ODS-FREE COOLING/FREEZING PRODUCT

Revision Date: 9/00
Process Code: Navy/Marines: ID-22-99; Air Force: AD04; Army: ELM, LOP
Usage: Navy: Medium; Marines: Medium; Army: High; Air Force: High
Compliance Impact: Low
Alternative for: ODS cooling products and freezing products containing chlorofluorocarbons (CFCs)
Applicable EPCRA Targeted Constituents: Trichlorofluoromethane (CAS: 75-69-4), Dichlorodifluoromethane (CAS: 75-71-8), Freon 113 (CAS: 76-13-1), Dichlorotetrafluoroethane (CFC-114) (CAS: 76-14-2)

Overview:

Various ODS-free products have been developed by several manufacturers for cooling applications, such as testing heat sensitive avionics, deicing equipment, electrical, and computer components.

ODSs have seen use in many different applications, including that of cooling agents. However, this direct application of chlorofluorocarbons (CFCs) does not lend itself to CFC recovery, and given the production ban, alternatives need to be substituted.

In compressed gas form, CFCs are effective cooling agents. For example, they are effective for heat sensitive electronics or for testing anti-icing instruments like the probe on F-16 aircraft engine intakes. When the pressurized CFC is directed at the component or point of desired cooling and let down to atmospheric pressure, a cooling effect takes place due to the isoenthalpic expansion of the compressed gas. Recovery of the spent gas is difficult; therefore, alternatives must increasingly be substituted. The alternatives that are readily available and also environmentally innocuous are the following:

  1. Compressed air-vortex cooling involves use of a vortex tube powered by compressed air. This typically small, hand-held device uses shop air (8 to 15 SCFM @ 80-125 psig) passed through a vortex chamber to produce a cooling effect. Outlet temperatures of approximately -40o F are produced. However, the supply air must be both clean and dry for proper operation of the vortex tube.


  2. Liquid nitrogen from a dispenser flask can be used to spray at the component; however, care must be taken when using the nitrogen gun, as component temperatures can reach -270o F. Cost is approximately $500.


  3. The refrigerant, HFC-134a, can also be used as a freeze spray in place of CFC-12 and HCFC-22, if compressed air and nitrogen are unavailable. However, HFC-134a sprays have been shown to produce higher levels of electrostatic discharge than either CFC-12 or HCFC-22. Be sure to check with the manufacturer before using.


  4. The CO2 component cooler consists of a CO2 cylinder, a cart to make it portable, and a hand-held dispenser. The CO2 cylinders are typically procured in 20-lb containers, although other sizes are available. CO2 is stored as a liquid under about 850 psig of pressure. As it vaporizes, its temperature can drop to less than -100o F allowing for the formation of tiny dry ice particles. The CO2 component cooler is not only "ozone-safe" but is also considered a low-cost, effective option for electronic component cooling.


Compliance Benefit:

Use of alternatives to CFC cooling agents that contain non-ozone depleting chemicals will help facilities meet the requirements under 40 CFR 82, Subpart D and Executive Order 12843 requiring federal agencies to maximize the use of safe alternatives to Class I and Class II ozone depleting substances, to the maximum extent practicable. In addition, the elimination of CFCs at the facility decreases the possibility that the facility would meet any of the reporting thresholds for CFCs under 40 CFR 355, 370 and EO 12856. Chemicals used as substitutions should be reviewed for SARA reporting issues.

The compliance benefits listed here are only meant to be used as a general guideline and are not meant to be strictly interpreted. Actual compliance benefits will vary depending on the factors involved, e.g. the amount of workload involved.


Materials
Compatibility:


Although each of these alternatives focus on using relatively inert and non-toxic compounds, some products are not compatible with certain materials or components. Always check with the original equipment manufacturer to verify material compatibility.


Safety and Health:

Potential hazards such as room ventilation issues, eye irritation, and skin freezing or burning when exposed to escaping coolant gases need to be considered. See the individual Pollution Prevention Opportunity Data Sheets for more specific information about the acceptable alternatives, safety and health, and their material compatibility concerns. Also, consult your local Industrial Health specialist, your local health and safety personnel, and the appropriate MSDSs before converting to any of the alternative products or processes.


Benefits:
  • Reduces the amount of ODSs going into the environment.
  • Many alternatives are inexpensive, lower cost than the CFC alternative.


Disadvantages:
  • Some of the alternatives are slightly less efficient in cooling.
  • An electrostatic discharge exists with some of the alternatives.

Note: Each alternative has its own unique set of benefits and disadvantages. See the individual Pollution Prevention Opportunity Data Sheets for more specific information about each alternative.


