North Carolina Regulatory Programs To Protect Groundwater


Prepared by:
David E.M. Patte and Leon E. Danielson


Published by: North Carolina Cooperative Extension Service

Publication Number: RE-10

Last Electronic Revision: March 1996 (JWM)


North Carolina's groundwater protection policies are implemented by several regulatory and nonregulatory programs. This publication describes some of the most important groundwater protection programs in North Carolina: (1) groundwater classifications and quality standards; (2) agricultural groundwater protection programs; (3) the underground storage tank program; and (4) the drinking water regulatory program. It is beyond the scope of this publication to discuss the solid waste, hazardous waste, and Superfund programs, all of which include groundwater protection provisions.

Groundwater Standards and Classifications

Groundwater standards and classifications provide a mechanism for the state to determine which activities require monitoring for groundwater quality, which groundwaters are contaminated, and to what degree contaminated groundwater must be restored. North Carolina's groundwater protection policy was significantly changed in July 1989 by the Environmental Management Commission to include new groundwater standards and classifications (see 15 NCAC 2L .0101 et seq.).

Groundwater Classifications

The new (1989) classifications for groundwater are defined as follows: GA waters - existing or potential source of drinking water supply for humans. This includes waters that require treatment to improve quality related to natural conditions (e.g., overcoming naturally occurring levels of iron or manganese). These waters naturally contain 250 mg/l or less of chloride.

GSA waters - existing or potential source of water supply for potable mineral water and conversion to fresh waters. These waters naturally contain greater than 250 mg/l chloride and also do not meet the dissolved solids quality criteria. (These are the saline waters common to coastal areas.)

GSC waters - Source of water supply for purposes other than drinking. This class includes those groundwaters that do not meet the quality criteria, and for which efforts to restore waters to a higher dassification are not technologically feasible.

Water Quality Standards

Groundwater quality standards are maximum allowable concentrations for 74 parameters which have been set based on primary and secondary drinking water standards, taste and odor thresholds, health advisories, and an incremental lifetime cancer risk of one additional case in a million. This includes 17 agricultural pesticides, nitrate, and nitrite (see figure 2). The standards apply equally to all classes of groundwater.

GA waters must meet quality standards for all 74 substances. GSA waters must meet quality standards for all parameters except chloride and dissolved solids. GC waters contain substances which do not meet quality criteria and which cannot be restored to meet the quality standards. Although GC waters do not meet certain quality standards they are not permitted to decline any further in quality. Steps must also be taken to prevent GC waters from contributing to the decline in quality of adjacent waters. Currently, there are no GC waters in the state (as of 12/89): In other words, the Groundwater Section considers it feasible to restore the quality of the current groundwater contamination incidents to within the allowable standards.


Figure 1. Groundwater Classifications and Quality Standards
GA Waters Must meet quality standards for all 74 substances.
GSA Waters Must meet quality standards for all 74 substances except dissolved solids and chloride.
GC Waters Contaminated waters which contain a (or many) substance(s) which do not meet the quality standards, and for which restoration of quality is not technologically feasible.


Figure 2. Groundwater Standards: Agricultural Chemicals Included in North Carolina Groundwater Standards (15 NCAC 2L .0202) (1989)
Common Name Trade Name Use Standard (mg/l)
Alachlor Lasso Herbicide 0.00015
Aldicarb Ternik Insecticide 0.009
Carbofuran Furadan Insecticide 0.036
Carbon tetrachloride various Insecticide 0.0003
Chlordane various Insecticide 0.000027
Various Copper formulations various Fungicide 1.0
Endrin various Insecticide 0.0002
Ethylene dibromide various Insecticide 0.0000005
Heptachlor various Insecticide 0.000076
Hexachlorobenzene various Seed Protectant 0.00002
Lindane various Insecticide 0.0000265
Methoxychlor Marlate Insecticide 0.1
Nitrate (as N) various Fertilizer 10.0
Nitrite (as N) various Fertilizer 1.0
Oxamyl Vydate L Fungicide 0.175
Pentachlorophenol Wood Treatment TC Insecticide 0.22
Toxaphene various Insecticide 0.000031
Various sulfur formulations various Inst./Fung. 250.0
1,2-dibromo-3-chloropropane various Nematicide 0.000025
2,SD various Herbicide 0.07
2,45-TP (Silvex) various Herbicide 0.01
Allowable pH levels: 65 - 8.5
(Source for trade names and use: 1989 North Carolina Agricultural Chemicals Manual. NCSU, College of Agriculture and Life Sciences.)


