ODS-FREE SUBSTITUTE FOR INSULATING FOAM

Revision Date: 5/00
Process Code: Navy/Marines: SR-04-99; Air Force: SV01; Army: N/A
Usage: Navy: Low; Marines: Low; Army: Medium; Air Force: Low
Compliance Impact: Low
Alternative for: CB 120 Filler Foam
Applicable EPCRA Targeted Constituents: Class I and Class II Ozone Depleting Substances

Overview:

CFCs and HCFCs are common blowing agents used in the expansion of polymer foams, such as expanded polystyrene (STYROFOAM®). Most companies, however, have switched from using CFCs as blowing agents to using HCFCs or other alternative methods.

Typically, most insulating foams use a CFC (Class I ODS) for the expansion of the polymer foam. However, the SNAP (Significant New Alternatives Policy) program that was implemented by the U.S. EPA established that under the Clean Air Act, CFC importation and production are prohibited in the U.S. effective January 1, 1996. CFC use, however, is still permitted as long as it complies with Section 610 of the Clean Air Act "Non-Essential Use Ban". Although the use is still permitted, the CFCs are becoming more expensive due to the decrease in availability due to the production ban.

Several alternative chemicals and technologies have come on the market, which do not use CFCs in their mixture. HCFC (a Class II ODS) is a common substitute found for CFC insulating foams. However, HCFCs are currently becoming curtailed in both production and use due to their ozone depleting potential. One new alternative to gas induced expansion is "electroset" technology. Electrosetting materials are made up of ordinary resins mixed with an electrically polarizable aggregate that makes the resin semiconductive while in its liquid state. The fluid resin is then heated electrically until, at a certain temperature, one constituent of the resin changes phase from liquid to gas, thus creating bubbles. The rest of the resin then solidifies, resulting in an expanded foam. By altering the applied electrical energy, qualities such as foam density and compressibility can be controlled. Using alternating current in the process produces a homogeneous foam. Direct current causes a thermal gradient in the resin resulting in foam with properties that vary within the foam matrix. Molded items can also be produced.

Below is a table excerpted from the U.S. EPA website, http://www.epa.gov/ozone, which lists several types of polyurethane foams, the targeted ODS, and the acceptable substitute:

Application

Targeted ODS

Substitute

Rigid Polyurethane, Appliance

CFC-11, class I ODS

HCFC-123
HCFC-141b
HCFC-142b
HCFC-22
Proprietary Blowing Agent 1 (PBA 1)
Saturated Light Hydrocarbons (C3-C6)
HFC-134a
HFC-152a
Electroset Technology
Carbon Dioxide
Vacuum Panels

Rigid Polyurethane, Appliance

HCFCs, class II ODS

Proprietary Blowing Agent (PBA 1)
Carbon Dioxide
HFC-134a
Saturated Light Hydrocarbons (C3-C6)

Rigid Polyurethane, Commercial

CFC-11, class I ODS

HCFC-123
HCFC-141b
HCFC-142b
HCFC-22
Proprietary Blowing Agent 1(PBA 1)
Saturated Light Hydrocarbons (C3-C6)
HFC-134a
HFC-152a
Electroset Technology
Carbon Dioxide

Rigid Polyurethane, Commercial

HCFCs, class II ODS

Proprietary Blowing Agent 1(PBA 1)

Flexible Polyurethane

CFC-11, class I ODS

Saturated Light Hydrocarbons (C3-C6)
HFC-134a
HFC-152a
Electroset Technology
Carbon Dioxide
Methylene Chloride
Acetone
AB Technology

Integral Skin Polyurethane

CFC-11, class I ODS

Saturated Light Hydrocarbons (C3-C6)
HFC-134a
HFC-152a
Electroset Technology
Carbon Dioxide
Methylene Chloride
Acetone
Formic Acid

Integral Skin Polyurethane

HCFCs, class II ODS

Carbon Dioxide
HFC-134a
Saturated Light Hydrocarbons (C3-C6)
Acetone
Formic Acid

Polyurethane, Extruded Sheet

CFC-12, class I ODS

Saturated Light Hydrocarbons (C3-C6)
HFC-134a
HFC-152a
Electroset Technology
Carbon Dioxide

Polyolefin

CFC-11, CFC-12, & CFC-114, class I ODSs

HCFC-142b
HCFC-22
HCFC-22/HCFC-142b Blends
HCFC-22/Saturated Light Hydrocarbons (C3-C6) Blends
Saturated Light Hydrocarbons (C3-C6)
HFC-134a
HFC-152a
HFC-143a
Electroset Technology
Carbon Dioxide
Methylene Chloride
HFC-152a/Saturated Light Hydrocarbons (C3-C6) Blends
Chemical Blend A

Rigid Polyurethane, Slabstock

CFC-11, class I ODS

HCFC-123
HCFC-141b
HCFC-22
Proprietary Blowing Agent 1 (PBA 1)
Saturated Light Hydrocarbons (C3-C6)
HFC-134a
HFC-152a
Electroset Technology
Carbon Dioxide

Rigid Polyurethane, Slabstock

HCFCs, class II ODS

Proprietary Blowing Agent 1 (PBA 1)

