ODS-FREE AIRCRAFT COMPONENTS CLEANING - OVERVIEW

Revision Date: 4/00
Process Code: Navy/Marines: ID-01-00, ID-22-01, ID-23-99; Air Force: CL01; Army: CLD
Usage: Navy: High; Marines: High; Army: Medium; Air Force: High
Compliance Impact: Low
Alternative for: Methyl chloroform (MCF) and Trichlorotrifluoroethane (CFC-113)
Applicable EPCRA Targeted Constituents: 1,1,1-Trichloroethane (CAS: 71-55-6)

Overview:

Chlorofluorocarbon (CFC) solvents, including MCF and CFC-113, are used extensively for cleaning metal, electronic, and precision parts during aircraft maintenance procedures. These solvents are also used in applications such as coatings, adhesives, lubricant carriers, and mold release agent carriers. However, CFC-113 and MCF are EPA Class I ozone-depleting substances (ODSs) and have been banned from production as of January 1, 1996. DoD policy is that CFCs and Halons can only be used for mission critical applications. Fortunately, numerous ODS-free alternatives are now available to replace CFC-113 and MCF. In many instances solvent use can even be reduced or eliminated

Cleaning for aircraft maintenance can, for the most part, be divided into three categories: metal, electronics, and precision cleaning. Metal cleaning refers to the removal of oil or grease from metal parts during maintenance and repair procedures. Landing gear and control surfaces fall under metal cleaning. Electronics cleaning includes the removal of flux from soldered operations. Encompassing both metal and electronics cleaning, the term "precision cleaning" is not as much a function of the component being cleaned, as it is of the level of cleanliness required. Components typically requiring precision cleaning are those with close tolerances, complex geometries, or sensitive to contamination. There are aircraft components that fall into all three categories.

The following suggestions are directed primarily at typical aircraft maintenance functions.

Cleaning Applications

The first step in eliminating the use of CFCs in aircraft maintenance is to characterize all cleaning steps. What parts need to be cleaned? What is the substrate and contaminant being cleaned? How clean does the part need to be? By identifying the cleaning needs, a proper alternative can be chosen. Certain materials are subject to corrosion, swelling, deformation, and damage to coatings and adhesives if the proper cleaning alternative is not chosen. Complexity of the part dictates whether vapor degreasing or aqueous cleaning should be used. Vapor degreasing works best for cleaning complex parts. Some cleaning steps may be identified that can be reduced, consolidated, or eliminated.

Most aircraft cleaning falls into two general cleaning processes: cold cleaning and vapor degreasing. In cold cleaning processes, parts are cleaned by either immersion and soaking, spraying, or wiping with ambient temperature solvents. The vapor degreasing process uses a boiling solvent to effect cleaning. A volatile solvent such as CFC-113 or MCF is heated in a reservoir below a suspended part. Solvent vapors rise to the top of the cleaning vessel and are condensed into droplets. The solvent droplets fall onto the part, dissolving contaminants. As the droplets collect and fall, contaminants are carried off the part and into the solvent reservoir. Since the contaminants are generally low or non-volatile, solvent vapors remain essentially pure; effective cleaning is maintained despite the increasing contamination of the solvent reservoir.

The following table lists cleaning operations and alternatives associated with aircraft maintenance:

Cleaning Application Current Cleaning method w/ CFC-113 or MCF Alternative Cleaning Method

Aircraft Exterior Surface

Aerosol Spray or Hand Wipe

Aqueous Cleaning - Alkaline Solution (Light Soil Removal)

   

Semi-Aqueous Cleaning - Aliphatic Naphtha/Alkaline (Moderately Heavy Soil Removal)

   

Semi-Aqueous Cleaning - Aliphatic Naphtha/Alkaline (Heavy Soil Removal)

   

Semi-Aqueous Cleaning - Terpene

   

Aliphatic Hydrocarbon Cleaning - Mineral Spirits

Landing Gear

In-Shop Overhaul: Vapor

Aqueous Cleaning - Alkaline Solution

 

Degreasing or Aerosol Spray

Semi-Aqueous Cleaning - Mineral Spirits

 

