Pollution Prevention Case Study

Northern Precision Casting

Replacing 1,1,1-Trichloroethane (TCA)
with Citrus-Based Solvents

Standard Industrial Classification (SIC) Investment Casting/3324
Process Solvent cleaning of wax pattern assemblies used in the investment casting process.
Type of Waste Fugitive emissions of 1,1,1-Trichloroethane (TCA)
Strategies Material Substitution - Solvent Replacement
Background Northern Precision Casting (NPC) is an investment casting operation located in Lake Geneva, Wisconsin. NPC employs over 150 people and casts more than 200,000 pounds of metal in a month.

The casting process at NPC involves pouring molten metal into ceramic molds. The ceramic molds are made by coating a wax pattern assembly with ceramic material. In order to have the ceramic coatings adhere to the wax material, it is necessary to clean the wax surfaces.

NPC cleaned the wax assemblies by washing them in solvent 1,1,1-Trichloroethane (TCA). The TCA would then evaporate leaving a clean wax surface for the ceramic coating process. NPC had TCA emissions of 18000 pounds (1988) as a result of this process.

Motivation Northern Precision Casting was motivated to change by the concern for environmental regulations pertaining to their TCA emissions.
Changes Implemented Northern Precision Casting told it's solvent manufacturer that they wanted to eliminate TCA from the wax cleaning process. The manufacturer suggested Freon as a substitute until a more suitable alternative could be identified. NPC went along with the freon substitution on a temporary basis since the emission levels were less than the TCA material. NPC used freon for six to nine months before the chemical manufacturer provided a citrus-based non-hazardous solvent. The citrus-based solvent has been very effective in cleaning the wax assemblies.
Problems Encountered There was significant concern about the potential impact of the change on product quality. However, after the solvent substitution, no change in quality was encountered. Initially, the citrus-based solvent had an odor that was offensive to the workers. This problem has been resolved.
Material/Energy Balance Original Process

Feedstock
Trichloroethane (TCA) - 18,000 pounds (1988)

Waste
TCA fugitive air emissions - 18,000 pounds (1988)

Disposal
Released from plant as fugitive air emissions

Pollution Prevention Approach

Feedstock
Latrex citrus-based solvent

Waste
Water-soluble liquid waste

Disposal
Discharged to Publicly-Owned Treatment Works (POTW)

Economics Capital Cost
No capital cost was involved

Operating/Maintenance Cost
There was no significant change in O/M cost.

Payback Period
Not available

Company Address Northern Precision Casting
Hwy. 36 N./P.O. Box 580
Lake Geneva, WI 53147
Contact Person Mr. Jerrie Brown,
Vice President - Operations
Phone: 414/248-4461
Additional Publications available from Pollution Prevention Clearinghouse Aqueous Industrial Cleaning Chemicals
DNR Publication #SW-147

Aqueous Parts Washing Equipment
DNR Publication #SW-148

GE Medical Systems Case Study
DNR Publication #SW-168

Pollution Prevention Resources Free, On-site Technical Assistance
University of Wisconsin Extension
Solid and Hazardous Waste Education Center
Milwaukee area: 414/475-2845
Remainder of state: 608/262-0385

Pollution Prevention Clearinghouse
Wisconsin Department of Natural Resources
Hazardous Waste Minimization Program
608/264-8852, 608/267-9523 or 608/267-3763

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Bureau of Cooperative Environmental Assistance
Wisconsin Department of Natural Resources
P.O. Box 7921
Madison, WI   53707
608/267-9700

PUBL-SW-161 95