Table 6-4 Factors which affect corrosion in water systems.

FACTOR

DEFINITION — CORROSION INFLUENCE

CONTROL

Dissolved Oxygen (DO)

Scale: 0-12 (mg/l). Defines oxygen gas dissolved in water (normal range = 3-9 mg/l).
Corrosivity increases with DO.

Very difficult to control in open systems. CAP water has higher levels (9-10 mg/l) than groundwater (~6 mg/l).

pH

Scale: 1-14 (s.u). Defines amount of free acidity in water. Log scale of acid concentration. One (1) unit decrease corresponds to a 10-fold increase in acid concentration. Normal range in groundwater and surface water: 6.5-8.5. Usually, higher pH means higher alkalinity.
Corrosivity increases with decreasing pH.

Relatively easy to control in water with low to moderate alkalinity. Requires the addition of chemicals such as lime.

Total Dissolved

Solids (TDS)

Scale: 0-? (mg/l) Refers to amount of dissolved minerals in water: ninety percent or more of TDS in natural waters includes the following elements:
Sodium, calcium, magnesium, potassium, chloride, sulfate, carbonate.
These elements are from table salt, gypsum, calcite and other minerals.
In general, corrosivity increases with TDS, depending on alkalinity.

Moderately easy to very difficult to change.

Dilution: easy.

Removal by filtration: moderately difficult and expensive.

Alkalinity

Scale: 0-? (mg/l as CaCO3). Refers to concentration of carbonates and bicarbonates present in water.
In general, corrosivity decreases with increasing alkalinity. Note: excessive calcium carbonate scale can clog pipes.

Moderately easy to change. Requires addition of acid or base (alkaline) chemicals.

Temperature

(Degrees Centigrade). Varies with season and location.
Corrosivity can increase or decrease, depending on alkalinity and temperature range. Note: higher temperatures increase metal oxidation rates, but they also increase scale formation by calcite precipitation.

Cannot be controlled.
Groundwater temperature is more constant (~20-30°C)
CAP fluctuates with ambient (~10-40°C)

Type of pipe

In general, metal pipes corrode and plastic pipes do not.
Most corrosive pipe: galvanized iron, galvanized steel, aluminum, iron.
Least corrosive pipe: plastic, stainless steel, copper.
Note: zinc metal corrodes much faster than iron, which helps protect
iron from corrosion in galvanized iron pipes.

Controllable in new homes.
Use of plastic pipes restricted by codes.
Can be expensive to retrofit.
Use of corrosion inhibitors such as polyphosphate.

Water Velocity

Corrosivity may increase at high velocity due to turbulence that helps DO react faster with the metal surface. However, at high velocity, faster scale formation of CaCO33 (a corrosion inhibitor) may also occur.

May be controllable through pipe design changes and use of low water use appliances, faucets, shower heads, etc.

Hardness

Hardness refers to the concentrations of calcium and magnesium ions, but is usually reported in mg/l of CaCO3. Water hardness is linked to scale formation and the reduced cleaning efficiency of soaps.

Hardness is linked to scale formation; therefore, in pipes hard water is less corrosive than soft water..





Through water softening and salt removal techniques.