Economic Analysis:

The capital cost of the CO2 component cooler (COMP-CO2LD) system includes the control unit, a 20-lb. cylinder, and a cart that is used to make the system portable. The following economic analysis was obtained from a case study on "Eliminating CFC-113 and Methyl Chloroform in Aircraft Maintenance Procedures" for the government of Thailand by the U.S. EPA Solvent Elimination Project.

Assumptions:

  • Number of CC-1 units needed to replace CFC-12: 50
  • Cost of CO2 system: $340.00
  • Labor requirements for both systems are approximately equal.
  • Number of CFC-12 cylinders used/year: 300
  • Number of CO2 cylinders needed to replace CFC-12 cylinders are equal.
  • Cost per CFC-12 cylinder: $105.00
  • Cost to refill CO2 cylinder: $6.00

Annual Operating Cost Comparison for CO2 and CFC-12 Component Cooling

  CO2 CFC-12

Capital Cost:

$17,000

$0

Operational Costs:

   

Material:

$1,800

$31,500

Total Operational Costs:

$1,800

$31,500

Total Recovered Income:

$0

$0

Net Annual Cost/Benefit:

-$1,800

-$31,500


Economic Analysis Summary

    Annual Savings for CO2 component cooler: $29,700
    Capital Cost for Diversion Equipment/Process: $17,000
    Payback Period for Investment in Equipment/Process: < 7 months

Click Here to view an Active Spreadsheet for this Economic Analysis and Enter Your Own Values.


Approving Authority:

Approval is controlled locally and should be implemented only after engineering approval has been granted. Major claimant approval is not required.


NSN/MSDS:
Product NSN Unit Size Cost MSDS*
Envi-ro-tech Freezer 1672 aer 6850-01-406-1356 12x10oz $93.66 Click me
E-series Freeze-It 6850-01-333-1841 12x14-15oz $73.73 Click me

*There are multiple MSDSs for most NSNs.
The MSDS (if shown above) is only meant to serve as an example.


Points of Contact:

Navy:
Mr. Peter Mullenhard
Navy Shipboard Environmental Information Clearinghouse, GEO-CENTERS, Inc.
1755 Jeff Davis Highway
Suite 910
Arlington, VA 22202
Phone: (703) 416-1023 ext 109 or (703) 416-1132
FAX: (703) 416-1178

Ms. Terry Taylor
Commanding Officer
NADEP, NAS Jacksonville
Material Engineering Lab, Mail Code: 4.3.4.4
Bldg. 793, NADEP
NAS Jacksonville, FL 32212
Phone: (904) 542-4519 ext 125
DSN: 942-4519
FAX: (904) 542-4523


Vendors:

Exair Corporation
1250 Century Circle North
Cincinnati,  OH   45246-3309
Phone: (800) 903-9247 
FAX: (513) 671-3363
Email: techelp@exair.com
URL: http://www.exair.com
Contact: Mr. Neal D. Raker, Application Engineer
Service: Manufacturer of Compressed-Air Vortex Cooler, Manufacturer of industrial compressed air products, vortex tubes and component coolers.

Tech Spray, Inc.
P.O. Box 949
Amarillo,  TX   79105-0949
Phone: (800) 858-4043 
Contact: Ms. Corry Carter
Contact: Mr. Jimmy Witcher, Sales Representative
Service: Manufacturer of HFC-134a Freeze Spray NSN: 6850-01-406-1356, Manufacturer Envir-Ro-Tech Freezer, product number P1672-10S, Sells “Envi-Ro-Tech Duster,” part number 1671-10S

GC Thorsen, Inc.
1801 Morgan Street
Rockford,  IL   61102
Phone: (815) 968-9661 
FAX: (815) 968-9029
Contact: Ms. Tammie Stanley, Product Manager
Service: Manufacturer of Series 2 Freeze Mist, part number 19-8410

Va-Tran Systems, Inc.
677 Anita Street
Suite A
Chula Vista,  CA   91911-4661
Phone: (619) 423-4555 102
FAX: (619) 423-4604
URL: http://www.vatran.com
Contact: Mr. Jeff Sloan
Service: Manufacturer of the “Sno-Gun” carbon dioxide pelletizing and blasting equipment.


Sources:

Ms. Terry Taylor, Material Engineering Lab, NADEP Jacksonville, August,1998.
Mr. David Robinson, Unit Environmental Coordinator, OC-ALC/TIPE, Tinker AFB, OK, January,1998.
Mr. Pete Mullenhard, GEO-CENTERS, Inc., August,1998.
Mr. Jim Sloan, Va-Tran Systems, Inc., January,1998.
Mr. Jeff Sloan, Va-Tran Systems, Inc., May 1996.


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