INTERNATIONAL CLEANER PRODUCTION INFORMATION CLEARINGHOUSE

CASE STUDY #126

1. Headline: Outokumpu flash smelting process for copper

allows high sulphur recovery, efficient energy

utilization, and flexibility in varied feed material.

2. Background: See below.

3. Cleaner Production Principle: new technology

4. Description of Cleaner Production Application: The

Outokumpu flash smelting process combines the conventional

operations of roasting, smelting and partial converting

into one process. Preheated oxygen-enriched air is used

to provide heat such that additional fuel is not required

for the reactions to proceed. Copper concentrate is

recovered from the slag and recycled through the smelter.

The clean slag is sent for disposal. Heat and dust are

recovered from the smelter gases producing dust for

recycle to the smelter, and SO2 gases for production of

sulfuric acid. The matte is further treated in

conventional converters to obtain blister copper.

Material/Energy Balance and Substitution

FEEDSTOCKS: Ore concentrate, fuel, electrical energy,

oxygen-enriched air, silica flux

WASTES: Gaseous stream of 10-30% SO2 for use in sulfuric

acid plant, particulates in gas stream (6-7% of the feed),

slag from electric furnace

MEDIUM: Gaseous, solid

5. Economics

OPERATION/MAINTENANCE: 61.0 cents/kg (27.7 cents/lb)

DISPOSAL & FEEDSTOCK: Operating costs reduced to 61.0

cents/kg from 97.8 cents with conventional process

6. Advantages:

FEEDSTOCK REDUCTION: Energy consumption is about 20 to

30% of that required by a conventional furnace

WASTE PRODUCTION: 50-80% recovery of sulfur from the

concentrate for use in sulfuric acid production,

eliminating SO2 emissions to the environment. Slag

cleaning reduces copper content from 24% to <0.6% prior to disposal, eliminating liquid run-off from granulation pond IMPACT: The main advantages of the Outokumpu process are the high sulphur recovery, the efficient energy utilization, and the flexible process in terms of accepting a varied feed material. 7. Constraints: No information provided. 8. CITATION/PAGE: Compendium on Low and Non-waste Technology, United Nations Economic and Social Counsel, "Primary Copper Production Using the Outokumpu Flash Furnace", Monograph ENV/WP.2/5/Add.115 9. Keywords: metal, copper, copper smelting, new technology, sulfur, heating, sulfuric acid, oxygen-enriched air, energy saving, fuel, ISIC 3720. 10. Reviewers Comments: This case study was originally abstracted for the US EPA Pollution Prevention Information Clearinghouse. It underwent a UNEP IE funded technical review in 1994 for quality and completeness. It was edited for the ICPIC diskette in July 1995. ( DOCNO: 400-115-A-328 )