On-the-Aircraft

Aqueous Cleaning - Alkaline Solution

 

Maintenance: Aerosol Spray

Aliphatic Hydrocarbon Cleaning - Mineral Spirit

Engine or Engine Modules

Vapor Degreasing

Aqueous Cleaning - Heated Tank

 

 

Aliphatic Hydrocarbon Cleaning - Mineral Spirit

 

Immersion

Aqueous Cleaning - Alkaline Solution, Heated Tank

 

Vapor Degreasing

Aqueous Cleaning - Alkaline Solution, Heated Tank

 

Vapor Degr. or Hand Wipe

Aqueous Cleaning - One Step Heavy-Duty Alkaline Solution

 

Immersion

Aqueous Cleaning - Four Step Heavy-Duty Alkaline Solution

 

Vapor Degr. or Hand Wipe

Aqueous Cleaning - Alkaline Solution

 

Vapor Degreasing

Blasting - High Pressure Steam/Water

   

Chlorinated Solvent Cleaning - Trichloroethylene

Engine or Engine Modules: Assembled and Partially Assembled Parts

Aerosol Spray or Hand Wipe

Aqueous Cleaning - Alkaline Solution

Flight Control Surfaces

Aerosol Spray or Hand Wipe

Aqueous Cleaning - Alkaline Solution

   

Aliphatic Hydrocarbon Cleaning - Mineral Spirit

   

Organic Solvent Cleaning - Methyl Ethyl Ketone or Acetone

Electrical Equipment

Aerosol Spray

Aqueous Cleaning - Alkaline Solution, Ultrasonic

   

Organic Solvent Cleaning - Isopropyl Alcohol

Hydraulic Lines

Hand Wipe or Vapor Degr.

Aqueous Cleaning - Water Base Soap Solution

Aircraft Seat Covers and Curtains/Draperies

Dry Cleaning

Chlorinated Solvent Cleaning - Perchloroethylene

Prior to Coating: Polyurethane

Hand Wipe

Organic Solvent Cleaning - Methyl Ethyl Ketone or Blends

Prior to Coating: Chromate Conversion

Hand Wipe

Organic Solvent Cleaning - Methyl Ethyl Ketone or Blends

   

Semi-Aqueous Cleaning - Aliphatic Naphtha/Alkaline

Prior to Coating: Other

Varied

Organic Solvent Cleaning

Prior to Adhesive Bonding

Spray or Hand Wipe

Organic Solvent Cleaning - Isopropyl Alcohol

 

Hand Wipe

Semi-Aqueous Cleaning - Terpene

Prior to Fluorescent Penetrant Inspection

Aerosol Spray or Hand Wipe

Chlorinated Solvent Cleaning - Trichloroethylene

   

Organic Solvent Cleaning - Methyl Ethyl Ketone

During Fluorescent Penetrant Inspection

Aerosol Spray or Hand Wipe

Organic Solvent Cleaning - Isopropyl Alcohol, Methyl Ethyl Ketone, or Acetone

Prior to Reassembly

Hand Wipe or Immersion

Hydrocarbon Cleaning

Prior to Welding

 

Organic Solvent Cleaning - Methyl Ethyl Ketone or Acetone

Prior to Painting

Aerosol Spray or Hand Wipe

Organic Solvent Cleaning - Methyl Ethyl Ketone and Toluene

DLA’s Environmental Catalog lists several aircraft cleaning products that do not contain chlorinated compounds, ODCs, HAPs and have low VOCs.


Compliance Benefit:

Use of ODS-free substances to clean aircraft components will help facilities meet the requirements under 40 CFR 82, Subpart D and Executive Order 12843 requiring federal agencies to maximize the use of safe alternatives to class I and class II ozone depleting substances, to the maximum extent practicable. In addition, the elimination of substances such as methyl chloroform and CFC-113 at the facility decreases the possibility that the facility would meet any of the reporting thresholds for those chemicals under 40 CFR 370 and EO 12856. Chemicals used as substitutions should be reviewed for SARA reporting issues.

