Product Substitution

November 1998 - TI#17739
"I Need a Substitute for 1,1,1-Trichloroethane..."
Drivers for Product Substitution
-HAZMAT Reduction Programs
-ODS Reduction Programs
-OtherDrivers
Potential Future Drivers for Product Substitution
-Revised AFI 32-7080
-Global Climate Change
Evaluating and Selecting Potential Alternatives
-Step 1: Defining How The Product Is Used
-Step 2: Searching for Potential Alternatives
-Step 3: Testing of Potential Alternatives
-Step 4: Implementing the Chosen Alternative(s)
Product Substitution Initiatives for Weapon Systems
-The Role of the Single Manager
-The HAZMAT Reduction Prioritization Process (HMRPP)
-Product Substitution Tools for Single Managers
Document References


"I Need a Substitute for 1,1,1-Trichloroethane..."
Since its inception in October 1992, PRO-ACT has responded to over 16,000 requests for technical assistance and research from its Air Force customers. During that time, over 2,400 of these requests, similar to the one above, have been for product substitutions.

Product substitution requests are submitted to PRO-ACT by customers representing all levels of the Air Force organization. These customers serve in a wide range of technical activities such as bioenvironmental engineering, supply, transportation, maintenance, and civil engineering. The majority of product substitution requests involve processes that are not governed by Technical Orders (T.O.s) or Military Specifications (MILSPECs). In these instances, PRO-ACT has a great deal of latitude in identifying and recommending one or more "environmentally friendly" substitute products. However, in those instances where the use of a product/material is mandated by a MILSPEC and/or T.O., PRO-ACT cannot recommend an "environmentally friendly" alternative product and the "environmentally dirty" product must continue to be used.

PRO-ACT serves as the Air Force's full-service, environmental information clearinghouse and research center and operates under the direction of the Air Force Center for Environmental Excellence, Environmental Quality Directorate (HQ AFCEE/EQ). As part of this service, PRO-ACT assists its Air Force customers in finding "environmentally friendly" substitutes for products containing ozone depleting substances (ODSs), EPA-17 industrial toxics, toxic release inventory (TRI) listed chemicals, and other hazardous materials (HAZMATs).

The Air Force has recognized the need to update MILSPECs and T.O.s to eliminate the use of those products/materials that pose a serious risk to people and the environment. To meet this need, the Air Force developed the Weapon System Hazardous Materials Reduction Prioritization Process (HMRPP). Under the HMRPP, input is received from the weapon system user community and used to assist Air Force Single Managers in prioritizing and selecting substitute products/materials for the hazardous materials currently mandated in their MILSPECs and T.O.s.

The purpose of this Fact Sheet is to increase Air Force awareness of the requirements that drive the continuing need to reduce the Air Force's use of "environmentally dirty" chemicals. Information is provided about the process employed by PRO-ACT to identify and recommend potential alternative products in support of these Air Force requirements. In addition, information is provided about the HMRPP and the roles that base-level hazardous material (HAZMAT) users and Air Force Single Managers play in revising T.O.s and MILSPECs.


Drivers for Product Substitution
This section presents a historical account of the Federal, Department of Defense (DoD), and Air Force drivers for the reduction of HAZMAT and Ozone Depleting Substances (ODSs) used by Air Force activities. It highlights the evolutionary process the Air Force has taken from its initial efforts at focusing on specific chemical lists to the current "risk and compliance-based" approach of the HMRPP.

HAZMAT Reduction Programs
In an effort to reduce the national aggregate release of certain toxic chemicals into the environment, the United States Environmental Protection Agency (EPA) launched its voluntary 33/50 Program in January 1991. Seventeen high-priority toxic chemicals were selected from the existing Toxic Release Inventory. (The TRI is a list of chemicals established in 1988 by the EPA. Releases of TRI chemicals are reported annually to EPA by industrial facilities under the Emergency Planning and Com-munity Right-to-Know Act, or EPCRA.) These 17 chemicals, commonly referred to as EPA-17 chemicals, were selected for reduction based upon their toxicity, high volume production/emission, and high potential for successful reduction through pollution prevention initiatives.

As reflected in its name, the 33/50 Program established an interim goal to achieve a 33% reduction in releases and off-site transfers of EPA-17 chemicals by the end of 1992 (from a 1988 base-line), and a final goal to achieve a 50% reduction by the end of 1995, at which time the 33/50 Program would end.

