CASE STUDY #126
1. Headline: Outokumpu flash smelting process for copper
allows high sulphur recovery, efficient energy
utilization, and flexibility in varied feed material.
2. Background: See below.
3. Cleaner Production Principle: new technology
4. Description of Cleaner Production Application: The
Outokumpu flash smelting process combines the conventional
operations of roasting, smelting and partial converting
into one process. Preheated oxygen-enriched air is used
to provide heat such that additional fuel is not required
for the reactions to proceed. Copper concentrate is
recovered from the slag and recycled through the smelter.
The clean slag is sent for disposal. Heat and dust are
recovered from the smelter gases producing dust for
recycle to the smelter, and SO2 gases for production of
sulfuric acid. The matte is further treated in
conventional converters to obtain blister copper.
Material/Energy Balance and Substitution
FEEDSTOCKS: Ore concentrate, fuel, electrical energy,
oxygen-enriched air, silica flux
WASTES: Gaseous stream of 10-30% SO2 for use in sulfuric
acid plant, particulates in gas stream (6-7% of the feed),
slag from electric furnace
MEDIUM: Gaseous, solid
5. Economics
OPERATION/MAINTENANCE: 61.0 cents/kg (27.7 cents/lb)
DISPOSAL & FEEDSTOCK: Operating costs reduced to 61.0
cents/kg from 97.8 cents with conventional process
6. Advantages:
FEEDSTOCK REDUCTION: Energy consumption is about 20 to
30% of that required by a conventional furnace
WASTE PRODUCTION: 50-80% recovery of sulfur from the
concentrate for use in sulfuric acid production,
eliminating SO2 emissions to the environment. Slag
cleaning reduces copper content from 24% to <0.6% prior to disposal, eliminating liquid run-off from granulation pond IMPACT: The main advantages of the Outokumpu process are the high sulphur recovery, the efficient energy utilization, and the flexible process in terms of accepting a varied feed material. 7. Constraints: No information provided. 8. CITATION/PAGE: Compendium on Low and Non-waste Technology, United Nations Economic and Social Counsel, "Primary Copper Production Using the Outokumpu Flash Furnace", Monograph ENV/WP.2/5/Add.115 9. Keywords: metal, copper, copper smelting, new technology, sulfur, heating, sulfuric acid, oxygen-enriched air, energy saving, fuel, ISIC 3720. 10. Reviewers Comments: This case study was originally abstracted for the US EPA Pollution Prevention Information Clearinghouse. It underwent a UNEP IE funded technical review in 1994 for quality and completeness. It was edited for the ICPIC diskette in July 1995. ( DOCNO: 400-115-A-328 )