Polystyrene, Extruded Boardstock and Billet

CFC-12, class I ODS

HCFC-142b
HCFC-22
HCFC-22/ Saturated Light Hydrocarbons (C3-C6) Blends
Saturated Light Hydrocarbons (C3-C6)
HFC-134a
HFC-152a
HFC-143a
Electroset Technology
Carbon Dioxide

Rigid Polyurethane & Polyisocyanurate Laminated Boardstock

CFC-11, class I ODS

HCFC-123
HCFC-141b
HCFC-142b
HCFC-22
HCFC-22/HCFC-141b Blends
HCFC-141b/HCFC-123 Blends
HCFC-22/HCFC-142b Blends
Proprietary Blowing Agent 1 (PBA1)
Saturated Light Hydrocarbons (C3-C6)
HFC-134a
HFC-152a
2-Chloropropane
Electroset Technology
Carbon Dioxide

Rigid Polyurethane & Polyisocyanurate Laminated Boardstock

HCFCs, class II ODS

Proprietary Blowing Agent 1 (PBA 1)
Saturated Light Hydrocarbons (C3-C6)

Phenolic Insulation Board & Bunstock

CFC-11 and CFC-113, class I ODS

HCFC-141b
HCFC-142b
HCFC-22
HCFC-22/HCFC-142b Blends
HCFC-22/Saturated Light Hydrocarbons (C3-C6) Blends
Saturated Light Hydrocarbons (C3-C6)
HFC-143a
2-Chloropropane
Electroset Technology
Carbon Dioxide


Compliance Benefit:

Use of an ODS-free substitute for insulating foam will help facilities meet the requirements under 40 CFR 82, Subpart D and Executive Order 12843 requiring federal agencies to maximize the use of safe alternatives to class I and class II ozone depleting substances, to the maximum extent practicable. In addition, using ODS-free insulating foam decreases the possibility that the facility will meet reporting thresholds for ODSs under 40 CFR 355, 370 and EO 12856. Chemicals used as substitutions should be reviewed for SARA reporting issues

The compliance benefits listed here are only meant to be used as a general guideline and are not meant to be strictly interpreted. Actual compliance benefits will vary depending on the factors involved, e.g. the amount of workload involved.


Materials Compatibility:

No material compatibility issues were identified.


Safety and Health:

Consult your local Industrial Health specialist, your local health and safety personnel, and the appropriate MSDS prior to implementing any of these technologies.


Benefits:
  • Reduce the amounts of CFCs and other ODSs going into the environment.


Disadvantages: None identified.


Economic Analysis:

The following economic analysis is based on information provided by vendors comparing an insulating foam which uses a CFC mixture in their formulation, with one that uses a substitute:

Assumptions:

  • Cost for a typical can of 12 oz. insulating foam: $6.99
  • Cost for a 12 oz. can of insulating foam which uses a CFC substitute: $5.97
  • Equal usage and labor rates.
  • 5 cans of insulating foam used per year.

Annual Operating Cost Comparison for Insulating Foam and CFC-free Insulating Foam

  Insulating Foam CFC-free Insulating Foam

Operational Costs:

   

Materials:

$34.95

$29.85

Total Costs:

$34.95

$29.85

Total Income:

   

Annual Benefit:

-$34.95

-$29.85

Economic Analysis Summary

    Annual Savings: $5.10
    Capital Cost for Equipment/Process: $29.85
    Payback Period for Investment in Equipment/Process: < 6 years

Click Here to view an Active Spreadsheet for this Economic Analysis and Enter Your Own Values.


Approving Authority:

Approval is controlled locally and should be implemented only after engineering approval has been granted. Major claimant approval is not required.


NSN/MSDS:
Product NSN Unit Size Cost MSDS*
None Identified     $  

*There are multiple MSDSs for most NSNs.
The MSDS (if shown above) is only meant to serve as an example.


Points of Contact:

EPA:
Stratospheric Ozone Protection Hotline
U.S. Environmental Protection Agency
Mail Code 6205J
401 M St., SW
Washington, DC 20460
Phone: (800)-296-1996 or (301)-614-3396


Vendors:

Macklanburg-Duncan
4041 N. Santa Fe
Oklahoma City,  OK   73118
Phone: (800) 654-8454 
or (405) 528-4411
Service: Produces Macklanburg-Duncan Minimal Expanding Foam, which contains an HCFC

Flexible Products Co.
Insta-Foam Division
2050 N. Broadway
Joliet,  IL   60435
Phone: (815) 774-6500 
or (800) 800-3626
FAX: (815) 774-6522
Service: Produces Insta-Seal, which also contains an HCFC

RHH Foam Systems, Inc.
PO Box 752
Cudahay,  WI   53110-0752
Phone: (800) 728-6067 
Service: Produces polyurethane foam which does not contain any Class I ODS

3M Corporation
1311 Waterford Rd.
Woodbury,  MN   55125
Phone: (800) 480-1704 
or (612) 737-7218
Service: Produces Scotch Seal Chemical Grout 5600, which does not contain any chlorinated solvents

U.S. Navy
Phone: (410) 293-2561 
Service: For information on “Electroset” technology


Sources:

None listed


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