EPA-17 Chemicals
  • Benzene
  • Cadmium & Compounds
  • Carbon Tetrachloride
  • Chloroform
  • Chromium & Compounds
  • Cyanides
  • Methylene Chloride
  • Lead & Compounds
  • Mercury & Compounds
  • Methyl Ethyl Ketone
  • Methyl Isobutyl
  • Ketone
  • Nickel & Compounds
  • Tetrachloroethylene
  • Toluene
  • 1,1,1-Trichloroethane
  • Trichloroethylene
  • Xylenes
Although not an official participant, the Air Force made a commitment to the spirit of EPA's 33/50 Program with the publication of the Joint Secretary of the Air Force/Air Force Chief of Staff "Air Force Pollution Prevention Program - Action Memorandum" and attached "Pollution Prevention (P2) Program Action Plan" in January 1993. Among the Plan's objectives were directives for all Major Commands (MAJCOMs) to: 1) reduce the use of HAZMATs in all phases of new weapon systems; 2) integrate fewer HAZMATs into new and existing weapon system T.O.s, MILSPECs, and Military Standards (MILSTDs); 3) accelerate replacement of HAZMATs in Air Logistics Center industrial processes; and 4) reduce purchases of EPA-17 chemicals 50% (from a 1992 baseline) by the end of 1996.

An overarching policy for hazardous material reduction and pollution prevention was first outlined in Air Force Policy Directive (AFPD) 32-70, "Environmental Quality," 20 July 1994, which states "...the Air Force will prevent future pollution by reducing use of hazardous materials and releases of pollutants into the environment to as near zero as possible.through source reduction, e.g. chemical substitution, process change and other techniques." Requirements for the Pollution Prevention Program set forth in AFPD 32-70 can be found in Air Force Instruction (AFI) 32-7080, "Pollution Prevention Program," 12 May 1994. This AFI outlines guidance and procedures and provides a framework for MAJCOMs and installations to ensure compliance with pollution prevention standards. The January 1993 Joint Secretary of the Air Force/Air Force Chief of Staff Action Memorandum was updated with a new Joint Memorandum, "Air Force Pollution Prevention Strategy," issued on 24 July 1995. This Air Force Strategy promotes the minimization of HAZMAT use and releases by encouraging broad institutional changes in awareness/education, processes/systems design, and policy/procedure development. In 1996, the Department of Defense (DoD) published a new Pollution Prevention Instruction (DODI 4715.4). This instruction contains policy for implementation of pollution prevention programs throughout the DoD, namely to ensure that installations comply with applicable environmental laws, regulations, Executive Orders, and standards. Similar to the strategy contained in the July 1995 Joint Air Force Memorandum, DODI 4715.4 sets a broad policy to reduce the use of HAZMATs, reduce the generation/release of pollutants, and reduce any adverse effects on human health and the environment caused by DoD activities.

Finally, the Air Force issued AFI 32-7086 "Hazardous Materials Management" on 1 August 1997. This AFI, which further implements the above-mentioned AFPD 32-70, establishes new procedures and standards that are revolutionizing the management of HAZMATs throughout the Air Force. Included in this AFI are chapters on the HAZMAT Pharmacy, Ozone Depleting Substance (ODS) Management, and the Hazardous Materials Management Process (HMMP).

The HMMP provides for the identification, management, tracking, and minimization of hazardous materials. It consists of three main, interrelated components: the installation HAZMAT Pharmacy Program (HPP), the weapon system HAZMAT Reduction Prioritization Process (HMRPP), and the ODS Management Program. The AFI defines HAZMAT to include both Class I and Class II ODSs; however, it excludes hazardous wastes, munitions, and pharmaceuticals. An important aspect of the AFI is that it identifies cross-functional cooperation as the key to effective HAZMAT management and establishes formal cross functional HMMP teams at all levels of command in the Air Force. To ensure senior leadership visibility and support, these HMMP teams report directly to the chairperson of the Environment, Safety and Occupational Health Committee (ESOHC) or Environmental Protection Committee (EPC), typically the installation Vice-Commander.

The HMRPP links installation HAZMAT reduction needs with the weapon system operations and maintenance processes and the single managers that drive most of the hazardous material usage at Air Force installations. This linkage is critical because installations have the information necessary to be able to identify weapon system HAZMAT usage requirements that are creating unacceptable environment, safety, and occupational health (ESOH) compliance problems and costs at the base level. Conversely, single managers have the authority to change the weapon system technical documents that contain the HAZMAT usage requirements. Single managers must ensure that any change to a documented weapon system operations or maintenance process does not compromise mission capability or increase ESOH risks and costs.

