manager, office(s) having engineering authority on the specific airframe(s) and the Air Force Corrosion Prevention and Control Office.


NSN/MSDS:
Product NSN Unit Size Cost MSDS*
None Identified     $  


*There are multiple MSDSs for most NSNs.
The MSDS (if shown above) is only meant to serve as an example.


Points of Contact:

Air Force:
Air Force Corrosion Prevention and Control Office
AFRL/MLS-OLR (Bldg. 165)
325 Richard Ray Blvd.
Robins AFB, GA 31098-1640
Phone: (478) 926-3284
DSN: 468-3284
Email: mailto:ADCORR@robins.mil

Army:
Mr. Edward Cooper
Corpus Christi Army Depot
AMSAM-CC-ES-IE
308 Crecy Street, Mail Stop 30
Corpus Christi, TX 78419-5260
Phone: (361) 961-6403
DSN: 861-6403
FAX: (361) 961-2046
Email: ecooper@ccad.army.mil

Navy:
Mr. Bob Fredrickson
Naval Facilities Engineering Service Center, ESC423
1100 23rd Avenue
Port Hueneme, CA 93043-4370
Phone: (805) 982-4897
DSN: 551-4897
FAX: (805) 982-4832


Vendors:

This is not meant to be a complete list, as there are other manufacturers of this type of equipment.

Archer Daniels Midland Company
995 Mill Street
Montreal,  Quebec   H3C1Y5
Canada
Phone: (800) 561-3715
Contact: Judith Leschaloupe
Email: jkl@adm-ogilivie.com
Service: EnviroStrip®

Clemco Industries Corporation
Aerolyte Systems Division
One Cable Car Drive
Washington,  MO   63090
Phone: (636) 239-0300 
FAX: (800) 726-7559


Sources:

None listed


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