The issue of how best to protect groundwater has not been without debate. There are three types of policies: (1) non-degradation (not allowing concentrations of any substances in groundwater to increase); (2) limited degradation (allowing concentrations of substances to increase to a certain standard); and (3) differential protection (protecting certain groundwater, such as sources of drinking water, more than other groundwater).

The US EPA and many states have adopted differential groundwater protection policies which provide greatest protection and program assistance to recharge areas around public groundwater wells (commonly referred to as "wellhead protection" areas) to protect important drinking water supplies. North Carolina policy makers believe that all groundwater should be protected equally without regard to present or potential use.

Also, the debate has focussed on whether groundwater should be allowed to be degraded to a certain standard, or not at all. North Carolina groundwater quality regulations do not allow detectable concentrations of nonnatural substances which do not have quality standards to occur in GA and GSA groundwaters. State regulations do allow however, for limited degradation of substances with quality standards to occur in designated areas around facilities which discharge possible groundwater pollutants. When permits are issued for these facilities, a compliance boundary is established (varies depending on the facility) and a review boundary is established around disposal systems at the mid-point between the compliance boundary and the waste boundary. Monitoring must be put in place at the review boundary, and any increase over the groundwater standards for a particular substance will require corrective action by the property owner to insure that groundwater quality beyond the property will not degrade.

Who is Affected?

All property owners are responsible for groundwater contamination which occurs (or has occurred) on their property. The State requires corrective action to be undertaken for any activity which "results in the discharge of waste or hazardous substance or oil..." and/or any "activity which results in an increase in concentration of a substance in excess of the groundwater standard... other than agricultural operations.... " (15 NCAC 2L .0106)

While farm owners are not required to restore the quality of contaminated groundwater or to monitor the groundwater resource, groundwater contamination attributed to farm use may engender regulatory action. The regulations state that "(w)here groundwater qualiq standards are exceeded as a result of the application of pesticides or other agricultural chemicals... the Director (of the Division of Environmental Management) sha21 request the Pesticide Board to take appropriate regulatory action to control the use of the chemical or chemicals responsible for, or contributing to, such violations, or to discontinue their use." (15 NCAC 2L .0106 (g)) Current groundwater standards include 17 agrichemicals, nitrate and nitrite concentrations, and a range for allowable pH levels (see figure 2).

Under the rules established by the groundwater classifications and standards, owners of permitted facilities who "cause, permit or have control over any discharge of waste" (1S NCAC 2L .0110) are expected to monitor groundwater and to comply with the new groundwater standards. Permitted facilities which must monitor for groundwater pollution include: waste lagoon systems, surface impoundments, spray irrigation of waste, large septic tank systems (usually industrial, or owned by units of government, utilities), rotary distribution systems (used in the outer banks for tertiary water treatment), and the land application of wastes. "Treatment works and disposal systems which serve facilities raising and feeding animals..." are not required to monitor for groundwater quality (15 NCAC 2H .0217). Landfills and hazardous waste facilities and sites are required to monitor for groundwater quality under different regulatory programs. Owners of facilities required to monitor groundwater must take corrective action to restore contaminated groundwaters to concentrations below the standards.

Figure 3. Factors Affecting Pesticide Leaching
Pesticide properties:
(1) Watersolubility The propensity for a pesticide to dissolve in water. The higher the solubility of the pesticide, the greater the potential for the pesticide to be carried in solution to groundwater.
(2) Soil adsorption The propensity for a Desticide to wstick" to soil partides. The lower the soil adsorption, the more likely it will be leached to the groundwater.
(3) Volatility The propensity for a pesticide to disperse into the air. Nonvolatile pesticides are generally more persistent in the soil, and may eventualy move into the groundwater if all other factors are equal.
(4) Soil dissipation or "soil half-life" The measure of a pesticide's persistence in soil. Includes volatility but also several decomposition processes. When a pesticide resists decomposition it wlll remain in the soil longer, increasing its potential threat to groundwater.
Soil properties:
(1) Soil composition features Presence of clay minerals and high organic matter content contributes to the adsorption of pesticides, reducing the potential of the pesticide to reach groundwater.
(2) Soil Physical Properties Leaching is more likely when soil texture is coarse and light (sandy soils), when soil structure is granular or blocky, when soils are porous, and when soil moisture is high.
Other factors:
(1) Depth to groundwater If the distance to groundwater is large, the potential for pesticides to reach groundwater will be reduced.
(2) Permeability of vadose zone (unsaturated zone) The physical properties of the zone beneath the soil layer will determine the fate of pesticides as they are transported by water.
(3) The amount and seasonal variation of recharge Rainfall, climate, irrigation, etc. affect the movement of pestiades.
(4) Agricultural practice Tillage, rotation cover crops integrated pest management, irrigation practices, etc., all have a signicant effect on the movement of pesticides into groundwater.
(Source: Ground Water Ouality Protection. L.W. Canter, RC. Knox and D.M. Fairchild. Lewis Publishers, Chelsea Ml, 1987. pp. 178-182)

See figure 6 for a list of state agencies which can help with groundwater related problems, responsibilities, regulations and permits.

