WATERBORNE PAINT

Revision Date: 9/01
Process Code: Navy/Marines: ID-05-00; Air Force: PA01; Army: PNT
Usage: Navy: High; Marines: High; Army: High; Air Force: High
Compliance Impact: High
Alternative for: Solvent-Based Paint
Applicable EPCRA Targeted Constituents: Toluene (CAS: 108-88-3), Xylene (CAS: 1330-20-7), Methyl Ethyl Ketone (CAS: 78-93-3), Acetone (CAS: 67-64-1), N-butyl Alcohol (CAS: 71-36-3), Chromium (CAS: 7440-47-3), Cyanide (CAS: 57-12-5), Lead (CAS: 7439-92-1), Zinc Compounds

Overview: Waterborne paints have been evaluated as alternatives to solvent-based paints. The volatile organic compound (VOC) content of waterborne paints is significantly lower than conventional solvent-based paints, thereby reducing VOC emissions. Waterborne (or latex) paints are composed of synthetic resins and pigments that are kept dispersed in water by surfactants. They also contain small amounts of coalescing solvents. Waterborne paints dry by evaporation of the water. The coalescing solvents allow the resin particles to fuse together (coalesce) as the water evaporates to form a continuous coating. Waterborne paints must be protected from freezing and applied at a minimum temperature of 50 degrees Fahrenheit.

Waterborne paints reduce VOC emissions and worker exposure to hazardous air pollutants. These paints can also reduce the amount of hazardous waste generated, depending on the type of paint used. Since waterborne coatings do not meet the requirements for solvent resistance and temperature as required for aerospace applications, these coatings are recommended by the Air Force for non-aerospace applications. The following is a description of nationally stock-listed latex paints:

  1. Exterior Acrylic Latex Paint: These paints are suitable for use on concrete, masonry, stucco, and wood. They can also be used for interior applications and may be applied by spray, brush, or roller. They dry to the touch in ten minutes and dry hard in two hours. Exterior acrylic latex paints are non-toxic and have a maximum volatile organic compound (VOC) content of 250 grams per liter.

  2. Concrete Floor Sealer/Finisher: Concrete floor sealer/finisher is a resin-based, water emulsion sealing and finishing compound for use on cured and uncured concrete floors. It may also be used on other masonry, linoleum, rubber tile, magnesite, and troweled asphalt and is applied by flooding and spreading. The typical VOC content is 250 grams per liter.

  3. Traffic and Airfield Marking Paint: This paint is water-borne, is 100 percent acrylic, and is suitable for application on traffic bearing surfaces such as Portland cement concrete, bituminous cement concrete, asphalt, tar, and previously painted areas of those surfaces. These paints are low VOC, and lead and chromate-free.

  4. Latex Stain: Latex stain is intended for new or previously stained exterior wood surfaces. It dries hard in one hour and has a VOC content of 250 grams per liter.

  5. Acrylic Enamel: Intended for use on exterior primed metal, concrete, masonry, and wood, acrylic enamel can be used for interior applications as well. These paints are lead-free, hexavalent chromate-free, mercury-free, and have a maximum VOC content of 200 grams per liter.

  6. Low VOC Aerosol Paint: Low VOC aerosol paint is fast-drying, general purpose interior/exterior enamel. It can be applied to metal, wood, plaster, masonry, stone, glass, leather, fiber or previously painted surfaces.

  7. Recycled Latex Paint: These paints contain a minimum of 50 percent post-consumer waste and are intended for use on interior or exterior wallboard, concrete, stucco, masonry, and wood. They may be applied by spray, brush, or roller, and have a maximum VOC content of 250 grams per liter.

  8. Semigloss Paint, Water-Borne for Metal Surfaces: Acrylic or modified acrylic topcoat paint is suitable for use on exterior or interior metal surfaces in all non-marine environments. Lead and chromate-free, this paint has a maximum VOC content of 250 grams per liter.

  9. Water-Borne Metal Primer: This acrylic primer can be used on exterior or interior metal surfaces in all non-marine environments. It has a maximum VOC content of 250 grams per liter.

  10. Stencil Paint: Water-emulsion paint is intended for markings and for obliterating markings on wood and fiberboard containers. It is non-flammable, brush applied, and has a maximum VOC content of 250 grams per liter.