ODS Reduction Programs
National and international scientific consensus exists in support of controlling, reducing, and/or eliminating the release of certain manufactured halogenated hydrocarbons that may contribute to the depletion of the Earth's stratospheric ozone layer. The stratospheric ozone layer protects the Earth from harmful ultraviolet (UV-B) radiation. The United Nations Environmental Program (UNEP) began negotiations to develop multilateral policies to protect the ozone layer in September 1987. Delegates from 43 nations signed the Montreal Protocol on Substances that Deplete the Ozone Layer, which was the first international treaty to address reducing the production and consumption of ozone depleting substances. The ultimate goal of the Protocol was to eliminate, with limited exceptions, the global use of ODSs in accordance with an agreed-upon phase-out schedule.

To implement and comply with the Protocol in the United States, as well as to enact certain sections of the Clean Air Act Amendments of 1990, the EPA published Subpart A, "Production and Consumption Controls," to Title 40 Code of Federal Regulations (CFR) Part 82, "Protection of Stratospheric Ozone." Subpart A imposes limits, according to specified schedules, on the production, consumption, and release of Class I and Class II ODSs and applies to any person that produces, transforms, destroys, imports, or exports certain ODSs. In October 1993, the EPA added Subpart D, "Federal Procurement," to Title 40 CFR Part 82. Subpart D requires Federal agencies to adopt procurement regulations which conform to the policies and requirements of Title VI of the Clean Air Act and which maximize the substitution in Federal procurement of safe alternatives for Class I and Class II ODSs.

Subpart G, "Significant New Alternatives Policy (SNAP) Program," was added to Title 40 CFR Part 82 in March 1994 and implements Section 612 of the Clean Air Act. The objectives of the SNAP Program are to identify substitutes for Class I and Class II ODSs, evaluate the acceptability of those substitutes, promote the use of substitutes presenting lower overall risks to human health and the environment, and prohibit the use of substitutes found to increase overall risks.

On 21 April 1993, the President signed Executive Order (EO) 12843, "Procurement Requirements and Policies for Federal Agencies for Ozone Depleting Substances." This EO requires Federal agencies, including the military services, to provide leadership in the phase-out of ODSs through compliance with the Montreal Protocol and to "reduce procurement and use of substances that cause stratospheric ozone depletion."

The previously mentioned January 1993 Joint Secretary of the Air Force/Air Force Chief of Staff Action Memorandum was published in anticipation of EO 12843. In addition to the HAZMAT guidance discussed above, this Memorandum imposed specific ODS purchase restrictions on the Air Force, with effective dates in 1993 and 1994. Certain applications deemed "mission critical" could continue to use Class I ODSs (obtained from a defense reserve supply established and maintained by the Defense Logistics Agency) if a waiver for the application had been approved by an Air Force Senior Acquisition Official (SAO). The Memorandum further outlined Air Force policy for minimizing the use of ODSs in the maintenance, disposal, design and acquisition of equipment.

As mentioned above, AFI 32-7080 requires MAJCOMs to execute Pollution Prevention Management Plans containing strategies for seven program elements, one of which is "Ozone Depleting Chemicals." AFI 32-7080 requires all MAJCOMs to: 1) prohibit the purchase of all Class I ODSs; 2) prohibit the purchase of halon fire extinguishing equipment and ODS air conditioning and refrigeration equipment for ground applications; 3) modify practices and implement conservation measures to reduce atmospheric discharge of ODSs; and 4) prioritize ODS use based on mission impact and act to convert such systems to non-ozone depleting chemicals.

Chapter 4 of AFI 32-7086 establishes the Air Force ODS Management Program, which is designed to mitigate risks to Air Force capability and reduce costs associated with continued reliance on ODSs. The objectives of the ODS Management Program include: 1) eliminating ODS usage wherever economically and technically feasible; 2) managing the allocation of mission critical Air Force supplies of Class I ODS; and 3) minimizing the release of ODSs into the environment. The program covers both facility and weapon system Class I and II ODS requirements. The AFI states that existing facility equipment that uses Class I ODSs can continue to rely on the Class I ODS until the facility equipment reaches the end of its economic life, then it must be replaced with equipment that does not use a Class I ODS. Additionally, AFI 32-7086 prohibits new facility equipment from requiring the use of a Class I ODS.