Figure 4. Pesticde Leaching Potential (Pesticides and related chemicals considered to have the greatest potential for leaching to groundwater by the US Environmental Protection Agency.)
PESTICIDES
Acifluorfen (H) Dalapon (H) Hexazinone (H)
Alachlor (H) Dibromochloropropane (N) Methomyl (I,N)
A dicarb (I) DCPA (H) Methoychlor (I)
Ametryn (H) Diazinon (I) Metolachlor (H)
Atrazine (H) Dicamba (H) Metribuzin (H)
Bromacil (H) 3,5-Dichlorobenzoic acid (H,I) Oxamyl (I)
Butylate (H) 1,2-Dichloropropane (N) Pentachlorophenol (H)
Carbaryl (I) Dieldrin (I) Pidoram (H)
Carbofuran (I) Dinoseb (H) Propachlor (H)
Carboxin (F) Diphenamid (H) Propazine (H)
Chloramben (H) Disulfoton (I) Propham (H)
alpha-Chlordane (I) Diron (H) Propoxur (I)
gamma-Chlordane (I) Endrin (I) Simazine (H)
Chlorothalonil (F) Ethylene dibromide (I,N) 2,4,5-T (H)
Cyanazine (H) Fluometuron (H) 2,4,5-TP (H)
Cycloate (H) Heptachlor (I) Tebuthiuron (H)
2,4D (H) Hexachlorobenzene(S) Terbacil (H)
Key F - Furlgicide, H - Herbicide, I - Insecticide, N - Nematicide, S - Seed Protectant
PESTICIDE METABOLTES
Aldicarb sulfone Disulfoton sulfone Metribuzin DA
Aldicarb sulfoxide ETU Metribuzin DADK
Atrazine, dealkylated Fenamiphos sulfone Metribuzin DK
Carbofuran-3-OH Fenamiphos sudoxide Pronamide metabolite, RH 24580
Carboxin suEoxide Heptachlor epoxide
DCPA acid metabolites Hexazinone
5-Hydroxy dicamba Methyl paraoxon
Source: Protecting Ground Water: Pesticides and Agricultural Practices. U.S. Environmental Protection Agency, Office of Ground-Water Protection, Washington, D.C. 1988.)

Agricultural Regulatory Programs to Protect Groundwater Quality

Pesticides and fertilizers can contaminate groundwater and can present a potential health hazard to nearby groundwater wells or surface waters. Many variables affect the potential "leaching" of pesticides and fertilizers into groundwater (see figure 3). The application of pesticides is subject to the N.C. Pesticide Act of 1971, to regulations adopted by the N.C. Pesticide Board, and to product labeling instructions.

The Pesticide Section in the Department of Agriculture administers regulations on the use, storage and disposal of pesticides as well as regulations regarding restricted use pesticides, pesticide applicators, and pesticide dealers. The Pesticide Board is the rule-making body which promulgates regulations regarding pesticides. Also, the Pesticide Board has the authority (G.S. 143 461) to designate any pesticide a restricted use pesticide and limit its use, its time and conditions of sale, its distribution, and may prohibit the use of any restricted use pesticide for designated purposes or at designated times.

The 1989 General Assembly authorized a study of the potential impact of pesticide use on groundwater in North Carolina. The study, which will begin during the summer of 1990, will monitor pesticides and metabolites the EPA considers to be highly leachable (see figure 4). Approximately 100 monitoring wells throughout the state will be specially constructed for the study. Also included in the study are 100 existing wells from the Department of Environment, Health and Natural Resources' ambient groundwater monitoring network. The sites are being selected to be representative of (a) the major hydrogeological areas in the state, and (b) the most vulnerable areas which might be affected by the agricultural use of pesticides. The Pesticide Board will consider the findings of the study and could establish new restrictions on pesticides which are problematic to North Carolina's groundwater quality.

