INTERNATIONAL CLEANER PRODUCTION INFORMATION CLEARINGHOUSE

Case Study #272

1. Headline: Internal recycling in a flexographic printing

facility reduces effluents

2. Background: Further to the adoption of flexographic

printing, the Cartonnages de l'Agenais studied how to

recycle the printers washing water to overcome pollution

and effluents coloring. A technique using ultrafiltration

was selected. This case study was carried out in 1992.

3. Cleaner Production Principle: internal recycling

4. Description of Cleaner Production Application:

Information about the process and wastes

The flexographic inks contain organic pigments without any

heavy metals. The washing water (1.5 m3/day), containing 1

% of ink can not be discharged outside due to its color, a

rate of suspended matter over 200 mg/l, and a COD over 400

mg/l.

The company has installed ultrafiltration enabling it to

reuse the purified water and to treat only a concentrated

effluent.

The process is based on ultrafiltration using mineral

membranes operating in tangential flow. The turbulent

brushing of the membrane surface prevents particles from

accumulating and clogging, which renders useless the

cleaning processes with chemical reagent.

Both modules with mineral membranes CARBOSEP enable 6 to 8

m3 a week to be treated. The high thermal, chemical and

mechanical resistance of the mineral membranes offers

almost total protection in case of accidental pollution.

The facility is entirely automated.

Level of marketing: The TECH-SEP company has built an

industrial prototype, the first facility able to treat

water containing ink using ultrafiltration by means of a

mineral membrane in tangential flow.

Material / energy balance and substitution

Drinking water saving : 400 m3/year.

5. Economics:

Cost of direct investment

Civil engineering

32 000

2 ultrafiltration modules 227 000

Accessories and miscellaneous 61 000

Total

320 000 FF (1992)

Operation and maintenance costs

Energy and reagent

9 200 FF

Maintenance

7 000 FF

Concentrate transportation 7 200 FF

Null amortization due to the subsidies received.

Water saving

1 500 FF

Pollution saving

40 500 FF (1992)

Period of amortization: 2 years.

6. Advantages: Suppression of any external discharge and

any risk of pollution.

No use for cleaning nor treatment reagent.

Drinking water resources saving.

Technique can be reproduced on any ink discharges.

7. Constraints: No information provided.

8. Contacts:

Agence de l'Eau Adour-Garonne

M. RAUCOULES

TEL: 33 61.36.37.38

M. J.C. RIVES

PrÆsident Directeur GÆnÆral

Cartonneries de l'Agenais

B.P. 11

82410 VALENCE D'AGEN - France

TEL: 33 63.39.51.27

S.A. Cartonnages de l'Agenais

Chemin d'Orliac

82400 VALENCE D'AGEN - France

TEL: 33 63.39.51.27

FAX: 33 63.29.18.80

M. Maton

M. Chatenet

Office International de l'Eau

Direction de la Formation et des Etudes

rue Edouard Chamberland

87065 Limoges Cedex, France

TEL: 33 55114770

FAX: 33 55777115

9. Keywords: France, ISIC 3411, ISIC 3412, ISIC 3420,

printing, recycling, ultrafiltration, heavy metal,

membrane, ink, flexographic printing, filtration

10. This case study was submitted to UNEP IE in 1994 by the

French Office International de l'Eau. It has not undergone

a formal technical review.