The AFI only requires existing weapon systems to eliminate Class I ODS requirements when a technically and economically feasible substitute is available. The Air Force's Defense Reserve stockpile of Class I ODSs enables weapon system single managers to make business-based decisions that do not increase the ESOH risks and costs when considering conversion to non-ODS systems and processes. Thus, single managers and the Major Commands (MAJCOMs) that use the weapon system may decide to continue to rely upon Defense Reserve supplies of a Class I ODS rather than funding the sometimes significant cost of implementing a non-ODS alternative. This business-based decision process does not apply to new weapon systems. They are prohibited by the AFI from including requirements for Class I ODS usage in their operations and maintenance. AFI 32-7086 also defines the Air Force Senior Acquisition Official (SAO) approval process. This process requires that an Air Force SAO approve any requirement in a contract for the use of a Class I ODS, as well as all allocations of Class I ODSs from the Defense Reserve to MAJCOMs and single managers. Air Force SAO approving officials are restricted to only those general officers or civilian equivalents in HQ USAF/ILE (Civil Engineering), HQ USAF/ILM (Maintenance), and SAF/AQR (Science, Technology, and Engineering). All requests for SAO approvals must first be processed through SAF/AQRE.

In addition to the restrictions placed on the purchase and use of Class I ODSs, AFI 32-7086 also establishes new restrictions on Air Force usage of Class II ODSs. New facility equipment and weapon systems whose projected lives extend beyond the year 2020 may not include any requirements for Class II ODS usage in their operations or maintenance. MAJCOMs and single managers are also tasked with eliminating existing requirements for Class II ODSs before production phase outs occur since the Air Force does not intend to stockpile Class II ODSs. Most Class II ODS production will phase out incrementally between 2004 and 2030; however, because of its high Ozone Depleting Potential, production of the solvent HCFC-141b will be phased out by 1 January 2003.

Other Drivers
The need to find acceptable product substitutions may also be driven by the requirements of other Federal mandates. For example, an installation may want to reduce the use of a particular chemical in order to avoid reporting requirements under EPCRA or Section 102(a) of the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). Eliminating the need to obtain a National Pollutant Discharge Elimination System (NPDES) permit as required under the Clean Water Act (CWA) may also be a driver for reducing use of a specific chemical.

Additional drivers for product substitutions may come from provisions of the Clean Air Act. In response to EPA's National Ambient Air Quality Standards in Title 40 CFR Part 50 as required by Section 109 of the Clean Air Act, various federal, state, and local governments have established regulations to control emissions of volatile organic compounds (VOCs), which contribute to the formation of ground-level ozone. Section 112 of the Clean Air Act requires the EPA to develop National Emission Standards for Hazardous Air Pollutants (NESHAPs) to regulate hazardous air pollutant emissions from certain source categories, including the aerospace industry. Emission requirements for the aerospace industry can be found in Title 40 CFR Part 63, Subpart GG, "National Emission Standards for Aerospace Manufacturing and Rework Facilities." By reducing HAZMAT usage, the overall impact of these other drivers may be reduced or eliminated.

MAJCOMs may also develop specific initiatives that establish HAZMAT and/or ODS reduction goals over and above those set by existing Federal and Air Force requirements. In addition, States and local governments may establish similar policies and initiatives that apply to particular communities or geographic regions. It is important that each installation's environmental management staff consult with MAJCOM and State/local agencies to ensure compliance with all applicable regulations requiring reductions in HAZMAT and ODS use. Installations can also obtain assistance from an AFCEE Regional Environmental Office (REO).


Potential Future Drivers for Product Substitution
Revised AFI 32-7080
AFI 32-7080, "Pollution Prevention," is currently under revision to more closely incorporate the concept of "Compliance Through Pollution Prevention" (CTP2). Although the goals to be included in the new AFI have not been finalized, early drafts indicate that they will be quite different from those in the current AFI. Rather than targeting specific chemical lists such as the EPA-17 and the TRI, the revised AFI will likely focus on reducing all HAZMATs, and on allowing installations and MAJCOMs to set their own priorities based upon usage, risks, and costs. Early drafts also indicate the criteria for measuring progress will also change, for example, from simply measuring the total amount of waste disposed, to measuring specific indicators such as reductions in the total number of discharge permits and/or reductions in the number of source sites which feed the permitted discharges.