The U.S. Department of Agriculture, Soil Conservation Service has developed a pesticide management program which indudes potential pesticide loss to leaching. Pesticide leaching potential is matched with the site-specific soil leaching potential to determine the overall leaching potential. This methodology, along with best management practices (including Integrated Pest Management (IPM) methods), are being used for recommendations to farm operators by Agricultural Extension agents and Soil Conservation Service specialists.

Underground Storage Tank Regulation

Underground storage tanks (USTs) must comply with federal and state registration requirements, regulations, and financial responsibilities. North Carolina statutes (NC GS 143-215.3 et seq.) reflect the federal requirements set forth in the Resource Conservation and Recovery Act (42 U.S.C.6901 et seq.) and the regulations promulgated by the EPA (40 CFR Parts 280 and 281). The U.S. EPA has delegated the administration of UST regulation in North Carolina to the UST Management Unit of the Pollution Control Branch of the Groundwater Section (Division of Environmental Management).

There are an estimated 220,000 underground storage tanks in North Carolina, 36 percent of which are estimated by the US EPA to be at risk of failing. 84,000 USTs are registered in the North Carolina regualtory program. Of these registered tanks, more than half are 15 years or older (see figure 5). Underground storage tanks are the main source of reported groundwater contamination incidents in North Carolina. The Groundwater Section has received notification of 854 leaking tanks, and groundwater contamination has been found at 419 of these sites. (Information provided to the 1990 Groundwater Protection Legislative Research Commission by the Division of Environmental Management.)

Figure 5 not shown.

The regulatory program requires that new USTs which contain petroleum must follow installation guidelines, be equipped for spill and overfill protection, protected from corrosion, and equipped with leak detection systems. Existing petroleum USTs must meet corrosion protection standards and must contain spill and overfill devices by 1998. USTs containing chemicals must meet even stricter standards induding double-walled systems, placing the UST in a concrete vault, and the installation of liners around the tank.

The following tanks are excluded from federal and state regulation and registration requirements:

  1. Farm or residential tanks of 1,100 gallons or less used for storage of motor fuel for noncommercial purposes;

  2. Tanks storing heating oil used on the premises where it is stored;

  3. Tanks on or above the floor of underground areas such as basements;

  4. Septic tanks and systems for collecting storm and wastewater;

  5. Flow-through process tanks;

  6. Tanks holding 110 gallons or less; and

  7. Emergency spill and overfill tanks.

Despite registration and regulatory exemptions, all tanks owners are responsible for any contamination they may cause to groundwater which violates groundwater quality standards as well as for subsequent clean up efforts imposed by the N.C. Groundwater Section.

Trust funds (one commercial and one noncommercial) have been established to help pay for cleanup costs associated with leaking tanks. According to a newly ratified bill by the N.C. General Assembly (1989), the trust funds cover those costs associated with a leaking tank which exceed S50,000 for cleanup of environmental damage, and $100,000 for compensation of third parties for bodily injury, and property damage up to an aggregate maximum of $1,000,000. (NC GS 143-215.94A et seq.)

Protection of Drinking Water

The Safe Drinking Water Act (42 USC 300f et seq.) and its North Carolina parallel, the N.C. Drinking Water Act (NC GS 130A Article 10) provide that drinking water must be safe regardless of its source. EPA establishes drinking water standards for various substances and delegates program responsibilities to the N. C. Division of Environmental Health, which implements the standards in its regulatory program.

Public Water Systems

Public water systems are regulated by the Division of Environmental Health, Public Water Supply Section. A public water system can be a "community water system" (serves 15 or more service connections or regularly serves at least 25 people year-round), a "non-communiq water systemw (system serving 25 or more people at least 60 days per year), or a "non-transient, non-community water system" (regularly serves at least 25 of the same persons 6 or more months per year). (10 NCAC 10D .0700)

Requirements to monitor drinking water vary depending on the type of public water system. The communiq water system has the highest require- ments for monitoring, it must be tested periodically for the following contaminants: microbiological or- ganisms, certain organic chemicals, certain inorganic chemicals (includes nitrate), radium, man-made radionuclides, trihalomethanes, corrosiviqw source fluoride, and volatile organic compounds. (10 NCAC 10D)

In addition, the Public Water Supply Section (Division of Environmental Health) investigates spills of hazardous substances that may affect public water supplies.

Private Wells

The regulation of private wells mandated by the N.C. Well Construction Act (NC GS 87-88) includes siting, design, and installation requirements. However, it remains the responsibility of the property owner to test his/her own water once the well is installed. Residents should consult their county health department to get their water tested for various contaminants. The State Health Lab (Division of Epidemiology) works closely with county health departments assessing the safeq of drinking water samples. If a pesticide is suspected as a contaminant, the samples will be analyzed by the Pesticide Epidemiology Section (again, through the county health department).