  11. Water Reducible Epoxy Primer: A corrosion-inhibiting primer, this coating is intended for use on clean, chemically pretreated metal surfaces where exposure to lead or chromate pigments is prohibited. Compatible with chemical agent resistant aliphatic polyurethane topcoats, it is intended for spray application and has a maximum VOC content of 340 grams per liter.

  12. Water-Borne Epoxy Coating Kits: Formulated for use on wood and concrete floors, these coatings are water-based, non-flammable, non-toxic, and resistant to brake fluid, petroleum-based agents, jet fuel, caustic compounds, and most acids up to a 20 percent concentration. The coating may be applied by spray, brush or roller, and has a maximum VOC content of 168 grams per liter.


Compliance Benefit: Using a waterborne paint decreases hazardous waste generation because overspray may be recaptured, and the process does not generate spent cleanup solvents. This benefit helps facilities meet the requirements of waste reduction under RCRA, 40 CFR 262, Appendix, and may also help facilities reduce their generator status and lessen their regulatory burden under RCRA, 40 CFR 262 (i.e., recordkeeping, reporting, inspections, transportation, accumulation time, emergency prevention and preparedness, emergency response). In addition, waterborne paints do not contain the volume of solvents that conventional paint contains and therefore, the possibility that a facility meets any of the reporting thresholds of SARA Title III (40 CFR 300, 355, 370, and 372; and EO 12856) for solvents is decreased. Moreover, since the VOC content in waterborne paints is significantly lower than conventional solvent paints, fewer VOCs are emitted to the air, a factor which may lessen the likelihood that a facility will require an air permit under 40 CFR 70 and 71.

The compliance benefits listed here are only meant to be used as a general guideline and are not meant to be strictly interpreted. Actual compliance benefits will vary depending on the factors involved, e.g. the amount of workload involved.


Materials Compatibility:
Waterborne paints can rust plain steel and can sometimes attack aluminum. Application equipment must be constructed of a corrosion-resistant material such as 316 stainless steel.

Waterborne coating material conducts high voltage electricity much more readily than solvent-based material. As a result, the electrostatics of a waterborne system will only work if all wetted equipment is isolated from potential grounds. Three methods can be used to avoid grounding out the electrostatics in a waterborne system: (1) isolate the entire paint system from electrical grounds; (2) isolate a small part of the wetted system with a voltage blocking device; and (3) indirectly charge the paint particles away from any of the wetted equipment. Each method has its advantages and disadvantages and should be evaluated for the specific application. The use of a voltage blocking device at each atomizer is often the most cost-effective method.


Safety and Health: Health and safety issues are reduced significantly by using waterborne paints. However, these paints contain coalescing solvents that can be slight irritants by inhalation. Proper personal protective equipment (PPE) is recommended.

Waterborne paints may also contain other solvents, such as butoxyethanol, isopropyl alcohol, and sec-butyl alcohol. These solvents have occupational exposure limits established by the National Institute for Occupational Safety and Health (NIOSH), American Conference of Government Industrial Hygienists (ACGIH), and/or Occupational Safety and Health Administration (OSHA). Consult your local industrial health specialist, your local health and safety personnel, and the appropriate MSDS prior to implementing this technology.


Benefits:
  • VOC emissions are significantly reduced.
  • Waterborne paints are generally easier to apply and clean up.
  • Good to excellent surface properties including gloss, rub resistance, anti-sealing effect, and non-yellowing film.
  • Some waterborne paints allow overspray to be recovered and recycled, effectively increasing transfer efficiency.
  • Disposal requirements for waterborne paint waste may be reduced, depending on local requirements and/or waste quantities.
  • Dried waterborne paint waste may be disposed in landfills as non-hazardous waste.
  • Health and safety requirements for workers are significantly reduced or eliminated.


Disadvantages:
  • May have lower chemical and solvent resistance.
  • Reduced temperature resistance.
  • Waterborne coatings are sensitive to humidity. Low humidity can cause coatings to dry extremely fast, creating craters in the final film. High humidity can cause very slow drying times, resulting in sagging.
  • Quality of application is dependent on surface cleanliness. The water’s high surface tension prevents the wetting of some surfaces and causes poor coating flow characteristics. Surfaces with grease and other contaminants are especially susceptible to poor coating.
  • Emulsion coatings have poor penetration and adhesion properties on porous surfaces, e.g. wood. Emulsion coatings do not adhere well to old chalky surfaces.
  • Lower abrasive resistance.
  • Requires wetted equipment to be isolated from potential grounds.