Global Climate Change
A large number of scientists worldwide have concluded that increased emissions of "greenhouse gases" into the Earth's atmosphere over the last century are responsible for significant changes in global climate. Greenhouse gases are produced primarily by fossil fuel combustion, evaporative emissions from fuels, industrial processes, solvent use, agriculture, and waste incineration. Atmospheric greenhouse gases cause infrared solar radiation to be "trapped" at the Earth's surface instead of being reflected back into space, and some data indicate the average global surface temperature has increased by 0.5øF to 1.1øF over the last century.

Greenhouse Gases
  • Carbon dioxide (CO2)
  • Methane (CH4)
  • Nitrous oxide (N2O)
  • Hydrofluorocarbons (HFCs)
  • Perfluorocarbons (PFCs)
  • Sulfur hexafluoride (SF6)
  • In response to the threat of global climate change, many international, national and local efforts have been focused on reducing global greenhouse gas emissions in accordance with specified target levels and schedules. The most recent effort was the Kyoto Protocol to the United Nations Framework Convention on Climate Change, held in December 1997. The primary objective of the Kyoto Protocol was to stabilize atmospheric concentrations of greenhouse gases consistent with sustainable economic development. The Convention required policy makers to decide on concrete actions and choose the level at which to stabilize atmospheric concentrations, a schedule for limiting greenhouse gas emissions, and appropriate technologies and policies for meeting this schedule.

    Currently, many States are developing greenhouse gas inventories. Inventories identify major emission sources and help create a baseline upon which to base future reduction strategies. The Federal government is responsible for developing National policy to address climate change; however, the States will be key players, given their expert knowledge about their own needs and conditions.

    A "Fact Sheet on Federal Energy Management," produced by the White House Initiative on Global Climate Change, outlines future initiatives to reduce emissions of greenhouse gases from Federal facilities through enhanced focus on energy efficiency, renewable energy, and sustainable building construction. It further states that "Federal agencies will be required to assess their greenhouse gas emissions in major actions they undertake." Products currently used by the Air Force that contribute to emissions of greenhouse gases (fuels and solvents) will be clear targets for continued replacement or reduction in the future.


    Evaluating and Selecting Potential Alternatives
    As discussed above, there are many Federal, DoD, and Air Force drivers for controlling, reducing, and eliminating the use of "environmentally dirty" chemicals and products. However, identifying which "environmentally friendly" products are potentially suitable as alternatives can be a difficult and complex task and there are many different approaches that can be used. Products for which substitutes are most frequently sought include cleaners, strippers, sealants, adhesives, coatings, and solvents.

    The stepped approach described below is presented as a "generic" example only and is based upon standard investigative protocols used by PRO-ACT in response to product substitution requests from Air Force customers. The specific elements within each step can vary significantly depending upon many factors, including the nature of the chemical itself and the manner in which it is being used. Individuals who need to evaluate and select potential product substitutions on their own are encouraged to establish and follow investigative protocols appropriate to their own unique needs. Of course, PRO-ACT (DSN 240-4240) is always available to provide product substitution services to the Air Force.

    Step 1: Defining How The Product Is Used
    The first step in the process of evaluating and selecting a product substitution is understanding the driving forces behind the need to find an alternative. Three key factors should be considered when searching for a potential substitute.

    First and foremost, is use of the product mandated by governing T.O.s or applicable MILSPECs? In other words, is it permissible to replace the product at all? T.O.s and MILSPECs applicable to specific tasks sometimes mandate the use of specially formulated products in order to meet crucial performance requirements.

    Regardless of any other factors, if a T.O. or MILSPEC governs a particular task, only products authorized by the T.O. and/or conforming to the MILSPEC for that task or product may be used. For example, MILSPEC MIL-C-81706, "Chemical Conversion Materials for Coating Aluminum and Aluminum Alloys" requires that products used in the applications governed by that MILSPEC be "formulated with chromates." Although chromate is an EPA-17 chemical, if it is substituted with a chromate-free chemical, the product would no longer conform to its governing MILSPEC.

    The second important factor to consider when searching for a potential alternative is to thoroughly understand how the product is currently being used. This includes identifying whether the product being considered for replacement is used in a single task, or in several different tasks. Unlike typical solvent-based cleaners that perform equally well in a variety of applications, many of the new and less polluting non-solvent cleaners may only perform in a limited range of applications. Therefore, if the product being replaced had been used in a variety of applications, it may be necessary to evaluate the different uses and select alternate products specific to each task.