The compliance benefits listed here are only meant to be used as a general guideline and are not meant to be strictly interpreted. Actual compliance benefits will vary depending on the factors involved, e.g. the amount of workload involved.


Materials Compatibility:

Materials compatibility depends on the alternative solvent/procedure implemented. Considerations can include corrosion, damage to coatings and adhesives, and swelling and deformation (especially for organic substitutes: alcohols, ketones, ethers, chlorinated solvents, etc.). Testing will reveal damage.


Safety and Health:

Organic Solvents can be extremely flammable/combustible. Use only in areas with good ventilation. Aliphatic hydrocarbons are also flammable and have low occupational exposure limits. Consult the MSDS of particular solvents to ensure that solvent is used properly and all necessary safety requirements (i.e., personal protective equipment, increased ventilation, fire fighting equipment) can be met. In addition, consult your local Industrial Health specialist, local health and safety personnel, and the SNAP comments prior to converting to any replacement product.


Benefits:
  • Reduce the amount of ozone-depleting substances and EPCRA-targeted chemicals going into the environment.
  • Reduce worker exposure to toxic chemicals.


Disadvantages:
  • "Down time" expected for adjustments to new system.


Economic Analysis: Because cleaning circumstances are so variable, the economic feasibility of substitute processes and chemicals needs to be evaluated for each application prior to conversion.


Approving Authority:

Approval is controlled locally and should be implemented only after engineering approval has been granted. Major claimant approval is not required.


NSN/MSDS:
Product NSN Unit Size Cost MSDS*
Hurri-Safe Hot Immersion Degreaser 6850-01-373-5866 5-gal $88.79 Click me
PF-145HP 6850-01-378-0044 6/1 gal. $89.02 Click me
Bio-T Max 6850-01-381-3944 55 gal. $1152.65 Click me
Mil-C-43616 Class IA 6850-00-005-5305 16 oz $1.81 Click me
Mil-C-87937 6850-01-429-2371 55 gal. $401.07 Click me
Mil-C-87937 TY I 6850-01-390-7808 1 gal $47.65 Click me
Mil-C-87937 TY II 6850-01-339-5227 5 gal. $47.12 Click me
Mil-C-87937 TY III 6850-01-390-9453 55 gal. $292.15 Click me
Mil-C-87937 TY IV 6850-01-433--0873 5 gal $40.00 Click me
Mil-C-85570 TY II 6850-01-236-0128 55 gal $225.37 Click me
Mil-C-85570 TY V 6850-01-235-7458 55 gal $261.37 Click me

*There are multiple MSDSs for most NSNs.
The MSDS (if shown above) is only meant to serve as an example.


Points of Contact:

Civilian:
Concurrent Technologies Corporation
National Defense Center for Environmental Excellence
Phone: (800) 282-4392

EPA:
Mr. William Monroe
Office of Stratospheric Ozone Protection - US EPA
Washington, DC
Phone: (202) 564-9161


Vendors:

PCI of America
6610 Rockledge Drive
Suite 200
Bethseda,  MD   20817
Phone: (301) 320-9100 
FAX: (800) 222-1455
URL: http://www.hurrisafe.com
Service: Hurrisafe 9050 HID

Golden Technology
14452 W. 44th Ave.
P.O. Box 437
Golden,  CO   80402
Phone: (800) 777-7870 
Service: Bio-T Max

P-T Technologies, Inc.
108 4th Avenue, South
Safety Harbor,  FL   34695
Phone: (800) 441-7874 
FAX: (813) 726-4644
Service: PF-145HP Degreaser


Sources:

ICOLP Manual, Eliminating CFC-113 and Methyl Chloroform in Aircraft Maintenance Procedures, 1993.
Hume, Bob, "Ozone Depleting Substances," NAVAIR 4th Annual Pollution Prevention & Technology Exchange Conference, p. 415-446, May 26, 1994.
Clark, Ken, "Low Solvent Cleaners and Corrosion Preventive Compounds," NAVAIR 4th Annual Pollution Prevention & Technology Exchange Conference, p. 589-592, May 26, 1994


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