Economic Analysis: Solvent-based paint systems can usually be converted to waterborne paint systems with a limited capital investment. The cost of waterborne paints will vary depending on the application used. In general, the price of waterborne paints is comparable to the price of solvent-based paints.

Assumptions:

  • Waterborne paint procurement cost: $20/gal.
  • Solvent based paint procurement cost: $20/gal.
  • Solvent procurement cost: $5/gal.
  • Water usage cost: $1.94/1000 gal.
  • Industrial wastewater disposal cost: $8.24/1000gal.
  • Waste paint/solvent disposal cost: $1.25/lb./LI>
  • Paint usage: 1,560 gal/year
  • Solvent usage (solvent based paint application equipment cleaning): 156 gal./yr.
  • Water usage (water based paint application equipment cleaning): 260 gal./yr.
  • Waste paint/solvent generated: 1,000 lb./yr.
  • Wastewater generated: 260 gal./yr.
  • Labor for materials handling and operation for both methods are assumed to be comparable.

Annual Operating Cost Comparison for Waterborne Paint Application and Solvent Based Paint Application

  Waterborne Paint Solvent-Based Paint
Operational Costs:    
Paint: $31,200 $31,200
Solvent: $0 $780
Process Water: $1 $0
Wastewater Disposal: $2 $0
Waste Paint/ Solvent Disposal: $0 $1,250
Total Operational Costs: $31,203 $33,230
Total Recovered Income: $0 $0
Net Annual Cost/Benefit: -$31,203 -$33,230

Economic Analysis Summary

    Annual Savings for Waterborne Paint Application: $2,027
    Capital Cost for Diversion Equipment/Process: $0
    Payback Period for Investment in Equipment/Process: Immediate

Click Here to view an Active Spreadsheet for this Economic Analysis and Enter Your Own Values. To return from the Active Spreadsheet, click the reverse arrow in the Tool Bar.


Approving Authority: Approval is controlled locally and should be implemented only after engineering approval has been granted. Major claimant approval is not required.

Technical Orders are the source of authority for all paints used on aerospace equipment by the Air Force. Only the waterborne epoxy is approved for use in T.O.1-1-8.


NSN/MSDS:
Product NSN Unit Size Cost MSDS*
Paint/Lacq./Clr. 8010-01-397-3559 55 gal. $838.74 Click me
Paint/Lacq./Red 8010-01-397-3560 1 gal. $25.82 Click me
Paint/Lacq./Clr.Gloss 8010-01-397-3588 5 gal. $88.96 Click me
Paint/Lacq./Blk.Semi 8010-01-397-3642 5 gal. $91.11 Click me


*There are multiple MSDSs for most NSNs.
The MSDS (if shown above) is only meant to serve as an example.


Points of Contact: Army:
Mr. Randy Doyle
HQ III Corps & Fort Hood
AT2F-PW-ENV, Bldg 429
Fort Hood, TX 76544
Phone: (254) 287-2718
DSN: 737-1099


Navy:
Mr. Rex Conner
Naval Aviation Depot
Naval Air Station Jacksonville
Jacksonville, FL 32212-0016
Phone: (904) 542-5240
DSN: 942-5420
FAX: (904) 542-0691


Vendors: This is not meant to be a complete list, as there are other manufacturers of this type of equipment.

Sherwin Williams
7230 1/2 Woodrow Street
Irmo,  SC   29063
Phone: (803) 603-8699  Contact: Mr. Tim Creech

Deft Inc.
17451 Von Karman Avenue
Irvine,  CA   92714
Phone: (949) 474-0400 
FAX: (949) 474-7269


Sources: R. Konieczynski, "Converting to Waterbornes for Less Cost," Metal Finishing, January 1995, Vol. 93, No. 1, pp. 20-23.
P. Bankert, "Waterborne Paint Circulation," Industrial Finishing, July 1990, Vol. 66, No. 7, pp. 42-43.
"GM Adopts Waterborne Basecoats," Industrial Finishing, July 1990, p. 32
R. Joseph, "Environmental Coating Problems," Metal Finishing, May 1994, pp. 44-45.



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