    The third key factor to consider is the severity of the consequences if the current product is not replaced. Are there critical regulatory, health, or safety concerns, or is the current product simply no longer available through supply?

    Other factors to be considered when evaluating the suitability of an alternative might include:

    1. How critical is the step in the process where the current product is used?
    2. Are there critical performance standards associated with the product's use?
    3. What other steps in the process might be impacted by the substitute?
    4. What types of surfaces or materials does the current product come in contact with?
    5. Are the surfaces coated with paint, oil, a lubricant, or a sealant?
    6. Are there different types of materials such as aluminum, plastic, or rubber?
    7. How is the current product applied?
    8. Is it sprayed or wiped on a surface or material?
    9. Are there compatibility issues concerning the reaction or mixture of a substitute with other chemicals?
    10. What equipment is used in the application process?
    11. What safety and personal protective equipment are required in applying the current product?
    12. What are the time and labor requirements for using the current product?
    Step 2: Searching for Potential Alternatives
    Once it is understood how the product is used and its potential hazards are known, the next step in identifying a successful substitute is to search for potential alternative products. This step is often the most difficult and time-consuming part of the product substitution process because there are many sources of information to be searched. In conducting product substitution research, PRO-ACT routinely searches the following sources:

    Existing Records - As mentioned in this Fact Sheet's opening paragraph, PRO-ACT has conducted research and recommended product replacements in response to over 2,400 product substitution requests. The research results from these requests are stored in a PRO-ACT database that is searchable by key words, National Stock Numbers (NSNs), or weapon system Mission Design Series (MDS).

    Experts - An Item Manager is an equipment specialist, engineer, or inventory manager at an Air Logistics Center (ALC) or Single Manager's office, and may also be referred to as a Military or Federal Specification Manager. Item Managers are excellent sources of information. They are aware of substitute products approved for use, and those being evaluated for use, in specific applications. PRO-ACT also routinely consults with experts representing Headquarters Air Force Center for Environmental Excellence (HQ AFCEE), the Air Force Civil Engineer Support Agency (AFCESA), the National Defense Center for Environmental Excellence (NDCEE), the Defense Logistics Agency (DLA), the General Services Administration (GSA), the US Environmental Protection Agency (EPA), and other Federal, State, and local agencies.

    Product Manufacturers - Commercial and industrial sectors have been working to remove "environmentally dirty" chemicals from their products and processes for a number of years in response to consumer demand. Manufacturers often inform PRO-ACT when a new "environmentally friendly" product becomes available or when an existing product has been made "cleaner" through reformulation.

    Crossfeed Information - A number of other agencies and organizations collect, post, or otherwise compile and distribute product substitution information. Some of the sources PRO-ACT contacts are the DLA Defense Supply Center, Richmond (DSCR), the Hazardous Technical Information Service (HTIS), and the General Services Administration's Paints and Chemicals Commodity Center (PCCC). Various product substitution bulletin boards and World Wide Web sites are also consulted.

    When searching for potential alternatives, consideration should be given to health and safety concerns, as well as cost. For example, it might not be advisable to replace a product containing only 5% of an EPA 17 chemical with a product containing 30% benzidine. Although benzidine is not an EPA-17 chemical, it is a human carcinogen. PRO-ACT recommends that installations consult with their Bioenvironmental Engineer for health and safety information and guidance on use of potential substitute products.

    Step 3: Testing of Potential Alternatives
    Potential alternatives should always be thoroughly tested before they are put into general use. This does not mean that the testing should necessarily be done in a laboratory. Rather, it means that all potential substitute products should be tested under the same conditions as the product being replaced (e.g. removing the same contaminant from the same material at the same temperature, etc.). Sometimes testing shows that an alternative can be implemented as a simple "drop-in" or "one-for-one" exchange with the original product. Other times however, changes to the original task may be required to accommodate an alternative product. For example, suppose an aqueous-based cleaner is being tested as a substitute for a solvent-based cleaner that had been used to remove grease from steel rods. The drying times will probably be longer with the aqueous-based cleaner and there may be water spots left on the rods after they are dried. To shorten the drying time and eliminate the water spots on the rods it may be necessary to add a hot air drying step to the rod-cleaning task. In addition to determining potential changes to the task, the testing of alternatives also helps identify possible user concerns, such as odors. After testing is completed, one or more alternative products may be selected for use.