Some counties charge a nominal fee for testing a resident's water for bacteriological, inorganic and organic contaminants. (The State Health Lab charges counties for the containers used for the samples: S1.00 per bacteria bottle, and $9.00 per sample kit. But the actual cost to the Division of Epidemiology for providing this service is estimated at $7.00 per bacteria sample, S112.00 per inorganic chemical sample, and S672.00 per organic chemical sample.) (Information provided to the 1990 Groundwater Protection Legislative Research Commission by the Division of Environmental Health.)


Figure 6 N. C. Groundwater Protection Agencies and Phone Numbers (12/89)

General Groundwater Authority

Dept. of Enviromnent, Health & Natural Resources, Division of Environmental Management,
Groundwater Section, 919-733-3221.

Spills/Emergency Response

Hazardous chemicals
Your local county emergency management agency. Dept. of Crime Control & Public Safety, Emergency
Management Division,919-733-3867; Statewide 24 hour emergency number is 1-800-662-7956.

Pesticides

Spills/Emergency Response
Pesticide Emergency Reaction Team, N.C. Department of Agriculture, 919 733-3556.

Illegal dumping, use restrictions, pesticide applicators licensing, etc.
Pesticides in drinking water
Contact your County Health Department, or the Dept. of Environment, Health & Natural Resources,
Division of Epidemiology, Epidemiology Section, 919-733-3410.

Individual Wells, suspected contamination of well water
Contact your County Health Department, or your Regional Office of the Dept. of Environment,
Health & Natural Resources, Division of Environmental Management.

Health effects of contaminants in drinking water
DEHNR, Division of Epidemiology, Epidemiology Section, 919-733-3410.

Public Drinking Water (public water system testing results, location, etc.)
DEHNR, Division of Environmental Health, Public Water Supply Section, 919-733-2321.

Water Use, Conservation, and Leak Detection
DEHNR, Division of Water Resowces, 919 733 4064.

Solid Waste Sites (operating)
DEHNR, Solid Waste Management Division, Solid Waste Section, 919-733-0692.

Hazardous Waste Facilities (operating)
DEHNR, Solid Waste Management Division, Hazardous Waste Section, 919-733-2178.

Hazardous Waste Sites (abandoned)
DEHNR, Solid Waste Management Division, Superfund Section, 919-733-2801.

Underground Storage Tanks (registration, financial liability questions, leaking USTs, etc.)
DEHNR, Division of Environmental Management, Groundwater Section, UST Program, 919-733-3221.

Septic Tanks Systems (Installation, failure, etc.)
County Health Department; Dept. of Environment, Health & Natural Resources, Solid Waste Management
Division, Solid Waste Section, 919-733-0692.

Sewage Treatment
Dept. of Environment, Health & Natwal Resources, Division of Environmental Management,
Water Quality Section 919-733-5083.

Surface water discharge permits (NPDES)
Dept. of Enviromnent, Health & Natural Resources, Division of Environmental Management,

Water Quality Section 919-733-5083.


The New Jersey Cooperative Extension gives the following advice for homeowners who want to test their water: "For private wells, at a minimum, an annual coliform (bacteria) test is recommended, more frequently if in an urbanized area, quarterly if previous samples were positive for coliform. Nitrate, lead, and volatile organic chemical tests are also recommended. If you have a taste, color or odor problem, organic chemical testing is recommended, especially if in an urbanized area or near a hazardous waste site, landfill, gas station, or dry cleaner. Other (secondary or aesthetic) tests are recommended only if there are specific prob.lems or concerns with the water: hardness (if you have problems with your wash); iron or manganese (red water, staining of laundry or plumbing fixtures); sodium (if on a reduced sodium diet); pH and corrosiviq (if pipes are corroding or blue copper stains are appearing on plumbing fixtures); hydrogen sulfide (rotten egg odor); volatile organic (medicinal taste, chemical odor, or oily)." (Source: Groundwater Protection. The Northeastern States Cooperative Extension Agent Training Conference, June 10-12, 1985, Chicopee, Massachusetts.)


Distributed in furtherance of the Acts of Congress of May 8 and June 30, 1914. Employment and program opportunities are offered to all people regardless of race, color, national origin, sex, age, or disability. North Carolina State University, North Carolina A&T State University, U.S. Department of Agriculture, and local governments cooperating.
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