    Step 4: Implementing the Chosen Alternative(s)
    In accordance with the HAZMAT authorization process defined in AFI 32-7086, Bioenvironmental Engineering, Safety, and Environmental Management personnel must approve all product substitutions before they can be implemented. It is a good idea to involve these individuals as early as possible in the product substitution process to avoid selecting alternatives that will not be approved for use. In addition, user acceptance of the alternative product is very important in assuring its successful implementation. It may be necessary to conduct training on the proper use of the new product, including any changes to the existing task and solutions to any user concerns noted in the testing phase. It is also a good idea to discuss with the users why the new product is needed and how it relates to the installation's overall environmental goals.


    Product Substitution Initiatives for Weapon Systems
    As mentioned at the beginning of this Fact Sheet, when a T.O. or MILSPEC mandates the use of an "environmentally dirty" product/material, the use of alternative products is not authorized. Operational needs, flight safety considerations, high purchase/replacement costs, and other factors often demand high performance criteria for the products/materials used to maintain modern Air Force weapon systems. Sometimes the use of an "environmentally dirty" product must be continued because alternative products do not exist that can meet these critical performance standards. Other times, however, alternative products do exist that could be successfully substituted for "dirty" products if the T.O. or MILSPEC was changed to allow for their use.

    The Role of the Single Manager
    In general, Single Managers are responsible for the planning, development, sustainment, and evolution of Air Force products and systems. There are two types of Single Managers. The first is a System Program Director (SPD) who directs an Air Force System Program Office (SPO) and is responsible for overall program execution of a military weapon system. The second type of Single Manager is a Product Group Manager (PGM). Each PGM is responsible for a specific product group (e.g. avionics, engines, etc.) that supports one or more SPDs. Typically, a weapon system, such as an aircraft, will have a single lead SPD with airframe and systems integration responsibilities and several PGMs that provide various products. All Single Managers have specific requirements to identify and eliminate, as much as possible, the use of hazardous chemicals targeted for reduction.

    The Hazardous Materials Reduction Prioritization Process
    As mentioned above, AFI 32-7086 establishes procedures and standards that govern the management of hazardous materials in the Air Force. The Hazardous Materials Management Process (HMMP) consists of three functional areas: the Hazardous Materials (HAZMAT) Pharmacy Program, the ODS Management Program, and the weapon system Hazardous Materials Reduction Prioritization Process (HMRPP). The purpose of the HMRPP is to provide a formalized mechanism for MAJCOMs and installations to implement weapon system HAZMAT reduction efforts.

    The HMRPP begins with the identification, by base level HMMP teams, of candidate tasks and processes for reduction/elimination of HAZMATs. The identification of candidate tasks and processes is based on annual usage rates and costs associated with:

    • Procurement of the HAZMAT;
    • Compliance cost and liability;
    • Disposal of the waste products;
    • Purchasing, operating, and maintaining control equipment;
    • Purchasing personal protective equipment for users; and
    • Providing user medical surveillance.
    Candidate tasks and processes are forwarded from the installation HMMP teams to their MAJCOM's HMMP team, who in turn consolidates and prioritizes all candidates received from across the Command, and forwards them to the Headquarters Air Force Materiel Command (HQ AFMC) HMMP team. Candidate processes from across the Air Force are further consolidated by the HQ AFMC HMMP team and distributed to the appropriate Single Manager for action. The Single Managers then identify and evaluate potential alternatives (products, equipment, or process changes) based on the following considerations:
    • The initial costs associated with implementing the alternative;
    • The total life-cycle cost of the alternative;
    • The life-cycle cost of continuing to use the current product/material; and
    • The Environment, Safety, and Occupational Health (ESOH) risks and costs of the alternative.
    The Single Managers send back a prioritized listing of potential alternatives to the appropriate MAJCOM HMMP team. The MAJCOM team then decides which, if any, of the potential alternatives will be implemented and begins the funding process.

    Product Substitution Tools for Single Managers
    The process of identifying and evaluating potential alternatives can be a lengthy and arduous task for Single Mangers and their staffs. HQ AFMC has funded two tools designed to help the Single Manager identify and eliminate HAZMATs from T.O.s and MILSPECs: 1) The Portable Document Format HAZMAT Search Tool (PHAST); and 2) The Process and Potential Alternatives (PAPA) database.

    The PHAST Program
    Developed by AFMC's Environmental Integration Branch (HQ AFMC/EMB) and the Air Force Product Data Systems Modernization Program Office (HQ AFMC/PDSM), PHAST is designed to assist Single Managers in identifying the mandated use of "environmentally dirty" chemicals in their T.O.s and MILSPECs. PHAST is a computer program that "scans" electronic versions of these and other documents looking for keywords such as chemical and product names, and T.O. and MILSPEC numbers. The final output is a listing of all places where the selected keywords appear in the document. For example, T.O. #1 is searched for benzene, an EPA 17 chemical. At the end of the search, a list would be generated that shows all references in the T.O. to benzene, to products containing benzene, and to other T.O.s and MILSPECs referenced by T.O. #1 that contain benzene or other benzene-containing products.

    The PAPA Database
    Once the Single Managers have identified where a task or process directs the use of a targeted chemical in a T.O. or MILSPEC, the next step is to begin a process to identify potential alternative products. To help Single Managers and their staffs accomplish this, HQ AFMC/ENBE developed the Process and Potential Alternatives (PAPA) data file. The file contains information on "environmentally clean" alternative products and processes. Most of the information contained in the original file was obtained from AFMC sponsored crossfeed meetings, government and industry test reports, and national meetings.

    Maintenance of AFMC's PAPA data file was contracted to PRO-ACT who converted it to a database format. The PAPA database has since been updated with information from PRO-ACT's product substitution research efforts, bringing the total to over 1700 individual records. The new PAPA database format allows the user to conduct detailed searches with easy-to-use screen interfaces. A new search routine has also been included that allows users to find and rank potential alternatives by weapon system category (e.g. aircraft, electronic systems, and dedicated support equipment), general process (e.g. cleaning, bonding, and surface preparation), and specific process (e.g. degreasing metal parts, welding, and painting). The information contained in the new PAPA database is being continuously updated and supplemented, and is available through PRO-ACT to all Air Force Single Managers and their staffs. The PAPA database has been upgraded for installation on the World Wide Web and is currently undergoing testing.

    Substituting chemicals/products for more "environmentally friendly" alternatives can be an effective means for reducing both the costs and the environmental and health related risks associated with using hazardous materials. Identifying acceptable alternatives is a cooperative effort involving the users, base and MAJCOM-level environmental professionals, and Air Force Single Managers and their staffs. As an Air Force environmental information clearinghouse and technical research service, PRO-ACT stands ready to assist the Air Force community in meeting its hazardous material usage reduction goals both now and in the future.


    Document References
    1. "Procurement Requirements And Policies For Federal Agencies For Ozone-Depleting Substances," Executive Order 12843, 21 April 1993.
    2. "EPA's 33/50 Program Final Report," United States Environmental Protection Agency, Office of Pollution Prevention and Toxics, March 1999.
    3. "Comprehensive Pollution Prevention Strategy," Secretary of Defense Memorandum, 11 August 1994.
    4. "Pollution Prevention," Department of Defense (DoD) Instruction No. 4715.4, 18 June 1996.
    5. "Air Force Pollution Prevention Program - ACTION MEMORANDUM," Joint Air Force Chief of Staff and Secretary of the Air Force Memorandum, 1 January 1993.
    6. "Air Force Pollution Prevention Strategy," Joint Air Force Chief of Staff and Secretary of the Air Force Memorandum, 24 July 1995.
    7. "Environmental Quality," Air Force Policy Directive (AFPD) 32-70, 20 July 1994.
    8. "Pollution Prevention Program," Air Force Instruction (AFI) 32-7080, 12 May 1994.
    9. "Compliance through Pollution Prevention," DRAFT AFI 32-7080, October 1997.
    10. "Hazardous Materials Management," AFI 32-7086, 1 August 1997.
    11. "Ten Years of the Montreal Protocol," United Nations Environmental Programme, Environmental and Societal Impacts Group, UNEP/ESIG Network Newsletter, Volume 13, Number 1, Oct - Dec 1997.
    12. "Protection of Stratospheric Ozone," Title 40 Code of Federal Regulation (CFR) Part 82, 1 July 1997.
    13. "National Primary and Secondary Ambient Air Quality Standards," 40 CFR Part 50, 26 Feb 1999
    14. "National Emission Standards for Aerospace Manufacturing and Rework Facilities," Title 40 CFR Part 63, Subpart GG, 1 July 1998
    15. "Kyoto Protocol to the United Nations Framework Convention on Climate Change," Conference of the Parties, Third Session, 10 December 1997.
    16. "The EPA Global Warming Site," http://www.epa.gov/globalwarming.
    17. "Ozone Depletion," EPA, http://www.epa.gov/ozone/.